Recent advances in the rare-earth metal triflates-catalyzed organic reactions

Catalytic enantioselective oxidative coupling of saturated ethers with carboxylic acid derivatives

(2019) Gang Wang et al.   Nature Communications

Enantioselective Synthesis of 4-Hydroxy-dihydrocoumarins via Catalytic Ring Opening/Cycloaddition of Cyclobutenones

(2019) Hang Zhang et al.   ORGANIC LETTERS

Iridium-Catalyzed Enantioselective Allylation of Aryl Enamides and Enecarbamates

(2019) Bei-Bei Yue et al.   ORGANIC LETTERS

A COMPUTATIONAL STUDY OF MODEL PARENT SYSTEMS AND REPORTED AZA-(ISO)NAZAROV / AZA-(ISO)PIANCATELLI ELECTROCYCLIC REACTIONS

(2019) Adan B. González-Pérez et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Mechanism study on asymmetric Michael addition reaction between alkynone and α-angelica lactone catalyzed by chiral N, N'-dioxide-Sc(III) complex

(2019) Yini Zuo et al.   CATALYSIS TODAY

Continuous-Flow Electrosynthesis of Benzofused S-Heterocycles by Dehydrogenative C-S Cross-Coupling

(2019) Chong Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bimetallic Catalytic Asymmetric Tandem Reaction of β-Alkynyl Ketones to Synthesize 6,6-Spiroketals

(2019) Shulin Ge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diversified Cycloisomerization/Diels-Alder Reactions of 1,6-Enynes through Bimetallic Relay Asymmetric Catalysis

(2019) Haifeng Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

(3+3)-Annulation of Carbonyl Ylides with Donor-Acceptor Cyclopropanes: Synergistic Dirhodium(II) and Lewis Acid Catalysis

(2019) Martin Petzold et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral N,N’‐Dioxide/Tm(OTf)3 Complex‐Catalyzed Asymmetric Bisvinylogous Mannich Reaction of Silyl Ketene Acetal with Aldimines

(2019) Sijia Zou et al.   ADVANCED SYNTHESIS & CATALYSIS

Iodine‐Mediated Synthesis of Methylthio‐Substituted Catechols from Cyclohexanones

(2019) Yue‐Hua Wu et al.   ADVANCED SYNTHESIS & CATALYSIS

One-Pot Synthesis of Cycloocta[b]indole through Formal [5+3] Cycloaddition Using Donor-Acceptor Cyclopropanes

(2019) Akito Okabe et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Cascade [1,5]-Hydride Transfer/Cyclization for Synthesis of [3,4]-Fused Oxindoles

(2019) Shuai Zhu et al.   JOURNAL OF ORGANIC CHEMISTRY

Rh(I)/Sc(OTf)3-co-catalyzed Michael addition of ammonium ylide to (E)-1,4-enediones: synthesis of functionalized 1,4-diketones

(2019) Qinghua Wei et al.   MOLECULAR DIVERSITY

A Domino Aza-Piancatelli Rearrangement/Intramolecular Diels–Alder Reaction: Stereoselective Synthesis of Octahydro-1H-cyclopenta[cd]isoindole

(2019) Shaik Gouse et al.   ORGANIC LETTERS

Asymmetric Synthesis of P-Stereogenic Compounds via Thulium(III)-Catalyzed Desymmetrization of Dialkynylphosphine Oxides

(2019) Yu Zhang et al.   ACS Catalysis

The Reaction of Donor‐Acceptor Cyclopropanes with 4,7‐Dihydroindole: A New Protocol for the Synthesis of Divergent C2‐Alkylated Indoles

(2019) Haydar Kilic et al.   ChemistrySelect

Carbonylation of C−N Bonds in Tertiary Amines Catalyzed by Low-Valent Iron Catalysts

(2019) Tawfiq Nasr Allah et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Arene cis-Dihydrodiols from 2-Pyrones

(2019) Quan Cai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of α,β-Epoxy-γ-lactams through Tandem Darzens/Hemiaminalization Reaction

(2019) Bin Shen et al.   ORGANIC LETTERS

Asymmetric Ring-Opening of Donor−Acceptor Cyclopropanes with Primary Arylamines Catalyzed by a Chiral Heterobimetallic Catalyst

(2019) Weiwei Luo et al.   ACS Catalysis

1-Aryltriazenes in the Suzuki, Heck, and Sonogashira Reactions in Imidazolium-ILs, with [BMIM(SO3 H)][OTf] or Sc(OTf)3 as Promoter, and Pd(OAc)2 or NiCl2 ·glyme as Catalyst

(2019) Suraj M. Sutar et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Rare-Earth Y(OTf)3 Catalyzed Coupling Reaction of Ethers with Azaarenes

(2019) Yue-Hua Wu et al.   ORGANIC LETTERS

Catalytic Three-Component Synthesis of Functionalized Naphtho[2,1-b]oxecines via a Double Bond Cleavage–Rearrangement Cascade

(2019) Cheng-Long Ji et al.   ORGANIC LETTERS

Acid-Assisted Hydrogenation of CO2 to Methanol in a Homogeneous Catalytic Cascade System

(2019) Wan-Yi Chu et al.   ACS Catalysis

Sequencing [4 + 1]-Cycloaddition and Aza-Michael Addition Reactions: A Diastereoselective Cascade for the Rapid Access of Pyrido[2′,1′:2,3]/Thiazolo[2′,3′:2,3]imidazo[1,5-a]quinolone Scaffolds as Potential Antibacterial and Anticancer Motifs

(2019) Vunnam Srinivasulu et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Diastereoselective Synthesis of Medium-Sized Carbocycle-Fused Piperidines via Sequential Hydride Shift Triggered Double C(sp3)–H Bond Functionalization

(2019) Miyabi Kataoka et al.   ORGANIC LETTERS

(4 + 3)-Cycloaddition of Donor–Acceptor Cyclopropanes with Thiochalcones: A Diastereoselective Access to Tetrahydrothiepines

(2019) André U. Augustin et al.   ORGANIC LETTERS

Lewis Acid Catalyzed Stereoselective Dearomative Coupling of Indolylboron Ate Complexes with Donor-Acceptor Cyclopropanes and Alkyl Halides

(2018) Saikat Das et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Tandem Michael Addition of Tryptamine-Derived Oxindoles to Alkynones: Concise Synthesis of Strychnos Alkaloids

(2018) Weigang He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Remarkable increase in the rate of the catalytic epoxidation of electron deficient styrenes through the addition of Sc(OTf)3 to the MnTMTACN catalyst

(2018) Aneta Nodzewska et al.   CHEMICAL COMMUNICATIONS

Highly Diastereoselective Synthesis of Tetralin-fused Spirooxindoles via Lewis Acid-catalyzed C(sp3)–H Bond Functionalization

(2018) Mizuki Machida et al.   CHEMISTRY LETTERS

Synthesis and Applications of Stenhouse Salts and Derivatives

(2018) Rafael F. A. Gomes et al.   CHEMISTRY-A EUROPEAN JOURNAL

Selective Hydrogenolysis of Furfural Derivative 2-Methyltetrahydrofuran into Pentanediol Acetate and Pentanol Acetate over Pd/C and Sc(OTf)3 Cocatalytic System

(2018) Kun Zhang et al.   ChemSusChem

Eosin Y–Yb(OTf)3 catalyzed visible light mediated electrocyclization/indole ring opening towards the synthesis of heterobiaryl-pyrazolo[3,4-b]pyridines

(2018) Shikha Singh et al.   NEW JOURNAL OF CHEMISTRY

The Piancatelli reaction and its variants: recent applications to high added-value chemicals and biomass valorization

(2018) Charlie Verrier et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Stereoselective Synthesis of Fully-Substituted Acrylonitriles via Formal Acylcyanation of Electron-Rich Alkynes

(2018) Bing Liu et al.   ORGANIC LETTERS

[4 + 2] Annulation Cascades of 2-Bromo-1-arylpropan-1-ones with Terminal Alkynes Involving C–Br/C–H Functionalization

(2018) Xuan-Hui Ouyang et al.   ORGANIC LETTERS

Construction of 1,3-Dithio-Substituted Tetralins by [1,5]-Alkylthio Group Transfer Mediated Skeletal Rearrangement

(2018) Naoya Hisano et al.   ORGANIC LETTERS

Diastereodivergent asymmetric Michael-alkylation reactions using chiral N,N′-dioxide/metal complexes

(2018) Yulong Kuang et al.   Chemical Science

Er(OTf)3 -Catalyzed Multicomponent Synthesis of 3,4-Dihydro-2H -pyran via Hetero-Diels-Alder Reaction under Ambient Temperature

(2018) Vediyappan Ramesh et al.   ChemistrySelect

Ytterbium (III) triflate/Sodium Dodecyl Sulfate: A Versatile Recyclable and Water-Tolerant Catalyst for the Synthesis of Bis(indolyl)methanes (BIMs)

(2018) Bruna Luisa Tornquist et al.   ChemistrySelect

Asymmetric Synthesis of Tetrahydroindolizines by Bimetallic Relay Catalyzed Cycloaddition of Pyridinium Ylides

(2018) Dong Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Annulation of a Highly Functionalized Diazo Building Block with Indoles under Sc(OTf)3/Rh2(OAc)4 Multicatalysis through Michael Addition/Cyclization Sequence

(2018) Shanmugam Sakthivel et al.   JOURNAL OF ORGANIC CHEMISTRY

Broadly Applicable Ytterbium-Catalyzed Esterification, Hydrolysis, and Amidation of Imides

(2018) Céline Guissart et al.   ORGANIC LETTERS

Direct Lewis Acid Catalyzed Conversion of Enantioenriched N-Acyloxazolidinones to Chiral Esters, Amides, and Acids

(2018) Jason M. Stevens et al.   JOURNAL OF ORGANIC CHEMISTRY

Lanthanide(III)-Catalyzed Synthesis of trans-Diaminocyclopentenones from Substituted Furfurals and Secondary Amines via a Domino Ring-Opening/4π-Electrocyclization Pathway

(2018) Afton Hiscox et al.   ORGANIC LETTERS

Highly Chemo- and Diastereoselective Dearomative [3 + 2] Cycloaddition Reactions of Benzazoles with Donor–Acceptor Oxiranes

(2018) Shan-Shan Zhang et al.   ORGANIC LETTERS

Lewis Acid Catalyzed [3+3] Annulation of Donor-Acceptor Cyclopropanes with γ-Hydroxyenones: Access to Highly Functionalized Tetrahydropyrans

(2017) Keshab Mondal et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Ytterbium triflate promoted solvent-free synthesis of 2-amino-4 H -pyranes

(2017) Serena Fiorito et al.   TETRAHEDRON LETTERS

Highly Efficient Asymmetric Synthesis of Chiral γ-Alkenyl Butenolides Catalyzed by Chiral N,N′-Dioxide–Scandium(III) Complexes

(2017) Jie Ji et al.   ACS Catalysis

A New Golden Age for Donor-Acceptor Cyclopropanes

(2014) Tobias F. Schneider et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intramolecular donor–acceptor cyclopropane ring-opening cyclizations

(2013) Marchello A. Cavitt et al.   CHEMICAL SOCIETY REVIEWS

Highly Efficient Synthesis of Polysubstituted 1,2-Dihydroquinolines via Tandem Reaction of α-Ketoesters and Arylamines Catalyzed by Indium Triflate

(2011) Ji-Chen Zhang et al.   ACS Catalysis

Sc(OTf)3-Catalyzed Direct Alkylation of Quinolines and Pyridines with Alkanes

(2009) Guojun Deng et al.   ORGANIC LETTERS