Intersperse Super P nanoparticles between NH4V3O8 microsheets to increase Li+ diffusion coefficient for lithium-ion battery

Ammonium vanadate (NH4V3O8) materials have attracted considerable attention due to their low cost, high discharge capacity, and simple synthesis process. However, the further application of NH4V3O8 materials as cathode for lithium-ion batteries is hindered by the low electronic conductivity and lithium-ion diffusion coefficient. Herein, intersperse Super P nanoparticles between NH4V3O8 microsheets to increase the Li+ diffusion coefficient of NH4V3O8 electrodes. Compared with pure NH4V3O8, the cycling stability of NH4V3O8/Super P composites improved obviously. At a current density of 15 mA g(-1) after 200 cycles, the reversible capacity of composites (110 mAh g(-1)) is much higher than the pure NH4V3O8 (70 mAh g(-1)). Besides, the composites exhibit excellent rate capability, and the reversible capacity achieves 66 mAh g(-1) at a high current density of 300 mA g(-1). The excellent electrochemical performance is mainly attributed to the addition of Super P carbon black nanoparticles, which increases the conductivity and the Li+ diffusion coefficient.

Automated summary

Interspersing Super P nanoparticles between NH4V3O8 microsheets increases the Li+ diffusion coefficient of the electrode, leading to significantly improved cycling stability and rate capability of the composites. The addition of Super P carbon black nanoparticles enhances conductivity and Li+ diffusion coefficient, contributing to the excellent electrochemical performance.