4.7 Article

Water insoluble and flexible transparent film based on carboxymethyl cellulose

Journal

CARBOHYDRATE POLYMERS
Volume 255, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2020.117353

Keywords

Sodium carboxymethyl cellulose (CMC); Water insoluble films; Freeze-thaw method; Transparent films

Funding

  1. Natural Science Foundation of China [21801171]
  2. Natural Science Foundation of Hebei Province [E2018210125, B2017210173]
  3. Hebei Key Laboratory of Advanced Materials for Transportation Engineering and Environment

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A green protocol for the preparation of renewable, insoluble, and transparent films based on carboxymethyl cellulose (CMC) has been successfully demonstrated, showing flexibility, high light transmittance, high mechanical performance, and good thermal stability. This approach offers a promising route to the fabrication of flexible and transparent films with good waterproof properties.
Preparation of renewable, insoluble, and transparent films is still a major challenge for the application of soft electronics and packing industry. Herein, a green protocol for preparation of such a film based on carboxymethyl cellulose (CMC) is presented, where acid assistant freeze-thaw method was used in combination with drying. We have shown that the resultant films displayed flexibility, high light transmittance (above 90 %), insolubility, high mechanical performances (elastic modulus of 29.6 MPa), and good thermal stability. Moreover, CMC film/filter paper was fabricated, and the waterproof and mechanical properties of which were investigated. This approach offers a promising route to the fabrication of flexible and transparent films with good waterproof properties based on soluble biomass.

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