Donor–acceptor bonding in novel low-coordinated compounds of boron and group-14 atoms C–Sn

The [B3 (NN)3 ]+ and [B3 (CO)3 ]+ Complexes Featuring the Smallest π-Aromatic Species B3 +

(2016) Jiaye Jin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Triatomic Silicon(0) Cluster Stabilized by a Cyclic Alkyl(amino) Carbene

(2016) Kartik Chandra Mondal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formation and Characterization of the Boron Dicarbonyl Complex [B(CO)2]−

(2015) Qingnan Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Triboracyclopropenyl Dianion: The Lightest Possible Main-Group-Element Hückel π Aromatic

(2015) Thomas Kupfer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Expanding the Ligand Framework Diversity of Carbodicarbenes and Direct Detection of Boron Activation in the Methylation of Amines with CO2

(2015) Wen-Ching Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Synthesis of B2(SIDip)2and its Reactivity Between the Diboracumulenic and Diborynic Extremes

(2015) Julian Böhnke et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Fate of NHC-Stabilized Dicarbon

(2015) Dayne C. Georgiou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Spectroscopic Distinction of Different Carbon Bases: An Insight from Theory

(2015) Ankur Kanti Guha et al.   JOURNAL OF ORGANIC CHEMISTRY

Bonding situation in silicon complexes [(L) 2 (Si 2 )] and [(L) 2 (Si)] with NHC and cAAC ligands

(2015) Nicole Holzmann et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Cyclic Bent Allene Hydrido-Carbonyl Complexes of Ruthenium: Highly Active Catalysts for Hydrogenation of Olefins

(2015) Conor Pranckevicius et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lewis Acid Activation of Carbodicarbene Catalysts for Rh-Catalyzed Hydroarylation of Dienes

(2015) Courtney C. Roberts et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental Assessment of the Strengths of B–B Triple Bonds

(2015) Julian Böhnke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multiple complexation of CO and related ligands to a main-group element

(2015) Holger Braunschweig et al.   NATURE

The boron–boron triple bond in NHC→BB←NHC

(2015) Nicole Holzmann et al.   Chemical Science

Spying on the boron–boron triple bond using spin–spin coupling measured from 11B solid-state NMR spectroscopy

(2015) Frédéric A. Perras et al.   Chemical Science

The boron–boron triple bond? A thermodynamic and force field based interpretation of the N-heterocyclic carbene (NHC) stabilization procedure

(2015) R. Köppe et al.   Chemical Science

Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise

(2014) Michèle Soleilhavoup et al.   ACCOUNTS OF CHEMICAL RESEARCH

Carbon Monoxide Bonding With BeO and BeCO3: Surprisingly High CO Stretching Frequency of OCBeCO3

(2014) Mohua Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Isolation of an Acyclic Tridentate Bis(pyridine)carbodicarbene and Studies on Its Structural Implications and Reactivities

(2014) Yu-Chen Hsu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C4Cumulene and the Corresponding Air-Stable Radical Cation and Dication

(2014) Yan Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Experimental Charge Density Study of a Silylone

(2014) Benedikt Niepötter et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isolation of a Bis(oxazol-2-ylidene)-Phenylborylene Adduct and its Reactivity as a Boron-Centered Nucleophile

(2014) Lingbing Kong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diborabutatriene: An Electron-Deficient Cumulene

(2014) Julian Böhnke et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene—Main-Group Chemistry: A Rapidly Evolving Field

(2014) Yuzhong Wang et al.   INORGANIC CHEMISTRY

The Elusive Three-Coordinate Dicationic Hydrido Boron Complex

(2014) Wen-Ching Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermolecular Hydroamination of 1,3-Dienes Catalyzed by Bis(phosphine)carbodicarbene–Rhodium Complexes

(2014) Matthew J. Goldfogel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An overview of N-heterocyclic carbenes

(2014) Matthew N. Hopkinson et al.   NATURE

Singlet carbenes as mimics for transition metals: synthesis of an air stable organic mixed valence compound [M2(C2)+˙; M = cyclic(alkyl)(amino)carbene]

(2014) Liqun Jin et al.   Organic Chemistry Frontiers

Dinitrogen as Double Lewis Acid: Structure and Bonding of Triphenylphosphinazine N2(PPh3)2

(2013) Nicole Holzmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boron-Boron Multiple Bond in [B(NHC)]2: Towards Stable and Aromatic [B(NHC)]nRings

(2013) Truong Ba Tai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Cyclic Silylone (“Siladicarbene”) with an Electron-Rich Silicon(0) Atom

(2013) Yun Xiong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Stable Singlet Biradicaloid Siladicarbene: (L:)2Si

(2013) Kartik Chandra Mondal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Quantifying and understanding the electronic properties of N-heterocyclic carbenes

(2013) David J. Nelson et al.   CHEMICAL SOCIETY REVIEWS

Comparative Study of Phosphine and N-Heterocyclic Carbene Stabilized Group 13 Adducts [L(EH3)] and [L2(E2Hn)]

(2013) Nicole Holzmann et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Advances in the Field of Main-Group Mono- and Diatomic “Allotropes” Stabilised by Neutral Ligands

(2013) David J. D. Wilson et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and Structure of Carbene-Stabilized N-Centered Cations [L2N]+, [L2NR]2+, [LNR3]2+, and [L3N]3+

(2013) Ágnes Kozma et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stabilization of Si(0) and Ge(0) compounds by different silylenes and germylenes: a density functional and molecular electrostatic study

(2013) Satyajit Sarmah et al.   DALTON TRANSACTIONS

A Cyclic Germadicarbene (“Germylone”) from Germyliumylidene

(2013) Yun Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthetic Modification of Acyclic Bent Allenes (Carbodicarbenes) and Further Studies on Their Structural Implications and Reactivities

(2013) Wen-Ching Chen et al.   ORGANOMETALLICS

Tris(alkyne) and Bis(alkyne) Complexes of Coinage Metals: Synthesis and Characterization of (cyclooctyne)3M+ (M = Cu, Ag) and (cyclooctyne)2Au+ and Coinage Metal (M = Cu, Ag, Au) Family Group Trends

(2013) Animesh Das et al.   ORGANOMETALLICS

Exploiting the Twofold Donor Ability of Carbodiphosphoranes: Theoretical Studies of [(PPh3)2C→EH2]q(Eq=Be, B+, C2+, N3+, O4+) and Synthesis of the Dication [(Ph3P)2CCH2]2+

(2013) Mehmet Ali Celik et al.   ChemPlusChem

Multiple-Charged P1-Centered Cations: Perspectives in Synthesis

(2012) Kai-Oliver Feldmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis Base Stabilized Dicarbon: Predictions from Theory

(2012) Jason L. Dutton et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An N-heterocyclic carbene adduct of diatomic tin, :SnSn:

(2012) Cameron Jones et al.   CHEMICAL COMMUNICATIONS

Do Carbenes Have a “Hidden” Carbon(0) Character? Revisiting the Electronic Structure of 2,2′-Bipyridyl Carbene

(2012) Ankur Kanti Guha et al.   CHEMISTRY-A EUROPEAN JOURNAL

Borylene Complexes (BH)L2 and Nitrogen Cation Complexes (N+)L2: Isoelectronic Homologues of Carbones CL2

(2012) Mehmet Ali Celik et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stabilization of cyclic and acyclic carbon(0) compounds by differential coordination of heterocyclic carbenes: a theoretical assessment

(2012) Ashwini K. Phukan et al.   DALTON TRANSACTIONS

Are N-Heterocyclic Carbenes “Better” Ligands than Phosphines in Main Group Chemistry? A Theoretical Case Study of Ligand-Stabilized E2 Molecules, L-E-E-L (L = NHC, phosphine; E = C, Si, Ge, Sn, Pb, N, P, As, Sb, Bi)

(2012) David J. D. Wilson et al.   INORGANIC CHEMISTRY

Ambient-Temperature Isolation of a Compound with a Boron-Boron Triple Bond

(2012) H. Braunschweig et al.   SCIENCE

A Boron-Boron Triple Bond

(2012) G. Frenking et al.   SCIENCE

Synthesis, Structure, and Reactivity of a Dihydrido Borenium Cation

(2011) Blanca Inés et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthetic Routes to N-Heterocyclic Carbene Precursors

(2011) Laure Benhamou et al.   CHEMICAL REVIEWS

Structures and Stabilities of Group 13 Adducts [(NHC)(EX3)] and [(NHC)2(E2Xn)] (E=B to In; X=H, Cl; n=4, 2, 0; NHC=N-Heterocyclic Carbene) and the Search for Hydrogen Storage Systems: A Theoretical Study

(2011) Nicole Holzmann et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent developments in the synthesis and isolation of p-block centered polycations

(2011) Jason L. Dutton et al.   COORDINATION CHEMISTRY REVIEWS

Carbene-stabilized main group diatomic allotropes

(2011) Yuzhong Wang et al.   DALTON TRANSACTIONS

Carbene Stabilization of Highly Reactive Main-Group Molecules

(2011) Yuzhong Wang et al.   INORGANIC CHEMISTRY

Synthesis and Characterization of a Neutral Tricoordinate Organoboron Isoelectronic with Amines

(2011) R. Kinjo et al.   SCIENCE

Divalent Pb(0) compounds

(2011) Nozomi Takagi et al.   THEORETICAL CHEMISTRY ACCOUNTS

Synthesis and Coordination Properties of Nitrogen(I)-Based Ligands

(2010) Hans Bruns et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Measure of All Rings-N-Heterocyclic Carbenes

(2010) Thomas Dröge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From Limestone to Catalysis: Application of Calcium Compounds as Homogeneous Catalysts

(2010) Sjoerd Harder   CHEMICAL REVIEWS

Carbodicarbenes and Related Divalent Carbon(0) Compounds

(2010) Susanne Klein et al.   CHEMISTRY-A EUROPEAN JOURNAL

Geminal dianions stabilized by phosphonium substituents

(2010) Sjoerd Harder   COORDINATION CHEMISTRY REVIEWS

N-Heterocyclic Carbene Stabilized Digermanium(0)

(2009) Anastas Sidiropoulos et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Molecular Double-Bond Covalent Radii for Elements Li–E112

(2009) Pekka Pyykkö et al.   CHEMISTRY-A EUROPEAN JOURNAL

Divalent Silicon(0) Compounds

(2009) Nozomi Takagi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Divalent E(0) Compounds (E=Si-Sn)

(2009) Nozomi Takagi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carbodiphosphorane C(PPh3)2as a Single and Twofold Lewis Base with Boranes: Synthesis, Crystal Structures and Theoretical Studies on [H3B{C(PPh3)2}] and [{(μ-H)H4B2}{C(PPh3)2}]+

(2009) Wolfgang Petz et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A Combined Charge and Energy Decomposition Scheme for Bond Analysis

(2009) Mariusz P. Mitoraj et al.   Journal of Chemical Theory and Computation

Molecules with All Triple Bonds: OCBBCO, N2BBN2, and [OBBBBO]2−†

(2009) Lucas C. Ducati et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Exocyclic Delocalization at the Expense of Aromaticity in 3,5-bis(π-Donor) Substituted Pyrazolium Ions and Corresponding Cyclic Bent Allenes†

(2009) Israel Fernández et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Coordination chemistry at carbon

(2009) Manuel Alcarazo et al.   Nature Chemistry

Divalent carbon(0) compounds

(2009) Gernot Frenking et al.   PURE AND APPLIED CHEMISTRY

Coordination Chemistry of Ene-1,1-diamines and a Prototype “Carbodicarbene”

(2008) Alois Fürstner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of an Extremely Bent Acyclic Allene (A “Carbodicarbene”): A Strong Donor Ligand

(2008) C. Adam Dyker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Divalent Carbon(0) Chemistry, Part 1: Parent Compounds

(2008) Ralf Tonner et al.   CHEMISTRY-A EUROPEAN JOURNAL

Divalent Carbon(0) Chemistry, Part 2: Protonation and Complexes with Main Group and Transition Metal Lewis Acids

(2008) Ralf Tonner et al.   CHEMISTRY-A EUROPEAN JOURNAL

First and Second Proton Affinities of Carbon Bases

(2008) Ralf Tonner et al.   CHEMPHYSCHEM

Bond Orbitals from Chemical Valence Theory

(2008) Artur Michalak et al.   JOURNAL OF PHYSICAL CHEMISTRY A

B2(BO)22-Diboronyl Diborene:  A Linear Molecule with a Triple Boron−Boron Bond

(2008) Si-Dian Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Stable Silicon(0) Compound with a Si=Si Double Bond

(2008) Y. Wang et al.   SCIENCE

catena-Phosphorus Cations

(2007) C. Adam Dyker et al.   Chemistry-An Asian Journal