Photoredox-Mediated Mono- and Difluorination of Remote Unactivated Methylene C(sp3)–H Bonds of N-Alkyl Sulfonamides

δ-C–H Mono- and Dihalogenation of Alcohols

(2020) Alastair N. Herron et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Iodine‐Catalysis Approach to C(sp3)‐H Fluorination with Nucleophilic Fluorine

(2020) Daniel Bafaluy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Radical‐Promoted Distal C‐H Functionalization of C(sp3) Centers with Fluorinated Moieties

(2020) Enzo Nobile et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Remote C(sp3 )−H Trifluoromethylation of Carboxamides and Sulfonamides

(2019) Zhonglin Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed remote C(sp3)–H azidation and oxidative trifluoromethylation of benzohydrazides

(2019) Xu Bao et al.   Nature Communications

Copper-Catalyzed Amide Radical-Directed Cyanation of Unactivated Csp3–H Bonds

(2019) Hongwei Zhang et al.   ORGANIC LETTERS

The fluorination of C-H bonds: developments and perspectives

(2019) Veronique Gouverneur et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoredox-Mediated Remote C(sp3)–H Heteroarylation of N-Alkyl Sulfonamides

(2019) Zhiqiang Deng et al.   JOURNAL OF ORGANIC CHEMISTRY

Fe(II)-Catalyzed Site-selective Functionalization of Unactivated C(sp3)-H Bonds Guided by Alkoxyl Radical

(2018) Lei Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sulfonamide-Directed Chemo- and Site-Selective Oxidative Halogenation/Amination Using Halogenating Reagents Generated in Situ from Cyclic Diacyl Peroxides

(2018) Denghu Chang et al.   JOURNAL OF ORGANIC CHEMISTRY

Remote C–H Functionalization via Selective Hydrogen Atom Transfer

(2018) David Nagib et al.   SYNTHESIS-STUTTGART

Copper-Catalyzed Arylation of Remote C(sp3 )−H Bonds in Carboxamides and Sulfonamides

(2018) Zhaodong Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoinduced Remote Functionalization of Amides and Amines Using Electrophilic Nitrogen Radicals

(2018) Sara P. Morcillo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Site-Selective Remote Radical C−H Functionalization of Unactivated C−H Bonds in Amides Using Sulfone Reagents

(2018) Yong Xia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Primary, Secondary, and Tertiary γ-C(sp3)–H Vinylation of Amides via Organic Photoredox-Catalyzed Hydrogen Atom Transfer

(2018) Hui Chen et al.   ORGANIC LETTERS

Electrochemical-Oxidation-Induced Site-Selective Intramolecular C(sp3)–H Amination

(2018) Xia Hu et al.   ACS Catalysis

Photoredox-Mediated Minisci-type Alkylation of N-Heteroarenes with Alkanes with High Methylene Selectivity

(2018) Guo-Xing Li et al.   ACS Catalysis

Multiple Enone-Directed Reactivity Modes Lead to the Selective Photochemical Fluorination of Polycyclic Terpenoid Derivatives

(2017) Cody Ross Pitts et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Advances in Reactions of Heteroatom-Centered Radicals

(2017) Tsuyoshi Taniguchi   SYNTHESIS-STUTTGART

A unified photoredox-catalysis strategy for C(sp3)–H hydroxylation and amidation using hypervalent iodine

(2017) Guo-Xing Li et al.   Chemical Science

Catalytic Dehydrogenative C–H Imidation of Arenes Enabled by Photo-generated Hole Donation to Sulfonimide

(2017) Eri Ito et al.   Chem

Hexafluoroisopropanol as a highly versatile solvent

(2017) Ignacio Colomer et al.   Nature Reviews Chemistry

A Convenient Late-Stage Fluorination of Pyridylic C−H Bonds with N -Fluorobenzenesulfonimide

(2016) Michael Meanwell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Triiodide-Mediated δ-Amination of Secondary C−H Bonds

(2016) Ethan A. Wappes et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Bromination of C(sp3 )−H Bonds Distal to Functional Groups

(2016) Tao Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed, Fluoroamide-Directed C–H Fluorination

(2016) Brian J. Groendyke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen Bonding to Hexafluoroisopropanol Controls the Oxidative Strength of Hypervalent Iodine Reagents

(2016) Ignacio Colomer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Amide-directed photoredox-catalysed C–C bond formation at unactivated sp3 C–H bonds

(2016) John C. K. Chu et al.   NATURE

Catalytic alkylation of remote C–H bonds enabled by proton-coupled electron transfer

(2016) Gilbert J. Choi et al.   NATURE

Recent advances in radical-mediated fluorination through C–H and C–C bond cleavage

(2016) Hong Yan et al.   Science China-Chemistry

An Iodine-Catalyzed Hofmann-Löffler Reaction

(2015) Claudio Martínez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Monofluorination of Organic Compounds: 10 Years of Innovation

(2015) Pier Alexandre Champagne et al.   CHEMICAL REVIEWS

Chemoselective Intramolecular Functionalization of Methyl Groups in Nonconstrained Molecules Promoted by N-Iodosulfonamides

(2015) Nieves R. Paz et al.   ORGANIC LETTERS

Development of a Direct Photocatalytic C–H Fluorination for the Preparative Synthesis of Odanacatib

(2015) Shira D. Halperin et al.   ORGANIC LETTERS

Transition-metal free oxidative aliphatic C–H fluorination

(2015) Xiaofei Zhang et al.   Organic Chemistry Frontiers

A Convenient Photocatalytic Fluorination of Unactivated CH Bonds

(2014) Shira D. Halperin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective fluorination of alkyl C–H bonds via photocatalysis

(2014) Choon Wee Kee et al.   CHEMICAL COMMUNICATIONS

Late-Stage Formation of Carbon-Fluorine Bonds

(2014) Michael G. Campbell et al.   CHEMICAL RECORD

A photocatalyzed aliphatic fluorination

(2014) Steven Bloom et al.   Chemical Science

C sp 3F Bond Formation: A Free-Radical Approach

(2013) Mukund P. Sibi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Manganese-Catalyzed Oxidative Benzylic C-H Fluorination by Fluoride Ions

(2013) Wei Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)

(2013) Jiang Wang et al.   CHEMICAL REVIEWS

Visible Light-Promoted Metal-Free C–H Activation: Diarylketone-Catalyzed Selective Benzylic Mono- and Difluorination

(2013) Ji-Bao Xia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron(II)-Catalyzed Benzylic Fluorination

(2013) Steven Bloom et al.   ORGANIC LETTERS

Metal-Free Fluorination of C(sp3)–H Bonds Using a Catalytic N-Oxyl Radical

(2013) Yuuki Amaoka et al.   ORGANIC LETTERS

Intramolecular C(sp3)–H amination

(2013) Jenna L. Jeffrey et al.   Chemical Science

A Polycomponent Metal-Catalyzed Aliphatic, Allylic, and Benzylic Fluorination

(2012) Steven Bloom et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative Aliphatic C-H Fluorination with Fluoride Ion Catalyzed by a Manganese Porphyrin

(2012) W. Liu et al.   SCIENCE

Organic fluorine compounds: a great opportunity for enhanced materials properties

(2011) Ricarda Berger et al.   CHEMICAL SOCIETY REVIEWS

Instantaneous Deprotection of Tosylamides and Esters with SmI2/Amine/Water

(2009) Tobias Ankner et al.   ORGANIC LETTERS

1,3-Diol Synthesis via Controlled, Radical-Mediated C−H Functionalization

(2008) Ke Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Understanding organofluorine chemistry. An introduction to the C–F bond

(2007) David O'Hagan   CHEMICAL SOCIETY REVIEWS

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS