Advances in supramolecular host-mediated reactivity

Capturing the Monomeric (L)CuH in NHC-Capped Cyclodextrin: Cavity-Controlled Chemoselective Hydrosilylation of α,β-Unsaturated Ketones

(2020) Guangcan Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Front Cover: Chemistry—A European Journal Turns 25 (Chem. Eur. J. 1/2020)

(2020) Haymo Ross   CHEMISTRY-A EUROPEAN JOURNAL

Host–Guest-Induced Electron Transfer Triggers Radical-Cation Catalysis

(2020) Rebecca L. Spicer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Radical Reactions in Cavitands Unveil the Effects of Affinity on Dynamic Supramolecular Systems

(2020) Manuel Petroselli et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Nanovessel-Catalyzed Three-Component Aza-Darzens Reaction

(2020) Stephen M. Bierschenk et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Responsive Host–Guest Chemistry of a Flexible Cage with Naphthalene Walls

(2020) Fei Jia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Four-step access to the sesquiterpene natural product presilphiperfolan-1β-ol and unnatural derivatives via supramolecular catalysis

(2020) Leonidas-Dimitrios Syntrivanis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Interplay of water and a supramolecular capsule for catalysis of reductive elimination reaction from gold

(2020) Valerie Vaissier Welborn et al.   Nature Communications

Enhanced reactivity of twisted amides inside a molecular cage

(2020) Hiroki Takezawa et al.   Nature Chemistry

Chemical reactivity under nanoconfinement

(2020) Angela B. Grommet et al.   Nature Nanotechnology

Cofactor controlled encapsulation of a rhodium hydroformylation catalyst

(2019) Lukas J. Jongkind et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Interplay between Light-Switching and Guest-Binding in Photochromic [Pd2Dithienylethene4] Coordination Cages

(2019) Ru-jin Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ultrafast photoactivation of C─H bonds inside water-soluble nanocages

(2019) Ankita Das et al.   Science Advances

Site-Selective Functionalization of Linear Diterpenoids through U-Shaped Folding in a Confined Artificial Cavity

(2019) Hiroki Takezawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Supramolecular Host-Selective Activation of Iodoarenes by Encapsulated Organometallics

(2019) Trandon A. Bender et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold‐catalyzed Cycloisomerization Reactions within Guanidinium M 12 L 24 Nanospheres: the Effect of Local Concentrations

(2019) Sergio Gonell et al.   ChemCatChem

Demethylenation of Cyclopropanes via Photo-Induced Guest-to-Host Electron Transfer in a M₆L₄ Cage

(2019) William Cullen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rational Redesign of a Regioselective Hydroformylation Catalyst for 3‐Butenoic Acid by Supramolecular Substrate Orientation

(2019) Shao‐Tao Bai et al.   ChemCatChem

Electrostatic Control of Macrocyclization Reactions within Nanospaces

(2019) Kaiya Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Ultimate Stereocontrol in Supramolecular Photochirogenesis. Photocyclodimerization of 2-Anthracenecarboxylate Mediated by Sulfur-Linked β-Cyclodextrin Dimers

(2019) Jiecheng Ji et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Supramolecular Strategy for Selective Catalytic Hydrogenation Independent of Remote Chain Length

(2019) Trandon A. Bender et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Microsolvation and Encapsulation Effects on Supramolecular Catalysis: C–C Reductive Elimination inside [Ga4L6]12– Metallocage

(2019) Gantulga Norjmaa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversal of Regioselectivity during Photodimerization of 2-Anthracenecarboxylic Acid in a Water-Soluble Organic Cavitand

(2019) Xueqin Wei et al.   ORGANIC LETTERS

Sesquiterpene Cyclizations inside the Hexameric Resorcinarene Capsule: Total Synthesis of δ-Selinene and Mechanistic Studies

(2019) Qi Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Supramolecular Fullerene Sponges as Catalytic Masks for Regioselective Functionalization of C60

(2019) Carles Fuertes-Espinosa et al.   Chem

Rationalizing the Activity of an “Artificial Diels-Alderase”: Establishing Efficient and Accurate Protocols for Calculating Supramolecular Catalysis

(2019) Tom A. Young et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Brønsted Acid-Catalyzed Carbonyl-Olefin Metathesis inside a Self-Assembled Supramolecular Host

(2018) Lorenzo Catti et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formation of a Highly Reactive Cobalt Nanocluster Crystal within a Highly Negatively Charged Porous Coordination Cage

(2018) Yu Fang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Control over Electrochemical Water Oxidation Catalysis by Preorganization of Molecular Ruthenium Catalysts in Self-Assembled Nanospheres

(2018) Joost Reek   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Confinement of Metal-N-Heterocyclic Carbene Complexes to Control Reactivity in Catalytic Reactions

(2018) Sylvain Roland et al.   CHEMISTRY-A EUROPEAN JOURNAL

Electrostatics Generated by a Supramolecular Capsule Stabilizes the Transition State for Carbon–Carbon Reductive Elimination from Gold(III) Complex

(2018) Valerie Vaissier Welborn et al.   Journal of Physical Chemistry Letters

Supramolecular Photochirogenesis Driven by Higher-Order Complexation: Enantiodifferentiating Photocyclodimerization of 2-Anthracenecarboxylate to Slipped Cyclodimers via a 2:2 Complex with β-Cyclodextrin

(2018) Xueqin Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Design and Assembly of Chiral Coordination Cages for Asymmetric Sequential Reactions

(2018) Jingjing Jiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High Activity and Efficient Turnover by a Simple, Self-Assembled “Artificial Diels–Alderase”

(2018) Vicente Martí-Centelles et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Deconvoluting the Role of Charge in a Supramolecular Catalyst

(2018) Cynthia M. Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalysis in a Cationic Coordination Cage Using a Cavity-Bound Guest and Surface-Bound Anions: Inhibition, Activation, and Autocatalysis

(2018) William Cullen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tandem Reactivity of a Self-Assembled Cage Catalyst with Endohedral Acid Groups

(2018) Lauren R. Holloway et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photocatalytic Supramolecular Enantiodifferentiating Dimerization of 2-Anthracenecarboxylic Acid through Triplet–Triplet Annihilation

(2018) Ming Rao et al.   ORGANIC LETTERS

Supramolecular Approaches To Control Activity and Selectivity in Hydroformylation Catalysis

(2018) Sandra S. Nurttila et al.   ACS Catalysis

Ultra-Small Face-Centered-Cubic Ru Nanoparticles Confined within a Porous Coordination Cage for Dehydrogenation

(2018) Yu Fang et al.   Chem

Ligand Template Strategies for Catalyst Encapsulation

(2018) Lukas J. Jongkind et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cavitands as containers for α,ω-dienes and chaperones for olefin metathesis

(2018) Julius Rebek Jr. et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cage Encapsulated Gold Nanoparticles as Heterogeneous Photocatalyst for Facile and Selective Reduction of Nitroarenes to Azo Compounds

(2018) Bijnaneswar Mondal et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactions of Folded Molecules in Water

(2018) Yang Yu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Self-Assembled Tetrahedral Hosts as Supramolecular Catalysts

(2018) Cynthia M. Hong et al.   ACCOUNTS OF CHEMICAL RESEARCH

Synthetic Catalysts Inspired by Hydrolytic Enzymes

(2018) Mitchell D. Nothling et al.   ACS Catalysis

Cucurbiturils as Reaction Containers for Photocycloaddition of Olefins

(2017) Mahesh Pattabiraman et al.   ISRAEL JOURNAL OF CHEMISTRY

β-Cyclodextrin-Mediated Enantioselective Photochemical Electrocyclization of 1,3-Dihydro-2H-azepin-2-one

(2017) Ali T. Mansour et al.   JOURNAL OF ORGANIC CHEMISTRY

Terpene Cyclizations inside a Supramolecular Catalyst: Leaving-Group-Controlled Product Selectivity and Mechanistic Studies

(2017) Qi Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iminium Catalysis inside a Self-Assembled Supramolecular Capsule: Scope and Mechanistic Studies

(2017) Thomas M. Bräuer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Permeable Self-Assembled Molecular Containers for Catalyst Isolation Enabling Two-Step Cascade Reactions

(2017) Yoshihiro Ueda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iminium Catalysis inside a Self-Assembled Supramolecular Capsule: Modulation of Enantiomeric Excess

(2016) Thomas M. Bräuer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cavitands as Reaction Vessels and Blocking Groups for Selective Reactions in Water

(2016) Daniele Masseroni et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Advantages of Catalysis in Self-Assembled Molecular Capsules

(2016) Lorenzo Catti et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Developing Concept of Bifunctional Catalysis with Transition Metal N-Heterocyclic Carbene Complexes

(2016) Balasubramaniyam Ramasamy et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Molecular Cage Impregnated Palladium Nanoparticles: Efficient, Additive-Free Heterogeneous Catalysts for Cyanation of Aryl Halides

(2016) Bijnaneswar Mondal et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Scope and Mechanism of Cooperativity at the Intersection of Organometallic and Supramolecular Catalysis

(2016) Mark D. Levin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Urea-Functionalized Self-Assembled Molecular Prism for Heterogeneous Catalysis in Water

(2016) Prodip Howlader et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Macrocyclization of Folded Diamines in Cavitands

(2016) Qixun Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ultrafine Pt Nanoclusters Confined in a Calixarene-Based {Ni24} Coordination Cage for High-Efficient Hydrogen Evolution Reaction

(2016) Shentang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Self-assembled nanospheres with multiple endohedral binding sites pre-organize catalysts and substrates for highly efficient reactions

(2016) Qi-Qiang Wang et al.   Nature Chemistry

Highly efficient catalysis of the Kemp elimination in the cavity of a cubic coordination cage

(2016) William Cullen et al.   Nature Chemistry

Hydration of aromatic alkynes catalyzed by a self-assembled hexameric organic capsule

(2016) Giorgio La Sorella et al.   Catalysis Science & Technology

Intramolecular hydroalkoxylation catalyzed inside a self-assembled cavity of an enzyme-like host structure

(2015) L. Catti et al.   CHEMICAL COMMUNICATIONS

Cucurbituril-Based Molecular Recognition

(2015) Steven J. Barrow et al.   CHEMICAL REVIEWS

Supramolecular Catalysis in Metal–Ligand Cluster Hosts

(2015) Casey J. Brown et al.   CHEMICAL REVIEWS

Transition metal catalysis in confined spaces

(2015) Stefan H. A. M. Leenders et al.   CHEMICAL SOCIETY REVIEWS

Enabling New Modes of Reactivity via Constrictive Binding in a Supramolecular-Assembly-Catalyzed Aza-Prins Cyclization

(2015) David M. Kaphan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Supramolecular Ga4L612– Cage Photosensitizes 1,3-Rearrangement of Encapsulated Guest via Photoinduced Electron Transfer

(2015) Derek M. Dalton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Deep Cavitand Templates Lactam Formation in Water

(2015) Simone Mosca et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Hydroformylation by a Rh-Catalyst Entrapped in a Supramolecular Metallocage

(2015) Cristina García-Simón et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Terpene cyclization catalysed inside a self-assembled cavity

(2015) Q. Zhang et al.   Nature Chemistry

A supramolecular microenvironment strategy for transition metal catalysis

(2015) D. M. Kaphan et al.   SCIENCE

Review: A History of Cyclodextrins

(2014) Grégorio Crini   CHEMICAL REVIEWS

Supramolecular control of selectivity in transition-metal catalysis through substrate preorganization

(2014) Paweł Dydio et al.   Chemical Science

Sponge-like molecular cage for purification of fullerenes

(2014) Cristina García-Simón et al.   Nature Communications

Supramolecular catalysis. Part 2: artificial enzyme mimics

(2013) Matthieu Raynal et al.   CHEMICAL SOCIETY REVIEWS

Hexameric Resorcinarene Capsule is a Brønsted Acid: Investigation and Application to Synthesis and Catalysis

(2013) Qi Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of highly strained terpenes by non-stop tail-to-head polycyclization

(2012) Sergey V. Pronin et al.   Nature Chemistry

Supramolecular ligand–ligand and ligand–substrate interactions for highly selective transition metal catalysis

(2011) Stefano Carboni et al.   DALTON TRANSACTIONS

Cucurbituril chemistry: a tale of supramolecular success

(2011) Eric Masson et al.   RSC Advances

Supramolecular catalysis beyond enzyme mimics

(2010) Jurjen Meeuwissen et al.   Nature Chemistry

Functional Molecular Flasks: New Properties and Reactions within Discrete, Self-Assembled Hosts

(2009) Michito Yoshizawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

In Situ Spectroscopic, Electrochemical, and Theoretical Studies of the Photoinduced Host−Guest Electron Transfer that Precedes Unusual Host-Mediated Alkane Photooxidation

(2009) Yuji Furutani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Unlockable-Relockable Iron Cage by Subcomponent Self-Assembly

(2008) Prasenjit Mal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION