Recent advances in (hetero)dimetallic systems towards tandem catalysis

Tandem α/β-alkylation and transfer hydrogenation by heterodimetallic ruthenium-iridium complex

(2020) Niranjan Dehury et al.   INORGANICA CHIMICA ACTA

Heterobimetallic Complexes Bridged by Imidazol{[4,5-f][1,10]-phenanthrolin}-2-ylidene: Synthesis and Catalytic Activity in Tandem Reactions

(2019) Lütfiye Gök Pezük et al.   ORGANOMETALLICS

Pd/Cu Cocatalyzed Oxidative Tandem C–H Aminocarbonylation and Dehydrogenation of Tryptamines: Synthesis of Carbolinones

(2019) Hui Han et al.   JOURNAL OF ORGANIC CHEMISTRY

Homo- and Heterobimetallic Complexes Bearing NHC Ligands: Applications in α-Arylation of Amide, Suzuki-Miyaura Coupling Reactions, and Tandem Catalysis

(2019) Adhir Majumder et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Artificial Nanometalloenzymes for Cooperative Tandem Catalysis

(2019) Hui Li et al.   ACS Applied Materials & Interfaces

Isomerizing Olefin Metathesis

(2019) Jacqueline Pollini et al.   CHEMISTRY-A EUROPEAN JOURNAL

Phosphine-ligated Ir(III)-complex as a bi-functional catalyst for one-pot tandem hydroformylation-acetalization

(2019) Huan Liu et al.   JOURNAL OF CATALYSIS

Synthesis and Catalytic Applications of Heterobimetallic Carbene Complexes Obtained via Sequential Metalation of Two Bisazolium Salts

(2019) Maximilian Böhmer et al.   ORGANOMETALLICS

A Synthetic Route to Chiral Benzo-Fused N-Heterocycles via Sequential Intramolecular Hydroamination and Asymmetric Hydrogenation of Anilino-Alkynes

(2019) Cong Xu et al.   ORGANOMETALLICS

From molecular metal complex to metal-organic framework: The CO2 reduction photocatalysts with clear and tunable structure

(2019) Yu-Hui Luo et al.   COORDINATION CHEMISTRY REVIEWS

Hetero-Bimetallic Complexes Based on an Anthyridine Ligand Preparation and Catalytic Activity

(2019) Shih-Chieh Aaron Lin et al.   ORGANOMETALLICS

One-Pot Tandem Photoredox and Cross-Coupling Catalysis with a Single Palladium Carbodicarbene Complex

(2018) Yu-Cheng Hsu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tandem Hydroaminomethylation Reaction to Synthesize Amines from Alkenes

(2018) Philippe Kalck et al.   CHEMICAL REVIEWS

A leap forward in iridium–NHC catalysis: new horizons and mechanistic insights

(2018) Manuel Iglesias et al.   CHEMICAL SOCIETY REVIEWS

PdII -Catalyzed Oxidative Tandem aza-Wacker/Heck Cyclization for the Construction of Fused 5,6-Bicyclic N,O-Heterocycles

(2018) Chenghao Ye et al.   Chemistry-An Asian Journal

A Selective and Functional Group-Tolerant Ruthenium-Catalyzed Olefin Metathesis/Transfer Hydrogenation Tandem Sequence Using Formic Acid as Hydrogen Source

(2018) Grzegorz K. Zieliński et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric one-pot reactions using heterogeneous chemical catalysis: recent steps towards sustainable processes

(2018) György Szőllősi   Catalysis Science & Technology

One-Pot Combination of Metal- and Bio-Catalysis in Water for the Synthesis of Chiral Molecules

(2018) Nicolás Ríos-Lombardía et al.   Catalysts

Annulation of a Highly Functionalized Diazo Building Block with Indoles under Sc(OTf)3/Rh2(OAc)4 Multicatalysis through Michael Addition/Cyclization Sequence

(2018) Shanmugam Sakthivel et al.   JOURNAL OF ORGANIC CHEMISTRY

Design of a Selective Ring-Closing Enyne Metathesis–Reduction for the Generation of Different Synthetic Scaffolds

(2018) Denis N. Prada Gori et al.   JOURNAL OF ORGANIC CHEMISTRY

Diastereodivergent Reductive Cross Coupling of Alkynes through Tandem Catalysis: Z- and E-Selective Hydroarylation of Terminal Alkynes

(2018) Megan K. Armstrong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Photocatalytic C–F Borylation of Polyfluoroarenes by Rh/Ni Dual Catalysis Providing Valuable Fluorinated Arylboronate Esters

(2018) Ya-Ming Tian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Advances in Catalyzed Sequential Reactions and the Potential Use of Tetrapyrrolic Macrocycles as Catalysts

(2018) Everton Santos et al.   MOLECULES

IrIII/AuI and RhIII/AuI Heterobimetallic Complexes as Catalysts for the Coupling of Nitrobenzene and Benzylic Alcohol

(2018) Maximilian Böhmer et al.   ORGANOMETALLICS

Cu/Pd cooperatively catalyzed tandem C–N and C–P bond formation: access to phosphorated 2H-indazoles

(2017) Weiwei Wei et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Diastereoselective Radical Oxidative C–H Aminations toward Chiral Atropoisomeric (P, N) Ligand Precursors

(2017) Yan-Na Ma et al.   ORGANIC LETTERS

Development of a One-Pot Four C–C Bond-Forming Sequence Based on Palladium/Ruthenium Tandem Catalysis

(2017) Anne-Doriane Manick et al.   ORGANIC LETTERS

Production of Alcohols from Olefins via One-Pot Tandem Hydroformylation–Acetalization–Hydrogenolysis over Bifunctional Catalyst Merging RuIII–P Complex and RuIII Lewis Acid

(2017) Peng Wang et al.   ORGANOMETALLICS

The merger of transition metal and photocatalysis

(2017) Jack Twilton et al.   Nature Reviews Chemistry

Photochemical Stereocontrol Using Tandem Photoredox–Chiral Lewis Acid Catalysis

(2016) Tehshik P. Yoon   ACCOUNTS OF CHEMICAL RESEARCH

From a Sequential to a Concurrent Reaction in Aqueous Medium: Ruthenium-Catalyzed Allylic Alcohol Isomerization and Asymmetric Bioreduction

(2016) Nicolás Ríos-Lombardía et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Immobilization of two organometallic complexes into a single cage to construct protein-based microcompartments

(2016) Basudev Maity et al.   CHEMICAL COMMUNICATIONS

Polyaromatic N-heterocyclic carbene ligands and π-stacking. Catalytic consequences

(2016) Eduardo Peris   CHEMICAL COMMUNICATIONS

Dual Catalysis Strategies in Photochemical Synthesis

(2016) Kazimer L. Skubi et al.   CHEMICAL REVIEWS

Mono and dimetallic pyrene-imidazolylidene complexes of iridium(iii) for the deuteration of organic substrates and the C–C coupling of alcohols

(2016) S. Ibañez et al.   DALTON TRANSACTIONS

Multiple-Metal (De-)Hydrogenation-Catalysed Processes

(2016) David Ventura-Espinosa et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Auto-Tandem Catalysis: Activation of Multiple, Mechanistically Distinct Process by a Single Catalyst

(2016) Jason E. Camp   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Accessing a Biologically Relevant Benzofuran Skeleton by a One-Pot Tandem Heck Alkynylation/Cyclization Reaction Using Well-Defined Palladium N-Heterocyclic Carbene Complexes

(2016) Anuj Kumar et al.   INORGANIC CHEMISTRY

Tandem Suzuki–Miyaura/transfer hydrogenation reaction catalyzed by a Pd–Ru complex bearing an anionic dicarbene

(2016) Mario J. Bitzer et al.   JOURNAL OF CATALYSIS

Acceptorless Dehydrogenative Coupling of o-Aminobenzamides with the Activation of Methanol as a C1 Source for the Construction of Quinazolinones

(2016) Feng Li et al.   ORGANIC LETTERS

Controlling the hydrogenolysis of silica-supported tungsten pentamethyl leads to a class of highly electron deficient partially alkylated metal hydrides

(2016) Niladri Maity et al.   Chemical Science

Metal–Metal Bonds in Catalysis

(2016) Ian G. Powers et al.   ACS Catalysis

Dinuclear Tetrapyrazolyl Palladium Complexes Exhibiting Facile Tandem Transfer Hydrogenation/Suzuki Coupling Reaction of Fluoroarylketone

(2016) Niranjan Dehury et al.   ACS Catalysis

Tandem catalysis versus one-pot catalysis: ensuring process orthogonality in the transformation of essential-oil phenylpropenoids into high-value products via olefin isomerization–metathesis

(2016) Carolyn S. Higman et al.   Catalysis Science & Technology

Tandem Reactions Combining Biocatalysts and Chemical Catalysts for Asymmetric Synthesis

(2016) Yajie Wang et al.   Catalysts

Structural and Reactivity Models for Copper Oxygenases: Cooperative Effects and Novel Reactivities

(2015) Joan Serrano-Plana et al.   ACCOUNTS OF CHEMICAL RESEARCH

The octahaem MccA is a haem c–copper sulfite reductase

(2015) Bianca Hermann et al.   NATURE

Orthogonal tandem catalysis

(2015) Tracy L. Lohr et al.   Nature Chemistry

Synthesis of Polyheteroaromatic Compounds via Rhodium-Catalyzed Multiple C–H Bond Activation and Oxidative Annulation

(2015) Shiyong Peng et al.   ORGANIC LETTERS

Tandem Dehydrogenation/Oxidation/Oxidative Cyclization Approach to Wrightiadione and Its Derivatives

(2015) Yujeong Jeong et al.   ORGANIC LETTERS

A Nanosized Janus Bis-N-heterocyclic Carbene Ligand Based on a Quinoxalinophenanthrophenazine Core, and Its Coordination to Iridium

(2015) Hugo Valdés et al.   ORGANOMETALLICS

Bimetallic N-Heterocyclic Carbene Rh(I) Complexes: Probing the Cooperative Effect for the Catalyzed Hydroelementation of Alkynes

(2015) Vera Diachenko et al.   ORGANOMETALLICS

Development of a One-Pot Tandem Reaction Combining Ruthenium-Catalyzed Alkene Metathesis and Enantioselective Enzymatic Oxidation To Produce Aryl Epoxides

(2015) Carl A. Denard et al.   ACS Catalysis

Gold-Catalyzed Allylation of Aryl Boronic Acids: Accessing Cross-Coupling Reactivity with Gold

(2014) Mark D. Levin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Indoles Using Visible Light: Photoredox Catalysis for Palladium-Catalyzed CH Activation

(2014) Jochen Zoller et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Multimetallic Catalysis Based on Heterometallic Complexes and Clusters

(2014) Paulin Buchwalter et al.   CHEMICAL REVIEWS

Bi- and tri-metallic Rh and Ir complexes containing click derived bis- and tris-(pyrazolyl-1,2,3-triazolyl) N–N′ donor ligands and their application as catalysts for the dihydroalkoxylation of alkynes

(2014) Khuong Q. Vuong et al.   DALTON TRANSACTIONS

Facile tandem Suzuki coupling/transfer hydrogenation reaction with a bis-heteroscorpionate Pd–Ru complex

(2014) Niranjan Dehury et al.   DALTON TRANSACTIONS

Mono- vs. Dinuclear Gold-Catalyzed Intermolecular Hydroamidation

(2014) Juan M. Serrano-Becerra et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Aza-acyclic Nucleoside Phosphonates Containing a Second Phosphonate Group As Inhibitors of the Human, Plasmodium falciparum and vivax 6-Oxopurine Phosphoribosyltransferases and Their Prodrugs As Antimalarial Agents

(2014) Dianne T. Keough et al.   JOURNAL OF MEDICINAL CHEMISTRY

Analysis of the Structural Diversity, Substitution Patterns, and Frequency of Nitrogen Heterocycles among U.S. FDA Approved Pharmaceuticals

(2014) Edon Vitaku et al.   JOURNAL OF MEDICINAL CHEMISTRY

Scope and Mechanism of Homogeneous Tantalum/Iridium Tandem Catalytic Alkane/Alkene Upgrading using Sacrificial Hydrogen Acceptors

(2014) David C. Leitch et al.   ORGANOMETALLICS

Rhodium(I)-N-Heterocyclic Carbene Catalyst for Selective Coupling of N-Vinylpyrazoles with Alkynes via C–H Activation

(2014) Ramón Azpíroz et al.   ACS Catalysis

Pyrene-Based Mono- and Di-N-Heterocyclic Carbene Ligand Complexes of Ruthenium for the Preparation of Mixed Arylated/Alkylated Arylpyridines

(2014) Sergio Gonell et al.   ACS Catalysis

Cooperative Bimetallic Asymmetric Catalysis: Comparison of a Planar Chiral Ruthenocene Bis-Palladacycle to the Corresponding Ferrocene

(2014) Tina Hellmuth et al.   ACS Catalysis

Heterogeneous Catalysis for Tandem Reactions

(2014) Maria J. Climent et al.   ACS Catalysis

Phosphinate Chemistry in the 21st Century: A Viable Alternative to the Use of Phosphorus Trichloride in Organophosphorus Synthesis.

(2013) Jean-Luc Montchamp   ACCOUNTS OF CHEMICAL RESEARCH

Rescuing Auxotrophic Microorganisms with Nonenzymatic Chemistry

(2013) Yunmi Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Co-immobilization of an Enzyme and a Metal into the Compartments of Mesoporous Silica for Cooperative Tandem Catalysis: An Artificial Metalloenzyme

(2013) Karin Engström et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperative Tandem Catalysis by an Organometallic Complex and a Metalloenzyme

(2013) Carl A. Denard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Two- and Three-dimensional Rings in Drugs

(2013) Matteo Aldeghi et al.   Chemical Biology & Drug Design

Synthesis of binaphthyl based phosphine and phosphite ligands

(2013) Mariette M. Pereira et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of Heterodimetallic Iridium-Palladium Complexes Containing Two Axes of Chirality: Study of Sequential Catalytic Properties

(2013) Sara Sabater et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Towards resource efficient chemistry: tandem reactions with renewables

(2013) Arno Behr et al.   GREEN CHEMISTRY

Catalytic Synthesis of n-Alkyl Arenes through Alkyl Group Cross-Metathesis

(2013) Graham E. Dobereiner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Upgrading Light Hydrocarbons via Tandem Catalysis: A Dual Homogeneous Ta/Ir System for Alkane/Alkene Coupling

(2013) David C. Leitch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A supramolecular approach to combining enzymatic and transition metal catalysis

(2013) Z. Jane Wang et al.   Nature Chemistry

A Tetracyclic Bis(imidazolindiylidene) Ligand and Its Diiridium and Dipalladium Complexes

(2013) Hugo Valdés et al.   ORGANOMETALLICS

Cooperative Catalysis: Large Rate Enhancements with Bimetallic Rhodium Complexes

(2013) Sandra W. S. Choy et al.   ORGANOMETALLICS

Bimetallic Complexes for Enhancing Catalyst Efficiency: Probing the Relationship between Activity and Intermetallic Distance

(2013) Marina G. Timerbulatova et al.   ORGANOMETALLICS

Heterometallic complexes, tandem catalysis and catalytic cooperativity

(2013) José A. Mata et al.   Chemical Science

Hydrodefluorination of carbon–fluorine bonds by the synergistic action of a ruthenium–palladium catalyst

(2013) Sara Sabater et al.   Nature Communications

Alkane Metathesis by Tandem Alkane-Dehydrogenation–Olefin-Metathesis Catalysis and Related Chemistry

(2012) Michael C. Haibach et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Applications of Early/Late Heterobimetallic Complexes

(2012) Benjamin G. Cooper et al.   CATALYSIS REVIEWS-SCIENCE AND ENGINEERING

Dual Catalysis with an IrIII-AuIHeterodimetallic Complex: Reduction of Nitroarenes by Transfer Hydrogenation using Primary Alcohols

(2012) Sara Sabater et al.   CHEMISTRY-A EUROPEAN JOURNAL

Comparison of symmetric and asymmetric bipolar type high triplet energy host materials for deep blue phosphorescent organic light-emitting diodes

(2012) Soon Ok Jeon et al.   JOURNAL OF MATERIALS CHEMISTRY

Isomerizing Olefin Metathesis as a Strategy To Access Defined Distributions of Unsaturated Compounds from Fatty Acids

(2012) Dominik M. Ohlmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthetic cascades are enabled by combining biocatalysts with artificial metalloenzymes

(2012) V. Köhler et al.   Nature Chemistry

Heterobimetallic Iridium–Ruthenium Assemblies through an Ambidentate Triazole-Diylidene Ligand: Electrochemical Properties and Catalytic Behavior in a Cascade Reaction

(2012) Sara Sabater et al.   ORGANOMETALLICS

Y-Shaped Tris-N-Heterocyclic-Carbene Ligand for the Preparation of Multifunctional Catalysts of Iridium, Rhodium, and Palladium

(2012) Sergio Gonell et al.   ORGANOMETALLICS

Total Synthesis of Indoline Alkaloids: A Cyclopropanation Strategy

(2011) Dan Zhang et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Highly Active Catalyst for the Hydrogenation of Amides to Alcohols and Amines

(2011) Jeremy M. John et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Review on Modern Advances of Chemical Methods for the Introduction of a Phosphonic Acid Group

(2011) Charles S. Demmer et al.   CHEMICAL REVIEWS

Advances in the Chemistry of Tetrahydroquinolines

(2011) Vellaisamy Sridharan et al.   CHEMICAL REVIEWS

Modified N,N′-Dicarbazolyl-3,5-benzene as a High Triplet Energy Host Material for Deep-Blue Phosphorescent Organic Light-Emitting Diodes

(2011) Yong Joo Cho et al.   CHEMISTRY-A EUROPEAN JOURNAL

Heterobimetallic complexes containing an N-heterocyclic carbene based multidentate ligand and catalyzed tandem click/Sonogashira reactions

(2011) Shaojin Gu et al.   DALTON TRANSACTIONS

Cooperativity in Bimetallic Dihydroalkoxylation Catalysts Built on Aromatic Scaffolds: Significant Rate Enhancements with a Rigid Anthracene Scaffold

(2011) Joanne H. H. Ho et al.   ORGANOMETALLICS

Tandem catalysis of ring-closing metathesis/atom transfer radical reactions with homobimetallic ruthenium–arene complexes

(2010) Yannick Borguet et al.   Beilstein Journal of Organic Chemistry

An Ir-Pt Catalyst for the Multistep Preparation of Functionalized Indoles from the Reaction of Amino Alcohols and Alkynyl Alcohols

(2010) Alessandro Zanardi et al.   CHEMISTRY-A EUROPEAN JOURNAL

One-Pot Preparation of Imines from Nitroarenes by a Tandem Process with an Ir-Pd Heterodimetallic Catalyst

(2010) Alessandro Zanardi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Advances in Multicatalyst Promoted Asymmetric Tandem Reactions

(2010) Jian Zhou   Chemistry-An Asian Journal

On the Mechanism of Palladium-Catalyzed Aromatic C−H Oxidation

(2010) David C. Powers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metathesis of Alkanes and Related Reactions

(2009) Jean-Marie Basset et al.   ACCOUNTS OF CHEMICAL RESEARCH

Highly Active and Recyclable Heterogeneous Iridium Pincer Catalysts for Transfer Dehydrogenation of Alkanes

(2009) Zheng Huang et al.   ADVANCED SYNTHESIS & CATALYSIS

Direct Phosphonylation of Aromatic Azaheterocycles

(2009) Sarah Van der Jeught et al.   CHEMICAL REVIEWS

Bite angle effects of diphosphines in C–C and C–X bond forming cross coupling reactions

(2009) Mandy-Nicole Birkholz (née Gensow) et al.   CHEMICAL SOCIETY REVIEWS

Auto-Tandem Catalysis: A Single Catalyst Activating Mechanistically Distinct Reactions in a Single Reactor

(2009) Naoya Shindoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Well-Defined Ir/Pd Complexes with a Triazolyl-diylidene Bridge as Catalysts for Multiple Tandem Reactions

(2009) Alessandro Zanardi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of (+)-Cephalostatin 1

(2009) Kevin C. Fortner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimetallic Pd(III) complexes in palladium-catalysed carbon–heteroatom bond formation

(2009) David C. Powers et al.   Nature Chemistry

Rhodium(I)-Catalyzed Cyclization Reaction ofo-Alkynyl Phenols and Anilines. Domino Approach to 2,3-Disubstituted Benzofurans and Indoles

(2009) Naohiro Isono et al.   ORGANIC LETTERS

Domino Approach to Benzofurans by the Sequential Sonogashira/Hydroalkoxylation Couplings Catalyzed by New N-Heterocyclic-Carbene-Palladium Complexes

(2009) Alessandro Zanardi et al.   ORGANOMETALLICS

Carboline Alkaloids fromTrigonostemon lii

(2009) Xu-Jia Hu et al.   PLANTA MEDICA

Spongipyran synthetic studies. Evolution of a scalable total synthesis of (+)-spongistatin 1

(2009) Amos B. Smith et al.   TETRAHEDRON

Some Recent Approaches to the Synthesis of 2-Substituted Benzofurans

(2008) Lidia De Luca et al.   CURRENT MEDICINAL CHEMISTRY

Allylic Alkylation and Ring-Closing Metathesis in Sequence:  A Successful Cohabitation of Pd and Ru

(2008) Claire Kammerer et al.   ORGANIC LETTERS

Homo- and Heterodinuclear Complexes with Triazolyl-diylidene. An Easy Approach to Tandem Catalysts

(2008) Alessandro Zanardi et al.   ORGANOMETALLICS