4.6 Article

Facile synthesis of ZnO/ZnS heterojunction nanoarrays for enhanced piezo-photocatalytic performance

Journal

MATERIALS LETTERS
Volume 292, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.matlet.2021.129635

Keywords

Nanocomposites; Piezoelectric materials; Energy storage and conversion

Funding

  1. National Key Research and Development Program of China [2017YFA0304203]
  2. National Natural Science Foundation of China [61722507, 61675121, 61705123, 61901249, 62020106014]
  3. PCSIRT [IRT_17R70]
  4. 111 project [D18001]
  5. Innovation Project of Graduate Education in Shanxi [2020SY058]
  6. Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi [2019L0002]
  7. Program for the Outstanding Innovative Teams of Higher Learning Institutions of Shanxi (OIT)
  8. Applied Basic Research Project of Shanxi Province [201801D221004, 201901D211191, 201901D211188]
  9. Shanxi 1331 KSC
  10. Russian Foundation for Basic Research
  11. NSF of China [62011530047, 20-53-53025]

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Constructing heterojunction ZnO/ZnS nanoarrays through hydrothermal method leads to enhanced piezo-photocatalytic performance compared to pure ZnO, with the degradation rate further improved by increasing ultrasonic power. The synergistic effect of piezoelectric effect and heterojunction photocatalysis plays a key role in this enhancement.
Constructing heterojunction is a promising approach to enhance the piezo-photocatalytic performance of ZnO nanostructures. In this study, ZnO/ZnS heterojunction nanoarrays have been synthesized by facile vulcanizing surface of wurtzite ZnO nanorods into blende ZnS nanoparticles through hydrothermal method. Both the synthesized wurtzite ZnO nanorods and blende ZnS nanoparticles are piezoelectric semiconductors with wide band gaps. For degrading methyl blue solution under UV irradiation and ultrasonic sonication, it is found that both the piezocatalytic, photocatalytic and piezo-photocatalytic performances of ZnO/ZnS nanoarrays are much higher than those of pure ZnO. In addition, the piezophotocatalytic degradation rate of ZnO/ZnS nanoarrays can be further increased by improving the ultrasonic power. The mechanism can be attributed to the synergetic effect of piezoelectric effect and heterojunction photocatalysis. (c) 2021 Elsevier B.V. All rights reserved.

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