Quantification of the Electrostatic Effect on Redox Potential by Positive Charges in a Catalyst Microenvironment

Integrating Electrochemical and Statistical Analysis Tools for Molecular Design and Mechanistic Understanding

(2020) Sophia G. Robinson et al.   ACCOUNTS OF CHEMICAL RESEARCH

Developing Scaling Relationships for Molecular Electrocatalysis through Studies of Fe-Porphyrin-Catalyzed O2 Reduction

(2020) Daniel J. Martin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Combining scaling relationships overcomes rate versus overpotential trade-offs in O2 molecular electrocatalysis

(2020) Daniel J. Martin et al.   Science Advances

Understanding How the Rate of C–H Bond Cleavage Affects Formate Oxidation Catalysis by a Mo-Dependent Formate Dehydrogenase

(2020) William E. Robinson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fast Proton Transfer and Hydrogen Evolution Reactivity Mediated by [Co13C2(CO)24]4–

(2020) Cody R. Carr et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Controlling the Oxygen Reduction Selectivity of Asymmetric Cobalt Porphyrins by Using Local Electrostatic Interactions

(2020) Rui Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bonding Energetics of Palladium Amido/Aryloxide Complexes in DMSO: Implications for Palladium‐Mediated Aniline Activation

(2020) Jun‐Yan Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intramolecular Electrostatic Effects on O2, CO2, and Acetate Binding to a Cationic Iron Porphyrin

(2020) Daniel J. Martin et al.   INORGANIC CHEMISTRY

Interfacial Field-Driven Proton-Coupled Electron Transfer at Graphite-Conjugated Organic Acids

(2020) Robert E. Warburton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Revealing the Relative Electronic Landscape of Colloidal ZnO and TiO2 Nanoparticles via Equilibration Studies

(2019) Janelle Castillo-Lora et al.   Journal of Physical Chemistry C

Synergistic Effects of Imidazolium-Functionalization on fac-Mn(CO)3 Bipyridine Catalyst Platforms for Electrocatalytic Carbon Dioxide Reduction

(2019) Siyoung Sung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selectivity Control for Electrochemical CO2 Reduction by Charge Redistribution on the Surface of Copper Alloys

(2019) Anthony Vasileff et al.   ACS Catalysis

CO2 electrochemical catalytic reduction with a highly active cobalt phthalocyanine

(2019) Min Wang et al.   Nature Communications

Nitrogenase Bioelectrochemistry for Synthesis Applications

(2019) Ross D. Milton et al.   ACCOUNTS OF CHEMICAL RESEARCH

Metalla-electrocatalyzed C–H Activation by Earth-Abundant 3d Metals and Beyond

(2019) Lutz Ackermann   ACCOUNTS OF CHEMICAL RESEARCH

Secondary Coordination Sphere Design to Modify Transport of Protons and CO2

(2019) Natalia D. Loewen et al.   INORGANIC CHEMISTRY

Controlled Expansion of a Strong-Field Iron Nitride Cluster: Multi-Site Ligand Substitution as a Strategy for Activating Interstitial Nitride Nucleophilicity

(2018) Myles J. Drance et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrochemical Methods for Assessing Kinetic Factors in the Reduction of CO2 to Formate: Implications for Improving Electrocatalyst Design

(2018) Atefeh Taheri et al.   ACS Catalysis

Local ionic liquid environment at a modified iron porphyrin catalyst enhances electrocatalytic performance of CO2 to CO reduction in water

(2018) Ally Aukauloo et al.   CHEMICAL COMMUNICATIONS

Effects of Charged Ligand Substituents on the Properties of the Formally Copper(III)-Hydroxide ([CuOH]2+) Unit

(2018) Debanjan Dhar et al.   INORGANIC CHEMISTRY

Computational Design of Synthetic Enzymes

(2018) Valerie Vaissier Welborn et al.   CHEMICAL REVIEWS

Homogeneous Molecular Catalysis of Electrochemical Reactions: Manipulating Intrinsic and Operational Factors for Catalyst Improvement

(2018) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tuning the Fe(II/III) Redox Potential in Nonheme Fe(II)–Hydroxo Complexes through Primary and Secondary Coordination Sphere Modifications

(2017) Zachary Gordon et al.   INORGANIC CHEMISTRY

Redox Potential and Electronic Structure Effects of Proximal Nonredox Active Cations in Cobalt Schiff Base Complexes

(2017) Alexander H. Reath et al.   INORGANIC CHEMISTRY

Electric-Field-Assisted Anion−π Catalysis

(2017) Masaaki Akamatsu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrocatalytic CO2 Reduction by Imidazolium-Functionalized Molecular Catalysts

(2017) Siyoung Sung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Materials for solar fuels and chemicals

(2017) Joseph H. Montoya et al.   NATURE MATERIALS

Reactivity Descriptors for the Activity of Molecular MN4 Catalysts for the Oxygen Reduction Reaction

(2016) José H. Zagal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Design and fine-tuning redox potentials of metalloproteins involved in electron transfer in bioenergetics

(2016) Parisa Hosseinzadeh et al.   BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS

An internal electron reservoir enhances catalytic CO2 reduction by a semisynthetic enzyme

(2016) Camille R. Schneider et al.   CHEMICAL COMMUNICATIONS

High Performance Fe Porphyrin/Ionic Liquid Co-catalyst for Electrochemical CO2 Reduction

(2016) Jaecheol Choi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Through-Space Charge Interaction Substituent Effects in Molecular Catalysis Leading to the Design of the Most Efficient Catalyst of CO2-to-CO Electrochemical Conversion

(2016) Iban Azcarate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration

(2016) Min Liu et al.   NATURE

Theoretical Heterogeneous Catalysis: Scaling Relationships and Computational Catalyst Design

(2016) Jeffrey Greeley   Annual Review of Chemical and Biomolecular Engineering

A pendant proton shuttle on [Fe4N(CO)12]− alters product selectivity in formate vs. H2 production via the hydride [H–Fe4N(CO)12]−

(2016) Natalia D. Loewen et al.   Chemical Science

Measuring Electric Fields and Noncovalent Interactions Using the Vibrational Stark Effect

(2015) Stephen D. Fried et al.   ACCOUNTS OF CHEMICAL RESEARCH

Vibrational Stark Effects To Identify Ion Pairing and Determine Reduction Potentials in Electrolyte-Free Environments

(2015) Tomoyasu Mani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Investigations of the Effect of the Non-Manganese Metal in Heterometallic-Oxido Cluster Models of the Oxygen Evolving Complex of Photosystem II: Lanthanides as Substitutes for Calcium

(2014) Po-Heng Lin et al.   INORGANIC CHEMISTRY

Probing active site chemistry with differently charged Au25q nanoclusters (q = −1, 0, +1)

(2014) Douglas R. Kauffman et al.   Chemical Science

Electrostatic control of regioselectivity via ion pairing in a Au(i)-catalyzed rearrangement

(2014) Vivian M. Lau et al.   Chemical Science

Scaling relations between adsorption energies for computational screening and design of catalysts

(2014) Matthew M. Montemore et al.   Catalysis Science & Technology

Electrocatalytic Hydrogen Evolution from Water by a Series of Iron Carbonyl Clusters

(2013) An D. Nguyen et al.   INORGANIC CHEMISTRY

Interfacial Electric Field Effects on a Carbene Reaction Catalyzed by Rh Porphyrins

(2013) Craig F. Gorin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heterometallic Triiron-Oxo/Hydroxo Clusters: Effect of Redox-Inactive Metals

(2013) David E. Herbert et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-inactive metals modulate the reduction potential in heterometallic manganese–oxido clusters

(2013) Emily Y. Tsui et al.   Nature Chemistry

Reduction potentials of heterometallic manganese-oxido cubane complexes modulated by redox-inactive metals

(2013) E. Y. Tsui et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Probing the Effect of the Solution Environment around Redox-Active Moieties Using Rigid Anthraquinone Terminated Molecular Rulers

(2012) Nadim Darwish et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Vibrational solvatochromism and electrochromism of infrared probe molecules containing C≡O, C≡N, C=O, or C−F vibrational chromophore

(2011) Jun-Ho Choi et al.   JOURNAL OF CHEMICAL PHYSICS

An Electric Field–Induced Change in the Selectivity of a Metal Oxide–Catalyzed Epoxide Rearrangement

(2011) Craig F. Gorin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nanoelectrochemistry: Metal Nanoparticles, Nanoelectrodes, and Nanopores

(2008) Royce W. Murray   CHEMICAL REVIEWS

Proton-Coupled Electron Transfer in Solution, Proteins, and Electrochemistry†

(2008) Sharon Hammes-Schiffer et al.   JOURNAL OF PHYSICAL CHEMISTRY B