4.7 Article

Ultra uniform metal-organic framework-5 loading along electrospun chitosan/polyethylene oxide membrane fibers for efficient PM2.5 removal

Journal

JOURNAL OF CLEANER PRODUCTION
Volume 291, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.jclepro.2020.125270

Keywords

MOF-5; Chitosan/PEO; Electrospinning; PM2.5; Membrane; Filtration efficiency

Funding

  1. National Natural Science Foundation of China [51973100, 51673103, 11847135]
  2. Advanced Talents Foundation of Qingdao Agricultural University [663/1117011]
  3. Project of Shandong Province Higher Education Science and Technology Program [J17KA016]
  4. State Key Laboratory of Bio-Fibers and Eco-Textiles (Qingdao University) [K2019-12]

Ask authors/readers for more resources

A novel method was used to fabricate continuous and uniform MOF-5 on flexible electrospun chitosan/PEO fibers for PM2.5 removal properties. Carboxyl groups were introduced for chemical bonding, and MOF-5 crystals were secured by adjusting the volatility speed. The resulting membrane showed high filtration efficiency, making it a promising material for PM2.5 filtration.
A novel facile fabrication method was adopted for the first time to fabricate continuous, uniform, and stable metal-organic framework-5 (MOF-5), supported on flexible and freestanding electrospun chitosan/ (polyethylene oxide) (PEO) membrane fibers with comprehensive PM2.5 removal properties at room temperature. Carboxyl groups were introduced to connect amino groups on the chitosan nanofibers at an early stage; Zn2+ then had the opportunity for uniform chemical bonding to the surface of the functional carboxyl groups of the chitosan/PEO fibers. Finally, preferentially oriented, highly ordered, uniform, and stable MOF-5 crystals were secured along the continuous chitosan/PEO fibers via adjusting the speed of volatility of the triethylamine. This work provided that electrospun chitosan/PEO nanofibers could serve as an effective platform for obtaining a flexible and freestanding MOF-5 based membrane. The chitosan/ PEO@MOF-5 nanofiber membrane showed PM2.5 filtration efficiency and quality factor were 99.95% and 0.0737 respectively. Additionally, our findings suggested that the prepared chitosan/PEO@MOF-5 nanofiber membrane could be a good candidate material for filtering PM2.5. (c) 2020 Elsevier Ltd. All rights reserved.

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