4.7 Article

Gas separation performance of MMMs containing (PIM-1)-functionalized GO derivatives

Journal

JOURNAL OF MEMBRANE SCIENCE
Volume 623, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.memsci.2020.118902

Keywords

Gas separation; PIM-1 membranes; Graphene oxide; Mixed matrix membranes; Physical aging

Funding

  1. EPSRC [EP/K016946/1, EP/M01486X/1]
  2. Department of Chemical Engineering and Analytical Science - The University of Manchester

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A strategy to reduce physical aging in PIM-1 membranes by incorporating novel functionalized graphene oxide (GO) fillers is reported. The best performance was achieved by a membrane containing 10 wt% of (PIM-1)-functionalized APTS-GO, maintaining 85% of the initial CO2 permeability after 150 days. This represents about nine-fold less CO2 permeability drop compared to pure PIM-1.
A strategy to reduce the physical aging in PIM-1 membranes by incorporating novel functionalized graphene oxide (GO) fillers is reported. PIM-1 was covalently attached both to as-synthesized GO and to GO reacted with (3-aminopropyl)triethoxysilane (APTS-GO), leading to homogeneous dispersion of the nanofillers in the mixed matrix membranes (MMMs). It was found that the aging rate decreases with increasing content of (PIM-1)-functionalized GO, as evidenced by the smaller decrease in gas permeability over time. The best performance was achieved by a membrane containing 10 wt% of (PIM-1)-functionalized APTS-GO. This membrane maintains 85% of the initial CO2 permeability after 150 days (drop of only 310 Barrer), which represents about nine-fold less CO2 permeability drop as compared to pure PIM-1.

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