NHC‐Catalyzed Desymmetrization of N‐Aryl Maleimides Leading to the Atroposelective Synthesis of N‐Aryl Succinimides

Isothiourea-Catalyzed Atropselective Acylation of Biaryl Phenols via Sequential Desymmetrization / Kinetic Resolution

(2020) Elizabeth Munday et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bifunctional N-Heterocyclic Carbenes Derived from l-Pyroglutamic Acid and Their Applications in Enantioselective Organocatalysis

(2020) Xiang-Yu Chen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Enantioselective Synthesis of N–C Axially Chiral Compounds by Cu‐Catalyzed Atroposelective Aryl Amination

(2020) Johanna Frey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atropisomerism in diarylamines: structural requirements and mechanisms of conformational interconversion

(2020) Romain Costil et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Tricyclic β-Lactones by NHC-Catalyzed Desymmetrization of Cyclic 1,3-Diketones

(2020) Sayan Shee et al.   ORGANIC LETTERS

Asymmetric Synthesis of Axially Chiral Anilides via Organocatalytic Atroposelective N-Acylation

(2020) Dawei Li et al.   ORGANIC LETTERS

Isothiourea-Catalyzed Atroposelective N-Acylation of Sulfonamides

(2020) Jun-Yang Ong et al.   ORGANIC LETTERS

NHC-Catalyzed Generation of α,β-Unsaturated Acylazoliums for the Enantioselective Synthesis of Heterocycles and Carbocycles

(2019) Santigopal Mondal et al.   ACCOUNTS OF CHEMICAL RESEARCH

Enantioselective Atropisomeric Anilides Synthesis via Cu-Catalyzed Intramolecular Adjacent C–N Coupling

(2019) Xiaozhong Fan et al.   ACS Catalysis

NHC-Catalyzed Atroposelective Acylation of Phenols: Access to Enantiopure NOBIN Analogs by Desymmetrization

(2019) Shenci Lu et al.   ORGANIC LETTERS

NHC-catalyzed atropoenantioselective synthesis of axially chiral biaryl amino alcohols via a cooperative strategy

(2019) Gongming Yang et al.   Nature Communications

Atroposelective Arene Formation by Carbene-Catalyzed Formal [4+2] Cycloaddition

(2019) Ke Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbene-Catalyzed Desymmetrization and Direct Construction of Arenes with All-Carbon Quaternary Chiral Center

(2019) Tingshun Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereo- and Atroposelective Synthesis of Bridged Biaryls Bearing an Eight-Membered Lactone through an Organocatalytic Cascade

(2019) Shenci Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbene Catalysis via Azolium Dienolates: An Efficient Strategy for Remote Enantioselective Functionalizations

(2018) Xiang-Yu Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A continuing challenge: N-heterocyclic carbene-catalyzed syntheses of γ-butyrolactones

(2018) Kathleen J. R. Murauski et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective N-Heterocyclic Carbene-Catalyzed Kinetic Resolution of Anilides

(2018) Jianbo Bie et al.   ORGANIC LETTERS

Access to All-Carbon Spirocycles through a Carbene and Thiourea Cocatalytic Desymmetrization Cascade Reaction

(2018) Shitian Zhuo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Catalysis via the α,β-Unsaturated Acyl Azolium

(2017) Changhe Zhang et al.   ACS Catalysis

N-Heterocyclic carbene-catalyzed desymmetrization of functionalized 1,4-dienes via Stetter Reaction

(2016) Qiqiao Lin et al.   CHEMICAL COMMUNICATIONS

Silver(I)-Catalyzed Atroposelective Desymmetrization of N-Arylmaleimide via 1,3-Dipolar Cycloaddition of Azomethine Ylides: Access to Octahydropyrrolo[3,4-c]pyrrole Derivatives

(2016) Hua-Chao Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Access to P-Stereogenic Phosphinates via N-Heterocyclic Carbene-Catalyzed Desymmetrization of Bisphenols

(2016) Zhijian Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral N-1-adamantyl-N-trans-cinnamylaniline type ligands: synthesis and application to palladium-catalyzed asymmetric allylic alkylation of indoles

(2016) Takashi Mino et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Discovery and enantiocontrol of axially chiral urazoles via organocatalytic tyrosine click reaction

(2016) Ji-Wei Zhang et al.   Nature Communications

Rate and Equilibrium Constants for the Addition of N-Heterocyclic Carbenes into Benzaldehydes: A Remarkable 2-Substituent Effect

(2015) Christopher J. Collett et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nonbiaryl and Heterobiaryl Atropisomers: Molecular Templates with Promise for Atropselective Chemical Transformations

(2015) Elango Kumarasamy et al.   CHEMICAL REVIEWS

Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes

(2015) Darrin M. Flanigan et al.   CHEMICAL REVIEWS

Organocatalytic Atroposelective Formal Diels–Alder Desymmetrization of N-Arylmaleimides

(2015) Florine Eudier et al.   ORGANIC LETTERS

Recent Advances in the N-Heterocyclic Carbene (NHC)-Organocatalyzed Stetter Reaction and Related Chemistry

(2015) Akkattu Biju et al.   SYNTHESIS-STUTTGART

Remote Control of Axial Chirality: Aminocatalytic Desymmetrization of N-Arylmaleimides via Vinylogous Michael Addition

(2014) Nicola Di Iorio et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile Synthesis of γ-Ketophosphonates by an Intermolecular Stetter Reaction onto Vinylphosphonates

(2014) Atanu Patra et al.   ORGANIC LETTERS

Asymmetric Synthesis of Atropisomeric Compounds with an N‒C Chiral Axis

(2014) Isao Takahashi et al.   ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL

SYNTHESIS OF A N-MESITYL SUBSTITUTED AMINOINDANOL-DERIVED TRIAZOLIUM SALT

(2014)   ORGANIC SYNTHESES

NHC-Catalyzed Hydroacylation of Styrenes

(2013) Michael Schedler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Activation of Carbohydrates as Formaldehyde Equivalents for Stetter Reaction with Enones

(2013) Junmin Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic insights into the triazolylidene-catalysed Stetter and benzoin reactions: role of the N-aryl substituent

(2013) Christopher J. Collett et al.   Chemical Science

Desymmetrization of cyclohexadienones viad-camphor-derived triazolium salt catalyzed intramolecular Stetter reaction

(2012) Min-Qiang Jia et al.   CHEMICAL COMMUNICATIONS

Diastereoselective and Enantioselective Desymmetrization of α-Substituted Cyclohexadienones via Intramolecular Stetter Reaction

(2012) Min-Qiang Jia et al.   JOURNAL OF ORGANIC CHEMISTRY

Efficient Synthesis of γ-Keto Sulfones by NHC-Catalyzed Intermolecular Stetter Reaction

(2012) Anup Bhunia et al.   ORGANIC LETTERS

Total Synthesis of (±)-Marinopyrrole A via Copper-Mediated N-Arylation

(2010) Argyrios A. Kanakis et al.   ORGANIC LETTERS

Enantioselective Protonation of Itaconimides with Thiols and the Rotational Kinetics of the Axially Chiral CN Bond

(2009) Shishi Lin et al.   Chemistry-An Asian Journal

The Metolachlor Herbicide: An Exercise in Today's Stereochemistry

(2009) Albrecht Mannschreck et al.   JOURNAL OF CHEMICAL EDUCATION

Asymmetric Radical and Anionic Cyclizations of Axially Chiral Carbamates†

(2008) David B. Guthrie et al.   ORGANIC LETTERS