Journal
CATALYSIS TODAY
Volume 265, Issue -, Pages 218-224Publisher
ELSEVIER
DOI: 10.1016/j.cattod.2015.08.061
Keywords
MCM-68; Phosphate-modification; DTO; Propylene; Coking-resistance
Funding
- Grants-in-Aid for Scientific Research [15H04185] Funding Source: KAKEN
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To control the acid sites distribution in MCM-68 zeolite catalyst, phosphate-loaded MCM-68 catalyst was prepared by impregnation with aqueous solution of (NH4)(2)HPO4 onto MCM-68 and subsequent calcination. Phosphate impregnation was effective for increasing the selectivity to propylene and butylenes. The propylene/ethylene ratio in the products was significantly increased by phosphate modification. The considerable enhancement of the yields of propylene and butylenes could be attributed to diminution of stronger acid sites, especially the acid sites distributed on the external surface of MCM-68 catalyst. Furthermore, phosphate-modified MCM-68 showed high resistance to coke formation, indicating this modification technique is useful to obtain long-lived catalysts in DTO reaction. (C) 2015 Elsevier B.V. All rights reserved.
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