Article
Spectroscopy
Tiago Fernandes, Natercia C. T. Martins, Ana L. Daniel-da-Silva, Tito Trindade
Summary: In this paper, the synthesis of magneto-plasmonic dendrimer-based nanosorbents containing Au nanostars is reported, and it is demonstrated that they can be used as versatile optical sensors for the detection of pesticides in spiked water samples. The magneto-plasmonic hybrid materials enhance the Raman signal of these pesticides under variable operational conditions, suggesting the versatility of these systems for water quality monitoring.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2022)
Article
Multidisciplinary Sciences
Sang Jin Lee, Tae Wu Kim, Jong Goo Kim, Cheolhee Yang, So Ri Yun, Changin Kim, Zhong Ren, Indika Kumarapperuma, Jane Kuk, Keith Moffat, Xiaojing Yang, Hyotcherl Ihee
Summary: This study investigates the light-induced structural transitions of bacteriophytochromes in a liquid solution phase using time-resolved x-ray solution scattering. It reveals the kinetic analysis of the structural species and provides mechanistic insights into how these photoreceptors transmit structural signals and regulate downstream biological responses.
Article
Chemistry, Multidisciplinary
Yu Mao, Zuoheng Zhang, Hongfeng Zhan, Jianfei Sun, Yan Li, Zhenhuang Su, Yonghua Chen, Xingyu Gao, Xiao Huang, Ning Gu
Summary: The mechanism of coprecipitation formation of iron oxides has been a long-standing challenge. In this study, a specially designed gas/liquid mixed phase fluidic reactor was used to investigate the formation process. The results suggest that the initial Fe3+ ions hydrolyze to form Fe(OH)(3), which then dehydrates to yield alpha-FeOOH. In the presence of Fe2+ ions, alpha-FeOOH finally transforms to Fe3O4.
CHEMICAL COMMUNICATIONS
(2022)
Article
Biochemistry & Molecular Biology
Sara Gomez, Natalia Rojas-Valencia, Tommaso Giovannini, Albeiro Restrepo, Chiara Cappelli
Summary: We explore the potential of resonance Raman spectroscopy for detecting ibuprofen in diluted aqueous solutions. By utilizing a fully polarizable quantum mechanics/molecular mechanics (QM/MM) approach coupled with molecular dynamics (MD) to account for the dynamic aspects of solvation, we demonstrate that selectively enhancing the Raman signal associated with the C-C stretching mode in the ring can facilitate the recognition of ibuprofen in water samples.
Article
Nanoscience & Nanotechnology
Gesiane P. Sousa, Anerise de Barros, Flavio M. Shimizu, Fernando A. Sigoli, Italo O. Mazali
Summary: In this work, highly crystalline beta-NaYF4:Yb3+,Er3+@NaYF4:Nd3+@NaYF4 UCNPs capped with an amino-modified nanosized silica shell were coupled with Au nanospheres. The plasmonic-driven dimerization of 4-ATP to DMAB was carried out solely by using the UCNP visible emissions to excite the Au nanoparticle localized surface plasmon resonance band. The reaction was monitored in situ through SERS, and IDMAP method was applied to analyze the SERS spectra acquired during the plasmonic photocatalytic measurements.
ACS APPLIED NANO MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Mbolantenaina Rakotomalala Robinson, Mustapha Abdelmoula, Martine Mallet, Romain Coustel
Summary: This work focuses on the synthesis and physico-chemical characterization of starch functionalized nano magnetites for pollutant sequestration. The presence of starch in the synthesis medium decreases magnetite crystallinity and enhances particle dispersion, resulting in fast-relaxing superparamagnetic particles at room temperature for high starch to iron mass ratios. The role of starch in the growth and stabilization of nano-magnetites is demonstrated.
MATERIALS CHEMISTRY AND PHYSICS
(2023)
Article
Physics, Applied
K. C. Anupam, Rony Saha, Jonathan Anderson, Anival Ayala, Christopher Engdahl, Edwin L. Piner, Mark W. Holtz
Summary: The study reported significant effects of nano-diamond seeding density on the growth, quality, and morphology of diamond films. Sparse seeding resulted in higher vertical and lateral growth rates before coalescence, with smaller lateral size and reduced surface roughness at higher seeding density. As thickness increased, material quality improved, as observed through narrowing of the diamond phonon peak and relative intensity measurements of Raman bands. x-ray photoelectron spectroscopy confirmed trends in diamond surface quality with varying seeding densities.
JOURNAL OF APPLIED PHYSICS
(2021)
Article
Chemistry, Multidisciplinary
Jana Hudecova, Josef Kapitan, Martin Dracinsky, Pavel Michal, Vaclav Profant, Petr Bour
Summary: This study investigated the structure of metal complexes with histidine residues using Raman spectroscopy and Raman optical activity methods. By combining computational and experimental results, the solution structure of histidine complexes was determined, revealing unique information about the metal complexes.
CHEMISTRY-A EUROPEAN JOURNAL
(2022)
Article
Chemistry, Analytical
Xiaozhang Qu, Dan Sun, Yuqi Cheng, Jiafeng Wang, Yan Wang, Weiqing Xu, Guohua Qi, Shuping Xu
Summary: The study used smart nanoprobes to discriminate and monitor the dynamic expression of PD-L1, revealing rapid modulation of PD-L1 content on cell membranes under external electrostimulation. The findings suggest that external electrostimulation may offer a superior approach for regulating PD-L1 compared to chemical drugs, showing potential clinical application value. This versatile strategy could be applied to many membrane protein-related studies, providing a practical method for assessing molecular profiles of cell membrane proteins in response to external stimuli.
Article
Chemistry, Multidisciplinary
Taylor A. Bramlett, Adam J. Matzger
Summary: This study experimentally determined the relative strength of halogen bonding interactions in solution by Raman spectroscopic observation of complexes formed from interacting iodobenzene-derived XB donors and pyridine XB acceptors. The evaluation of binding energy coupling with ALMO-EDA analysis revealed a prominent role for charge transfer interactions in halogen bonding energy contributions. Raman spectra accurately predicted stronger interactions within IPFB complexes than with IDNB complexes, despite IPFB having similar electrostatics to IDNB and containing a smaller sigma-hole.
CHEMISTRY-A EUROPEAN JOURNAL
(2021)
Article
Chemistry, Multidisciplinary
Katerina Peterkova, Mark Stitch, Rayhaan Z. Boota, Paul A. Scattergood, Paul I. P. Elliott, Michael Towrie, Peter Podbevsek, Janez Plavec, Susan J. Quinn
Summary: G-quadruplexes are important targets in cancer research and understanding their binding with diagnostic probes is crucial for the development of molecular tools. This study investigates the binding of an enantiopure NIR emitting [Os(TAP)(2)(dppz)](2+) complex to G-quadruplex structures formed by human telomere and cMYC sequences in solution using NMR and time-resolved infrared spectroscopy. The results show that the emission response of the complex is sensitive to subtle changes in the binding environment, indicating potential applications in cancer diagnostics.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Chemistry, Analytical
Bingyong Lin, Yueliang Wang, Yuanyuan Yao, Lifen Chen, Yanbo Zeng, Lei Li, Zhenyu Lin, Longhua Guo
Summary: Surface-enhanced Raman scattering (SERS) is a super-sensitive analysis technology that relies on the target molecular fingerprint information. Microgels are potential materials to suppress interference from adhesive macromolecules. The proposed method in this study involves a simple and oil-free synthesis of microgels for small-molecule detection.
ANALYTICAL CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Zhoutao Sun, Chen Kang, Xiaohui Fang, Hongmei Liu, Jinxin Guo, Xinping Zhang
Summary: Research demonstrates high sensitivity detection of crystal violet in aqueous solution using a capillary-based static liquid phase SERS method without the need for pre-functionalization, achieving an enhancement factor as high as 10^8 and a detection limit of 10^-9 M.
NANOSCALE ADVANCES
(2021)
Article
Spectroscopy
Sumayyah A. B. Chotoye, Maddison M. Eisnor, Rachael B. E. Ball, Christa L. Brosseau
Summary: Glutathione is a crucial biological free radical scavenger that helps prevent oxidative stress. Its decrease in concentration is associated with serious health issues. The development of an electrochemical surface-enhanced Raman spectroscopy method for the monitoring of glutathione could be valuable in healthcare monitoring. The platform combines SERS and electrochemical potential for enhanced detection, showing promise for point-of-care diagnostics.
JOURNAL OF RAMAN SPECTROSCOPY
(2023)
Article
Chemistry, Multidisciplinary
Zhiwei Zhao, Xu Zhang, Zhen Zhou, Erkang Wang, Zhangquan Peng
Summary: This study reveals the mechanism of solution-mediated oxygen reduction reaction in Li-O-2 batteries through experiments and theoretical calculations, providing important guidance for the optimization of soluble catalysts.
Article
Geology
Agathe M. Eijsink, James D. Kirkpatrick, Francois Renard, Matt J. Ikari
Summary: There is a lack of direct relation between laboratory measurements and field observations, especially for phyllosilicate-rich gouges. By integrating laboratory friction experiments with surface topography microscopy, a quantitative correlation between frictional slip behavior and fault surface morphology of centimeter-scale samples has been demonstrated. The morphological characteristics observed in the laboratory could indicate the earthquake nucleation potential on natural fault surfaces.
Article
Geochemistry & Geophysics
J. A. McBeck, B. Cordonnier, F. Renard
Summary: Determining the size of the representative elementary volume (REV) is crucial for upscaling properties from laboratory measurements to crustal systems. The REV size is expected to evolve as fracture networks propagate and coalesce. However, it may not systematically increase in all experiments due to the highly heterogeneous porosity distributions. In sandstone experiments, the REV size does increase systematically, suggesting that intact sandstone estimates may be applicable to damaged sandstone.
GEOPHYSICAL JOURNAL INTERNATIONAL
(2023)
Article
Geosciences, Multidisciplinary
Marthe G. Guren, Henrik A. Sveinsson, Anders Malthe-Sorenssen, Francois Renard
Summary: The creation of new fractures during an earthquake contributes to rock damage and helps dissipate strain energy. Simulation results show that fracture propagation speed and crack oscillations can lead to nanoscale roughness and fragments. These nanoparticles may control energy dissipation during frictional slip.
GEOPHYSICAL RESEARCH LETTERS
(2022)
Article
Geosciences, Multidisciplinary
John M. Aiken, Robert A. Sohn, Francois Renard, Juerg Matter, Peter Kelemen, Bjorn Jamtveit
Summary: Serpentinization and carbonation of mantle rocks are important processes in geoscience, affecting arc volcanism, earthquake processes, chemosynthetic biological communities, and carbon sequestration. Research has shown that free gas generated during peridotite alteration or microbial activity migrates through the formation in episodic bursts of activity. These observations reveal a dynamic mode of fluid migration during serpentinization and highlight the significant role of free gas in pore pressure, fluid flow, and alteration kinetics during peridotite weathering.
GEOPHYSICAL RESEARCH LETTERS
(2022)
Article
Geochemistry & Geophysics
James Ronald Johnson, Maya Kobchenko, Andrew Charles Johnson, Nazmul Haque Mondol, Francois Renard
Summary: A 2D Hele-Shaw cell was built to study microfracture nucleation, growth, and network formation, finding that lateral confinement and expulsion rate significantly influence the formation of microfracture network.
Article
Geochemistry & Geophysics
Maude Julia, Christine V. Putnis, Helen E. King, Francois Renard
Summary: The interactions between calcium carbonate and cadmium-rich fluid were studied at the nano and microscale under fluid flow and static fluid conditions. The study examined three forms of CaCO3: calcite in single crystals of Iceland Spar, calcite in polycrystalline Carrara marble, and aragonite single crystals. The experiments revealed the nanoscale effect of cadmium on CaCO3 dissolution and growth, as well as the precipitation of a Cd-rich phase on the samples' surfaces. Hydrothermal experiments showed that the reactivity of single calcite crystals was passivated by the epitaxial growth of a less soluble Cd-rich endmember on the sample surface. On the other hand, the presence of grain boundaries or structural changes in Carrara marble and aragonite allowed the replacement of samples by a porous (Ca,Cd)CO3 solid-solution phase.
Article
Engineering, Environmental
G. Montes-Hernandez, L. Feugueur, C. Vernier, A. E. S. Van Driessche, F. Renard
Summary: Current wastewater treatment technologies struggle to remove antibiotics, leading to contamination of water sources. This study demonstrates that aqueous carbonation of portlandite can effectively remove commonly used antibiotics from water. Amoxicillin showed the highest removal efficiency (9.5 mg/g), followed by cefazoline (4.3 mg/g) and ceftriaxone (2.7 mg/g). Comparatively, nanomagnetite-interfacial Fenton reaction is more effective in removing amoxicillin (76.5 mg/g), but is slower and more complex chemically. Both methods show promise at the laboratory scale and can be implemented in wastewater treatment plants.
JOURNAL OF WATER PROCESS ENGINEERING
(2023)
Article
Geochemistry & Geophysics
Jean-Pierre Gratier, Luca Menegon, Francois Renard
Summary: A mechanism involving grain boundary sliding is described for the deformation of fine-grained calcareous shales, which can accommodate large strains of 100%-300% in the Oisans massif in the Western Alps.
JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH
(2023)
Article
Water Resources
Marthe Gronlie Guren, Francois Renard, Catherine Noiriel
Summary: Using time-lapse X-ray micro-tomography, this study provides a detailed 3D characterization of the geometry evolution and dissolution rate mapping of four carbonate samples at pH 4.0. The dissolution rates exhibit a large spatial variability, with crystal edges and convex topographies showing the highest rates and flat surfaces and concave areas showing slower retreat. Microcrystalline aragonite dissolves at a higher rate compared to calcite, and rough microcrystalline calcite surface dissolves more slowly than specific faces of calcite spar crystal. The presence of mineral impurities and the geometry of the crystals and fluid-mineral interface affect the global dissolution process of carbonate rocks.
FRONTIERS IN WATER
(2023)
Article
Geosciences, Multidisciplinary
Joachim Mathiesen, Gaute Linga, Marek Misztal, Francois Renard, Tanguy Le Borgne
Summary: Solute transport in multiphase flow through porous media plays a crucial role in natural systems and geoengineering applications. This study investigates dispersion in multiphase flows using highly resolved numerical simulations of immiscible two-phase flow. The results show that the activation and deactivation of different flow pathways under capillary forces accelerate solute spreading compared to single phase flow. The study establishes transport laws under dynamic multiphase flows and identifies the controlling factors for solute dispersion in porous media.
GEOPHYSICAL RESEARCH LETTERS
(2023)
Article
Physics, Applied
Aldritt Scaria Madathiparambil, Kim Robert Tekseth, Fredrik K. Murer, Benoit Cordonnier, Nicolaine Agofack, Jessica McBeck, Pierre Cerasi, Francois Renard, Basab Chattopadhyay, Dag W. Breiby
Summary: Understanding the mechanical behavior of rocks is crucial for subsurface activities. This study combines 4D mu CT imaging with strain analysis to study the deformation process of Draupne shale. The study reveals intermittent deformation at different locations within the sample, which eventually evolves into a major fracture plane. This suggests that the previously reported macroscopic stress-strain relationship of Draupne shale samples may consist of irreversible processes.
PHYSICAL REVIEW APPLIED
(2023)
Article
Geochemistry & Geophysics
Jessica McBeck, Benoit Cordonnier, Yehuda Ben-Zion, Francois Renard
Summary: The spatial organization of deformation can provide important information about the timing of catastrophic failure in the brittle regime. Recent analyses show that deformation experiences temporary phases of delocalization superposed on an overall trend of localization. X-ray tomography experiments reveal that larger confining pressure promotes more dilation and greater localization of high strain events, while greater amounts of preexisting damage promote delocalization. Importantly, dilative strain may provide more reliable information about the timing of catastrophic failure than shear strain.
JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH
(2023)
Article
Geochemistry & Geophysics
Fabian Barras, Kjetil Thogersen, Einat Aharonov, Francois Renard
Summary: The question of what arrests an earthquake rupture is crucial for predicting earthquake magnitude. Using a minimal model, researchers have identified the basic physical parameters that may control the arrest of large ruptures and derived closed-form expressions to predict rupture arrest under different conditions.
JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH
(2023)
Article
Geochemistry & Geophysics
Stephen Paul Michalchuk, Sascha Zertani, Francois Renard, Florian Fusseis, Alireza Chogani, Oliver Plumper, Luca Menegon
Summary: This study analyzed pseudotachylytes and mylonitized pseudotachylytes from Lofoten, Norway to understand the evolution of fluid pathways and porosity. It was found that porosity is dispersed within the pseudotachylyte vein, but increased along garnet grain boundaries. The porosity is mainly formed due to metamorphic growth of garnet. In the mylonitized pseudotachylyte, porosity is dramatically reduced due to solution-precipitation processes. Porosity reduction may lead to shear zone hardening and new pseudotachylyte formation.
JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH
(2023)
Article
Environmental Sciences
Jess Mcbeck, Benoit Cordonnier, Michele Cooke, Laura Fattaruso, Francois Renard
Summary: Determining how fracture network development leads to macroscopic failure in heterogeneous materials may help estimate the timing of failure in rocks in the upper crust as well as in engineered structures. The proportion of extensile and shear deformation produced by fracture development indicates the appropriate failure criteria to apply, and thus is a key constraint in such an effort. According to synchrotron observations and modeling of triaxial compression experiments on granite, fracture networks transition from shear to extensile immediately before macroscopic failure in order to optimize the total mechanical efficiency of the system.
COMMUNICATIONS EARTH & ENVIRONMENT
(2023)