Catalysts and shape selective catalysis in the methanol-to-olefin (MTO) reaction

Molecular elucidating of an unusual growth mechanism for polycyclic aromatic hydrocarbons in confined space

(2020) Nan Wang et al.   Nature Communications

High Propylene Selectivity in Methanol Conversion over a Small-pore SAPO Molecular Sieve with Ultra-small Cage

(2020) Miao Yang et al.   ACS Catalysis

Light Olefin Diffusion during the MTO Process on H-SAPO-34: A Complex Interplay of Molecular Factors

(2020) Pieter Cnudde et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Impact of zeolite framework composition and flexibility on MTO selectivity: confinement or diffusion?

(2020) Avelino Corma et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Imaging spatiotemporal evolution of molecules and active sites in zeolite catalyst during methanol-to-olefins reaction

(2020) Mingbin Gao et al.   Nature Communications

Simultaneous Evaluation of Reaction and Diffusion over Molecular Sieves for Shape-Selective Catalysis

(2020) Jingfeng Han et al.   ACS Catalysis

Cage-defining Ring: A Molecular Sieve Structural Indicator for Light Olefin Product Distribution from the Methanol-to-Olefins Reaction

(2019) Jong Hun Kang et al.   ACS Catalysis

Methanol to Olefins Reaction Route Based on Methylcyclopentadienes as Critical Intermediates

(2019) Wenna Zhang et al.   ACS Catalysis

Recent Progress in Methanol‐to‐Olefins (MTO) Catalysts

(2019) Miao Yang et al.   ADVANCED MATERIALS

Presituated “coke”-determined mechanistic route for ethene formation in the methanol-to-olefins process on SAPO-34 catalyst

(2019) Jibin Zhou et al.   JOURNAL OF CATALYSIS

Cavity-controlled diffusion in 8-membered ring molecular sieve catalysts for shape selective strategy

(2019) Shushu Gao et al.   JOURNAL OF CATALYSIS

Chemical and Structural Parameter Connecting Cavity Architecture, Confined Hydrocarbon Pool Species, and MTO Product Selectivity in Small-Pore Cage-Based Zeolites

(2019) Pau Ferri et al.   ACS Catalysis

Insights into NH4-SAPO-34 preparation procedure: Effect of the number of ammonium exchange times on catalytic performance of Zn-modified SAPO-34 zeolite for methanol to olefin reaction

(2019) Huiwen Huang et al.   MICROPOROUS AND MESOPOROUS MATERIALS

Increasing the selectivity to ethylene in the MTO reaction by enhancing diffusion limitation in the shell layer of SAPO-34 catalyst

(2018) Jiawei Zhong et al.   CHEMICAL COMMUNICATIONS

Small-Pore Zeolites: Synthesis and Catalysis

(2018) Michiel Dusselier et al.   CHEMICAL REVIEWS

Further Studies on How the Nature of Zeolite Cavities That Are Bounded by Small Pores Influences the Conversion of Methanol to Light Olefins

(2018) Jong Hun Kang et al.   CHEMPHYSCHEM

Design of efficient bifunctional catalysts for direct conversion of syngas into lower olefins via methanol/dimethyl ether intermediates

(2018) Xiaoliang Liu et al.   Chemical Science

Evolution of C–C Bond Formation in the Methanol-to-Olefins Process: From Direct Coupling to Autocatalysis

(2018) Xinqiang Wu et al.   ACS Catalysis

Synthesis of high-Si hierarchical beta zeolites without mesoporogen and their catalytic application in the methanol to propene reaction

(2018) Xuebin Zhao et al.   Catalysis Science & Technology

The template-assisted zinc ion incorporation in SAPO-34 and the enhanced ethylene selectivity in MTO reaction

(2018) Jiawei Zhong et al.   Journal of Energy Chemistry

Insight into the deactivation mode of methanol-to-olefins conversion over SAPO-34: Coke, diffusion, and acidic site accessibility

(2018) Shushu Gao et al.   JOURNAL OF CATALYSIS

Methanol to Olefins Reaction over Cavity-type Zeolite: Cavity Controls the Critical Intermediates and Product Selectivity

(2018) Wenna Zhang et al.   ACS Catalysis

Realizing and Recognizing Syngas-to-Olefins Reaction via a Dual-Bed Catalyst

(2018) Youming Ni et al.   ACS Catalysis

Heterogeneous Catalysis for the Valorization of CO2: Role of Bifunctional Processes in the Production of Chemicals

(2018) Abhay Dokania et al.   ACS Energy Letters

Effect of framework topology of SAPO catalysts on selectivity and deactivation profile in the methanol-to-olefins reaction

(2017) Irene Pinilla-Herrero et al.   JOURNAL OF CATALYSIS

Direct Production of Lower Olefins from CO2 Conversion via Bifunctional Catalysis

(2017) Peng Gao et al.   ACS Catalysis

Highly Selective Conversion of Carbon Dioxide to Lower Olefins

(2017) Zelong Li et al.   ACS Catalysis

Investigation of methanol conversion over high-Si beta zeolites and the reaction mechanism of their high propene selectivity

(2017) Xuebin Zhao et al.   Catalysis Science & Technology

Recent advances of the nano-hierarchical SAPO-34 in the methanol-to-olefin (MTO) reaction and other applications

(2017) Jiawei Zhong et al.   Catalysis Science & Technology

Complex relationship between SAPO framework topology, content and distribution of Si and catalytic behaviour in the MTO reaction

(2017) I. Pinilla-Herrero et al.   Catalysis Science & Technology

Formation Mechanism of the First Carbon-Carbon Bond and the First Olefin in the Methanol Conversion into Hydrocarbons

(2016) Yue Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct and Highly Selective Conversion of Synthesis Gas into Lower Olefins: Design of a Bifunctional Catalyst Combining Methanol Synthesis and Carbon-Carbon Coupling

(2016) Kang Cheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective formation of light olefins from dimethyl ether over MCM-68 modified with phosphate species

(2016) Sungsik Park et al.   CATALYSIS TODAY

Selective conversion of syngas to light olefins

(2016) F. Jiao et al.   SCIENCE

Direct observation of methylcyclopentenyl cations (MCP+) and olefin generation in methanol conversion over TON zeolite

(2016) Jinbang Wang et al.   Catalysis Science & Technology

CHA/AEI intergrowth materials as catalysts for the Methanol-to-Olefins process

(2015) Rachel L. Smith et al.   APPLIED CATALYSIS A-GENERAL

The formation and degradation of active species during methanol conversion over protonated zeotype catalysts

(2015) U. Olsbye et al.   CHEMICAL SOCIETY REVIEWS

Morphology-induced shape selectivity in zeolite catalysis

(2015) Shewangizaw Teketel et al.   JOURNAL OF CATALYSIS

Dehydration Pathways of 1-Propanol on HZSM-5 in the Presence and Absence of Water

(2015) Yuchun Zhi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Effect of Pore and Cage Size on the Formation of Aromatic Intermediates During the Methanol-to-Olefins Reaction

(2015) Mark A. Deimund et al.   TOPICS IN CATALYSIS

Development of the CON-type Aluminosilicate Zeolite and Its Catalytic Application for the MTO Reaction

(2015) Masato Yoshioka et al.   ACS Catalysis

Methanol to Olefins (MTO): From Fundamentals to Commercialization

(2015) Peng Tian et al.   ACS Catalysis

Transport Phenomena in Nanoporous Materials

(2014) Jörg Kärger   CHEMPHYSCHEM

Catalytic conversion of dimethyl ether into propylene over MCM-68 zeolite

(2014) Sungsik Park et al.   JOURNAL OF CATALYSIS

Cavity Controls the Selectivity: Insights of Confinement Effects on MTO Reaction

(2014) Jinzhe Li et al.   ACS Catalysis

Direct Observation of Cyclic Carbenium Ions and Their Role in the Catalytic Cycle of the Methanol-to-Olefin Reaction over Chabazite Zeolites

(2013) Shutao Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Spatial confinement effects of cage-type SAPO molecular sieves on product distribution and coke formation in methanol-to-olefin reaction

(2013) Jingrun Chen et al.   CATALYSIS COMMUNICATIONS

Heptamethylbenzenium cation formation and the correlated reaction pathway during methanol-to-olefins conversion over DNL-6

(2013) Jinzhe Li et al.   CATALYSIS TODAY

Conversion of Methanol to Hydrocarbons: How Zeolite Cavity and Pore Size Controls Product Selectivity

(2012) Unni Olsbye et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diffusion in porous crystalline materials

(2012) Rajamani Krishna   CHEMICAL SOCIETY REVIEWS

A methanol to olefins review: Diffusion, coke formation and deactivation on SAPO type catalysts

(2012) D. Chen et al.   MICROPOROUS AND MESOPOROUS MATERIALS

Mechanism of the Catalytic Conversion of Methanol to Hydrocarbons

(2012) Samia Ilias et al.   ACS Catalysis

Effect of Cage Size on the Selective Conversion of Methanol to Light Olefins

(2012) Yashodhan Bhawe et al.   ACS Catalysis

Comparative study of MTO conversion over SAPO-34, H-ZSM-5 and H-ZSM-22: Correlating catalytic performance and reaction mechanism to zeolite topology

(2011) Jinzhe Li et al.   CATALYSIS TODAY

Observation of Heptamethylbenzenium Cation over SAPO-Type Molecular Sieve DNL-6 under Real MTO Conversion Conditions

(2011) Jinzhe Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Shape Selectivity in the Conversion of Methanol to Hydrocarbons: The Catalytic Performance of One-Dimensional 10-Ring Zeolites: ZSM-22, ZSM-23, ZSM-48, and EU-1

(2011) Shewangizaw Teketel et al.   ACS Catalysis

Shape selective methanol to olefins over highly thermostable DDR catalysts

(2010) Yasukazu Kumita et al.   APPLIED CATALYSIS A-GENERAL

Conversion of methanol over H-ZSM-22: The reaction mechanism and deactivation

(2010) Jinzhe Li et al.   CATALYSIS TODAY

Selectivity control through fundamental mechanistic insight in the conversion of methanol to hydrocarbons over zeolites

(2010) Shewangizaw Teketel et al.   MICROPOROUS AND MESOPOROUS MATERIALS

Product shape selectivity dominates the Methanol-to-Olefins (MTO) reaction over H-SAPO-34 catalysts

(2009) Bart P.C. Hereijgers et al.   JOURNAL OF CATALYSIS

Space- and Time-Resolved In-situ Spectroscopy on the Coke Formation in Molecular Sieves: Methanol-to-Olefin Conversion over H-ZSM-5 and H-SAPO-34

(2008) Davide Mores et al.   CHEMISTRY-A EUROPEAN JOURNAL

Towards a molecular understanding of shape selectivity

(2008) Berend Smit et al.   NATURE