Supramolecular control of selectivity in transition-metal catalysis through substrate preorganization

Room Temperature Ambient Pressure (RTAP)-Hydroformylation in Water Using a Self-Assembling Ligand

(2013) Alexander T. Straub et al.   ADVANCED SYNTHESIS & CATALYSIS

Weak Arene CH⋅⋅⋅O Hydrogen Bonding in Palladium-Catalyzed Arylation and Vinylation of Lactones

(2013) Zhiyan Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen-Bond-Promoted Palladium Catalysis: Allylic Alkylation of Indoles with Unsymmetrical 1,3-Disubstituted Allyl Acetates Using Chiral Bis(sulfoxide) Phosphine Ligands

(2013) Le Du et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Supramolecular Control of Selectivity in Hydroformylation of Vinyl Arenes: Easy Access to Valuable β-Aldehyde Intermediates

(2013) Paweł Dydio et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalysis in Confined Spaces

(2013) Rafael Gramage-Doria et al.   ChemCatChem

Hydrogen-bond mediated regio- and enantioselectivity in a C–H amination reaction catalysed by a supramolecular Rh(ii) complex

(2013) Thorsten Höke et al.   CHEMICAL COMMUNICATIONS

Tandem decarboxylative hydroformylation–hydrogenation reaction of α,β-unsaturated carboxylic acids toward aliphatic alcohols under mild conditions employing a supramolecular catalyst system

(2013) Lisa Diab et al.   CHEMICAL COMMUNICATIONS

Interception and Characterization of Alkyl and Acyl Complexes in Rhodium-Catalyzed Hydroformylation of Styrene

(2013) Eleanor R. Nelsen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Intermolecular [2+2] Photocycloadditions of Isoquinolone Mediated by a Chiral Hydrogen-Bonding Template

(2013) Susannah C. Coote et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Precise Supramolecular Control of Selectivity in the Rh-Catalyzed Hydroformylation of Terminal and Internal Alkenes

(2013) Paweł Dydio et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Substrate Distortion Contributes to the Catalysis of Orotidine 5′-Monophosphate Decarboxylase

(2013) Masahiro Fujihashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sub-ångström-resolution crystallography reveals physical distortions that enhance reactivity of a covalent enzymatic intermediate

(2013) Stefan Lüdtke et al.   Nature Chemistry

Rhodium-catalyzed hydroformylation of alkynes employing a self-assembling ligand system

(2013) Vladislav Agabekov et al.   Chemical Science

Selective Isomerization–Hydroformylation Sequence: A Strategy to Valuable α-Methyl-Branched Aldehydes from Terminal Olefins

(2013) Paweł Dydio et al.   ACS Catalysis

More Chemistry in Small Spaces

(2012) Dariush Ajami et al.   ACCOUNTS OF CHEMICAL RESEARCH

Tandem Rhodium-Catalyzed Hydroformylation-Hydrogenation of Alkenes by Employing a Cooperative Ligand System

(2012) Daniela Fuchs et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Insights into a Supramolecular Self-Assembling Catalyst System: Evidence for Hydrogen Bonding during Rhodium-Catalyzed Hydroformylation

(2012) Urs Gellrich et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Confined Nanospaces in Metallocages: Guest Molecules, Weakly Encapsulated Anions, and Catalyst Sequestration

(2012) Hani Amouri et al.   CHEMICAL REVIEWS

Metal–Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal–Organic Materials

(2012) Timothy R. Cook et al.   CHEMICAL REVIEWS

Artificial enzymes based on supramolecular scaffolds

(2012) Zeyuan Dong et al.   CHEMICAL SOCIETY REVIEWS

Building on architectural principles for three-dimensional metallosupramolecular construction

(2012) Maarten M. J. Smulders et al.   CHEMICAL SOCIETY REVIEWS

A Library Approach to the Development of BenzaPhos: Highly Efficient Chiral Supramolecular Ligands for Asymmetric Hydrogenation

(2012) Luca Pignataro et al.   CHEMISTRY-A EUROPEAN JOURNAL

From Containers to Catalysts: Supramolecular Catalysis within Cucurbiturils

(2012) Barry C. Pemberton et al.   CHEMISTRY-A EUROPEAN JOURNAL

Supramolecular Self-Assembled Ligands in Asymmetric Transition Metal Catalysis

(2012) Rosalba Bellini et al.   ISRAEL JOURNAL OF CHEMISTRY

Enantio- and Regioselective Epoxidation of Olefinic Double Bonds in Quinolones, Pyridones, and Amides Catalyzed by a Ruthenium Porphyrin Catalyst with a Hydrogen Bonding Site

(2012) Philipp Fackler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of remote meta-C–H bonds assisted by an end-on template

(2012) Dasheng Leow et al.   NATURE

A New Direction in Enantioselective Catalysis: Scaffolding Ligands in Olefin Hydroformylation

(2011) Charles S. Yeung et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Removable Directing Groups in Organic Synthesis and Catalysis

(2011) Géraldine Rousseau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Remote Supramolecular Control of Catalyst Selectivity in the Hydroformylation of Alkenes

(2011) Paweł Dydio et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen bond induced enantioselectivity in Mn(salen)-catalysed sulfoxidaton reactions

(2011) Felix Voss et al.   CHEMICAL COMMUNICATIONS

Preface for the themed issue of Chemical Society Reviews

(2011) Matthias Beller   CHEMICAL SOCIETY REVIEWS

Formation of Quaternary Carbon Centers by Highly Regioselective Hydroformylation with Catalytic Amounts of a Reversibly Bound Directing Group

(2011) Yusuke Ueki et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Asymmetric Hydrogenation of Olefins with PhthalaPhos, a New Class of Chiral Supramolecular Ligands

(2011) Luca Pignataro et al.   CHEMISTRY-A EUROPEAN JOURNAL

Diels-Alder Reactions of Inert Aromatic Compounds within a Self-Assembled Coordination Cage

(2011) Shinnosuke Horiuchi et al.   Chemistry-An Asian Journal

Supramolecular ligand–ligand and ligand–substrate interactions for highly selective transition metal catalysis

(2011) Stefano Carboni et al.   DALTON TRANSACTIONS

Enantioselective Hydroformylation of Aniline Derivatives

(2011) Candice L. Joe et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Intramolecular [2 + 2]-Photocycloaddition Reactions of 4-Substituted Quinolones Catalyzed by a Chiral Sensitizer with a Hydrogen-Bonding Motif

(2011) Christiane Müller et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

“Cofactor”-Controlled Enantioselective Catalysis

(2011) Paweł Dydio et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Crystalline molecular flasks

(2011) Yasuhide Inokuma et al.   Nature Chemistry

Diastereoselective Hydroformylation of 2,5-Cyclohexadienyl-1-carbinols with Catalytic Amounts of a Reversibly Bound Directing Group

(2011) Ippei Usui et al.   ORGANIC LETTERS

Regioselective Hydroformylation of Allylic Alcohols

(2011) Thomas E. Lightburn et al.   ORGANIC LETTERS

Enzyme Mimics Based Upon Supramolecular Coordination Chemistry

(2010) Michael J. Wiester et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Development of Unique Chemical Phenomena within Nanometer-Sized, Self-Assembled Coordination Hosts

(2010) Michito Yoshizawa et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Water-soluble, self-assembling container molecules: an update

(2010) Zachary Laughrey et al.   CHEMICAL SOCIETY REVIEWS

Transition-State Stabilization by a Secondary Substrate-Ligand Interaction: A New Design Principle for Highly Efficient Transition-Metal Catalysis

(2010) Tomáš Šmejkal et al.   CHEMISTRY-A EUROPEAN JOURNAL

Naphthalene Diels−Alder in a Self-Assembled Molecular Flask

(2010) Takashi Murase et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Quaternary Carbon Centers via Hydroformylation

(2010) X. Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

‘Carbene Radicals’ in CoII(por)-Catalyzed Olefin Cyclopropanation

(2010) Wojciech I. Dzik et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Application of a Chiral Scaffolding Ligand in Catalytic Enantioselective Hydroformylation

(2010) Amanda D. Worthy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen-Bond-Mediated Enantio- and Regioselectivity in a Ru-Catalyzed Epoxidation Reaction

(2010) Philipp Fackler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand Self-Assembling through Complementary Hydrogen-Bonding in the Coordination Sphere of a Transition Metal Center: The 6-Diphenylphosphanylpyridin-2(1H)-one System

(2010) Urs Gellrich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Supramolecular catalysis beyond enzyme mimics

(2010) Jurjen Meeuwissen et al.   Nature Chemistry

Multifunctional ligands in transition metal catalysis

(2010) Robert H. Crabtree   NEW JOURNAL OF CHEMISTRY

Reactivity modulation in container molecules

(2010) Boris Breiner et al.   Chemical Science

Proton-Mediated Chemistry and Catalysis in a Self-Assembled Supramolecular Host

(2009) Michael D. Pluth et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium- and Copper-Catalyzed Arylation of Carbon−Hydrogen Bonds

(2009) Olafs Daugulis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Light-Driven Enantioselective Organocatalysis

(2009) Christiane Müller et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Remote Control of Regio- and Diastereoselectivity in the Hydroformylation of Bishomoallylic Alcohols with Catalytic Amounts of a Reversibly Bound Directing Group

(2009) Christian U. Grünanger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Singly Hydrogen Bonded Supramolecular Ligands for Highly Selective Rhodium-Catalyzed Hydrogenation Reactions

(2009) Pierre-Alain R. Breuil et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Functional Molecular Flasks: New Properties and Reactions within Discrete, Self-Assembled Hosts

(2009) Michito Yoshizawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Supramolecular Catalyst for Aldehyde Hydrogenation and Tandem Hydroformylation-Hydrogenation

(2009) Lisa Diab et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective Hydroformylation of Sulfonamides using a Scaffolding Ligand

(2009) Amanda D. Worthy et al.   ORGANIC LETTERS

Ligand-Enabled Reactivity and Selectivity in a Synthetically Versatile Aryl C-H Olefination

(2009) D.-H. Wang et al.   SCIENCE

Branched-Regioselective Hydroformylation with Catalytic Amounts of a Reversibly Bound Directing Group

(2008) Christian U. Grünanger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Supramolecular Catalyst for the Decarboxylative Hydroformylation of α,β-Unsaturated Carboxylic Acids

(2008) Tomáš Šmejkal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Libraries of Bidentate Phosphorus Ligands; Synthesis Strategies and Application in Catalysis

(2008) P. Elsbeth Goudriaan et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Manganese Catalysts with Molecular Recognition Functionality for Selective Alkene Epoxidation

(2008) Jonathan F. Hull et al.   INORGANIC CHEMISTRY

Supramolecular Catalysis of Orthoformate Hydrolysis in Basic Solution: An Enzyme-Like Mechanism

(2008) Michael D. Pluth et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Asymmetric Cyclopropanation with Diazosulfones: Rigidification and Polarization of Ligand Chiral Environment via Hydrogen Bonding and Cyclization

(2008) Shifa Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Scaffolding Ligands: An Efficient Strategy for Directing Reactions

(2008) Thomas E. Lightburn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Finding the Proton in a Key Intermediate ofanti-Markovnikov Alkyne Hydration by a Bifunctional Catalyst

(2008) Douglas B. Grotjahn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Allylation ofN-Heterocycles with Allylic Alcohols Employing Self-Assembling Palladium Phosphane Catalysts

(2008) Ippei Usui et al.   ORGANIC LETTERS

Highly Regioselective Hydroformylation of Styrene and Its Derivatives Catalyzed by Rh Complex with Tetraphosphorus Ligands

(2008) Shichao Yu et al.   ORGANIC LETTERS

BIOCHEMISTRY: How Enzymes Work

(2008) D. Ringe et al.   SCIENCE

A Supramolecular Catalyst for Regioselective Hydroformylation of Unsaturated Carboxylic Acids

(2007) Tomáš Šmejkal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Molecular recognition in homogeneous transition metal catalysis: a biomimetic strategy for high selectivity

(2007) Siddartha Das et al.   CHEMICAL COMMUNICATIONS

Reactivity within a confined self-assembled nanospace

(2007) Tehila S. Koblenz et al.   CHEMICAL SOCIETY REVIEWS

Hydrogen-Bond Acceptance of Bifunctional Ligands in an Alkyne−Metal π Complex

(2007) Douglas B. Grotjahn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY