Dinitrogen and Carbon Dioxide Activation to Form C–N Bonds at Room Temperature: A New Mechanism Revealed by Experimental and Theoretical Studies

A Facile N≡N Bond Cleavage by the Trinuclear Metal Center in Vanadium Carbide Cluster Anions V3C4−

(2020) Zi-Yu Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Coupling N2 and CO2 in H2O to synthesize urea under ambient conditions

(2020) Chen Chen et al.   Nature Chemistry

Direct transformation of dinitrogen: synthesis of N-containing organic compounds via N−C bond formation

(2020) Ze-Jie Lv et al.   National Science Review

C–N Coupling in N2 Fixation by the Ditantalum Carbide Cluster Anions Ta2C4–

(2019) Zi-Yu Li et al.   INORGANIC CHEMISTRY

Clean and Efficient Transformation of CO2 to Isocyanic Acid: The Important Role of Triatomic Cation ScNH+

(2019) Ming Wang et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Scandium-Promoted Direct Conversion of Dinitrogen into Hydrazine Derivatives via N–C Bond Formation

(2019) Ze-Jie Lv et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dinitrogen Fixation and Reduction by Ta3N3H0,1– Cluster Anions at Room Temperature: Hydrogen-Assisted Enhancement of Reactivity

(2019) Yue Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Complete cleavage of the N≡N triple bond by Ta2N+ via degenerate ligand exchange at ambient temperature: A perfect catalytic cycle

(2019) Caiyun Geng et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Ligand Effects on the Reactivity of [CoX]+ (X = CN, F, Cl, Br, O, OH) Towards CO2: Gas-Phase Generation of the Elusive Cyanoformate by [Co(CN)]+ and [Fe(CN)]+

(2018) Marjan Firouzbakht et al.   TOPICS IN CATALYSIS

Heterogeneous Fe3 single-cluster catalyst for ammonia synthesis via an associative mechanism

(2018) Jin-Cheng Liu et al.   Nature Communications

Coupling of Methane and Carbon Dioxide Mediated by Diatomic Copper Boride Cations

(2018) Qiang Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ta2+-mediated ammonia synthesis from N2 and H2 at ambient temperature

(2018) Caiyun Geng et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

The structure of vanadium nitrogenase reveals an unusual bridging ligand

(2017) Daniel Sippel et al.   Nature Chemical Biology

Bond Activation by Metal–Carbene Complexes in the Gas Phase

(2016) Shaodong Zhou et al.   ACCOUNTS OF CHEMICAL RESEARCH

Efficient Room-Temperature Activation of Methane by TaN+ under C−N Coupling

(2016) Shaodong Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Simultaneous electrocatalytic reduction of dinitrogen and carbon dioxide on conducting polymer electrodes

(2016) Didem Balun Kayan et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage

(2014) Brian M. Hoffman et al.   CHEMICAL REVIEWS

Nitrogen Atom Transfer from a Dinitrogen-Derived Vanadium Nitride Complex to Carbon Monoxide and Isocyanide

(2014) Yutaka Ishida et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic aspects of dinitrogen cleavage and hydrogenation to produce ammonia in catalysis and organometallic chemistry: relevance of metal hydride bonds and dihydrogen

(2013) Hong-Peng Jia et al.   CHEMICAL SOCIETY REVIEWS

CN and CC Bond Formations in the Thermal Reactions of “Bare” Ni(NH2)+ with C2H4: Mechanistic Insight on the Metal-Mediated Hydroamination of an Unactivated Olefin

(2012) Robert Kretschmer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Neutral Metal Atoms Acting as a Leaving Group in Gas-Phase SN2 Reactions: M(CH3)+ + NH3 → CH3NH3+ + M (M = Zn, Cd, Hg)

(2012) Robert Kretschmer et al.   ORGANOMETALLICS

Mechanistic Aspects and Elementary Steps of NH Bond Activation of Ammonia and CN Coupling Induced by Gas-Phase Ions: A Combined Experimental/Computational Exercise

(2011) Robert Kretschmer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Organometallic Reactions of Ammonia

(2010) Jessica L. Klinkenberg et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Advances in selective activation and application of ammonia in homogeneous catalysis

(2010) Jarl Ivar van der Vlugt   CHEMICAL SOCIETY REVIEWS