4.7 Article

Mussel-inspired reinforcement of a biodegradable aliphatic polyester with bamboo fibers

Journal

JOURNAL OF CLEANER PRODUCTION
Volume 296, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.jclepro.2021.126587

Keywords

Bamboo fiber; PBS-Based biocomposites; Polydopamine; Interfacial adhesion

Funding

  1. National Natural Science Foundation of China [31670571]
  2. Beijing Natural Science Foundation [6202024]
  3. European Research Council under the European Union's Horizon 2020 research and innovation program (ERC Advanced Grant) [788489]
  4. China Scholarship Council

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A green, facile and effective method inspired by nature was reported to promote interfacial adhesion in biocomposites based on PBS reinforced with bamboo fibers modified with polydopamine, leading to significant improvements in both mechanical and water resistance properties.
Natural fiber-reinforced biocomposites displaying light weight, low thermal conductivity and reduced environmental footprint are increasingly relevant in structural, packaging, cementitious and masonry materials. However, the poor interfacial compatibility between fibers and typical polymers has limited the development of mechanical strength and water resistance. Here, we report a green, facile and effective method inspired by nature to promote interfacial adhesion in biocomposites based on a biodegradable aliphatic polyester (polybutylene succinate, PBS). For this purpose, PBS was reinforced with bamboo fibers modified with (3-aminopropyl) triethoxysilane and polydopamine (PDA). The PDA deposition and covalent adhesion with the fibers were promoted by self-polymerization and Michael addition and/or Schiff based secondary reactions. A distinct improvement in reinforcement was achieved together with gains in performance, including tensile strength (70%), tensile modulus (25%), flexural strength (37%), flexural modulus (24%) and impact strength (63%). The results far exceeded those measured for other fiber-reinforced biocomposites while simultaneously introduced water resistance. (c) 2021 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).

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