Carbones and Carbon Atom as Ligands in Transition Metal Complexes

Solvent-Induced Bond-Bending Isomerism in Hexaphenyl Carbodiphosphorane: Decisive Dispersion Interactions in the Solid State

(2020) Silas Böttger et al.   INORGANIC CHEMISTRY

Cu(I) Complexes of Multidentate N,C,N- and P,C,P-Carbodiphosphorane Ligands and Their Photoluminescence

(2020) Marius Klein et al.   MOLECULES

Geminal Dianions Stabilized by Main Group Elements

(2019) Marie Fustier-Boutignon et al.   CHEMICAL REVIEWS

Synthesis and Characterization of a N,C,N-Carbodiphosphorane Pincer Ligand and Its Complexes

(2019) Marius Klein et al.   ORGANOMETALLICS

Dimerisation of Dipiperidinoacetylene: Convenient Access to Tetraamino‐1,3‐Cyclobutadiene and Tetraamino‐1,2‐Cyclobutadiene Metal Complexes

(2019) Ludwig Hackl et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Experimental and Theoretical Study of the Structures and Properties of [CDPMe -Ni(CO)3 ] and [Ni2 (CO)4 (µ2 -CO)(µ2 -CDPMe )]

(2019) Kimon Flosdorf et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Carbodiphosphorane-based nickel pincer complexes and their (de)protonated analogues: dimerisation, ligand tautomers and proton affinities

(2018) Leon Maser et al.   DALTON TRANSACTIONS

Simple generation of a dirhodium μ-carbido complex via thiocarbonyl reduction

(2018) Harrison J. Barnett et al.   DALTON TRANSACTIONS

Observation of Carbodicarbene Ligand Redox Noninnocence in Highly Oxidized Iron Complexes

(2018) Siu-Chung Chan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dative and electron-sharing bonding in transition metal compounds

(2018) Paul Jerabek et al.   JOURNAL OF COMPUTATIONAL CHEMISTRY

Double dative bond between divalent carbon(0) and uranium

(2018) Wei Su et al.   Nature Communications

Activation of CS2and COS at a Rhodium(I) Germyl Complex: Generation of CS and Carbido Complexes

(2017) Theresia Ahrens et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Flexibility of the Carbodiphosphorane, (Ph3P)2C: Structural Characterization of a Linear Form

(2017) Patrick J. Quinlivan et al.   INORGANIC CHEMISTRY

Weakening of Carbide–Platinum Bonds as a Probe for Ligand Donor Strengths

(2017) Anders Reinholdt et al.   INORGANIC CHEMISTRY

Gold(I) and Gold(III) complexes of the [CH(dppm)2]+ and C(dppm)2 PCP pincer ligand systems

(2017) Christian Reitsamer et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Carbodicarbenes: Unexpected π-Accepting Ability during Reactivity with Small Molecules

(2017) Wen-Ching Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reductive Ring Opening of a Cyclo-Tri(phosphonio)methanide Dication to a Phosphanylcarbodiphosphorane: In Situ UV-Vis Spectroelectrochemistry and Gold Coordination

(2017) Sivathmeehan Yogendra et al.   ORGANOMETALLICS

Ruthenium Olefin Metathesis Catalysts Featuring a Labile Carbodicarbene Ligand

(2017) Allegra L. Liberman-Martin et al.   ORGANOMETALLICS

Invisible Chelating Effect Exhibited between Carbodicarbene and Phosphine through π–π Interaction and Implication in the Cross-Coupling Reaction

(2017) Wei-Chih Shih et al.   ORGANOMETALLICS

Carbon(0)-Bridged Pt/Ag Dinuclear and Tetranuclear Complexes Based on a Cyclometalated Pincer Carbodiphosphorane Platform

(2017) Kazuyuki Kubo et al.   ORGANOMETALLICS

Energy decomposition analysis

(2017) Lili Zhao et al.   Wiley Interdisciplinary Reviews-Computational Molecular Science

Synthesis of a Carbodicyclopropenylidene: A Carbodicarbene based Solely on Carbon

(2016) Conor Pranckevicius et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Delivering carbide ligands to sulfide-rich clusters

(2016) Anders Reinholdt et al.   CHEMICAL COMMUNICATIONS

Donor–acceptor bonding in novel low-coordinated compounds of boron and group-14 atoms C–Sn

(2016) Gernot Frenking et al.   CHEMICAL SOCIETY REVIEWS

Three and four coordinate Fe carbodiphosphorane complexes

(2016) Conor Pranckevicius et al.   DALTON TRANSACTIONS

Mechanism of Molybdenum-Mediated Carbon Monoxide Deoxygenation and Coupling: Mono- and Dicarbyne Complexes Precede C–O Bond Cleavage and C–C Bond Formation

(2016) Joshua A. Buss et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Syntheses and Structural Characterization of Mono-, Di-, and Tetranuclear Silver Carbone Complexes

(2016) Tomohito Morosaki et al.   ORGANOMETALLICS

Expanding the Ligand Framework Diversity of Carbodicarbenes and Direct Detection of Boron Activation in the Methylation of Amines with CO2

(2015) Wen-Ching Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Remarkable reactivity of a rhodium(i) boryl complex towards CO2 and CS2: isolation of a carbido complex

(2015) Sabrina I. Kalläne et al.   CHEMICAL COMMUNICATIONS

Synthesis, Structure, and Reactivities of Iminosulfane- and Phosphane-Stabilized Carbones Exhibiting Four-Electron Donor Ability

(2015) Tomohito Morosaki et al.   CHEMISTRY-A EUROPEAN JOURNAL

Addition compounds between carbones, CL2, and main group Lewis acids: A new glance at old and new compounds

(2015) Wolfgang Petz   COORDINATION CHEMISTRY REVIEWS

Cyclic Bent Allene Hydrido-Carbonyl Complexes of Ruthenium: Highly Active Catalysts for Hydrogenation of Olefins

(2015) Conor Pranckevicius et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lewis Acid Activation of Carbodicarbene Catalysts for Rh-Catalyzed Hydroarylation of Dienes

(2015) Courtney C. Roberts et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand Sphere Conversions in Terminal Carbide Complexes

(2015) Thorbjørn J. Morsing et al.   ORGANOMETALLICS

Carbide complexes as π-acceptor ligands

(2015) Anders Reinholdt et al.   Chemical Science

Syntheses, Structures, and Reactivities of Two Chalcogen-Stabilized Carbones

(2014) Tomohito Morosaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Isolation of an Acyclic Tridentate Bis(pyridine)carbodicarbene and Studies on Its Structural Implications and Reactivities

(2014) Yu-Chen Hsu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dative Bonds in Main-Group Compounds: A Case for More Arrows!

(2014) Gernot Frenking   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

New bonding modes of carbon and heavier group 14 atoms Si–Pb

(2014) Gernot Frenking et al.   CHEMICAL SOCIETY REVIEWS

Intermolecular Hydroamination of 1,3-Dienes Catalyzed by Bis(phosphine)carbodicarbene–Rhodium Complexes

(2014) Matthew J. Goldfogel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[(μ-C){Re(CO)2(η-C5H5)}2]: A Surprisingly Simple Bimetallic Carbido Complex

(2013) Rowan D. Young et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral heterobimetallic complexes of carbodiphosphoranes and phosphinidene–carbene adducts

(2013) Manuel Alcarazo et al.   CHEMICAL COMMUNICATIONS

Carbodicarbenes, Carbon(0) Derivatives, Can Dimerize

(2013) David A. Ruiz et al.   Chemistry-An Asian Journal

A Golden Ring: Molecular Gold Carbido Complexes

(2013) Elliot S. Borren et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthetic Modification of Acyclic Bent Allenes (Carbodicarbenes) and Further Studies on Their Structural Implications and Reactivities

(2013) Wen-Ching Chen et al.   ORGANOMETALLICS

Novel access to carbodiphosphoranes in the coordination sphere of group 10 metals: template synthesis and protonation of PCP pincer carbodiphosphorane complexes of C(dppm)2

(2012) Christian Reitsamer et al.   DALTON TRANSACTIONS

Heterodinuclear Bridging Carbido and Phosphoniocarbyne Complexes

(2012) Anthony F. Hill et al.   ORGANOMETALLICS

Coordination complexes of TiX4 (X=F, Cl) with a bulky N-heterocyclic carbene: Syntheses, characterization and molecular structures

(2012) Adinarayana Doddi et al.   POLYHEDRON

Recent advances in the chemistry of ruthenium carbido complexes

(2011) Shin Takemoto et al.   COORDINATION CHEMISTRY REVIEWS

Reaction of C(PPh3)2 with MI2 Compounds (M = Zn, Cd) - Formation and Crystal Structures of [I2Zn{C(PPh3)2}], [(I2Cd{C(PPh3)2})2] and the Salt-Like Compounds (HC{PPh3}2)[MI3(THF)] and (HC{PPh3}2)2[ZnI4]

(2011) Wolfgang Petz et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Syntheses and Crystal Structures of [Hg{C(PPh3)2}2][Hg2I6] and [Cu{C(PPh3)2}2]I and Comparative Theoretical Study of Carbene Complexes [M(NHC)2] with Carbone Complexes [M{C(PH3)2}2] (M = Cu+, Ag+, Au+, Zn2+, Cd2+, Hg2+)

(2011) Wolfgang Petz et al.   ORGANOMETALLICS

New platinum complexes with carbodiphosphorane as pincer ligand via ortho phenyl metallation

(2011) Wolfgang Petz et al.   POLYHEDRON

Synthesis and Ligand Properties of a Persistent, All-Carbon Four-Membered-Ring Allene

(2009) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and structure of a bis-N-heterocyclic carbene complex of uranium tetrachloride exhibiting short Cl⋯Ccarbene contacts

(2009) Benedict M. Gardner et al.   DALTON TRANSACTIONS

Syntheses and crystal structures of linear coordinated complexes of Ag+ with the ligands C(PPh3)2 and (HC{PPh3}2)+

(2009) Wolfgang Petz et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Coordination chemistry at carbon

(2009) Manuel Alcarazo et al.   Nature Chemistry

Iridium−Molybdenum Carbido Complex via C−Se Activation of a Selenocarbonyl Ligand: (μ-Se2)[Ir2{C≡Mo(CO)2(Tp*)}2(CO)2(PPh3)2] (Tp* = hydrotris(dimethylpyrazolyl)borate)

(2009) Ian A. Cade et al.   ORGANOMETALLICS

A Bis-Carbyne (Ethanediylidyne) Complex via the Catalytic Demercuration of a Mercury Bis(carbido) Complex

(2009) Annie L. Colebatch et al.   ORGANOMETALLICS

Divalent carbon(0) compounds

(2009) Gernot Frenking et al.   PURE AND APPLIED CHEMISTRY

Coordination Chemistry of Ene-1,1-diamines and a Prototype “Carbodicarbene”

(2008) Alois Fürstner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of an Extremely Bent Acyclic Allene (A “Carbodicarbene”): A Strong Donor Ligand

(2008) C. Adam Dyker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Divalent Carbon(0) Chemistry, Part 1: Parent Compounds

(2008) Ralf Tonner et al.   CHEMISTRY-A EUROPEAN JOURNAL

First and Second Proton Affinities of Carbon Bases

(2008) Ralf Tonner et al.   CHEMPHYSCHEM

Facile Generation of Lithiocarbyne Complexes: [M(CLi)(CO)2{HB(pzMe2)3}] (M = Mo, W; pz = Pyrazol-1-yl)

(2008) Richard L. Cordiner et al.   ORGANOMETALLICS

First Cyclic Carbodiphosphoranes of Copper(I) and Gold(I) and Their Application in the Catalytic Cleavage of X−H Bonds (X = N and O)

(2008) Rosa Corberán et al.   ORGANOMETALLICS

Carbid-verbrückte Komplexe [HB(pz)3(OC)2Mo≡C-Pt(PPh3)2Br], [(TPP)Fe≡C-M(CO)4-M(CO)5] (M = Mn, Re), [(TPP)Fe=C=Cr(CO)5] und (TPP)Fe=C=Fe(CO)4] (pz = 3,5-dimethylpyrazol-1-yl; TPP = Tetra-phenylporphyrinat) aus Halogeno-Carbin und -Carben-Komplexen

(2008) Wolfgang Knauer et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE