Synthesis of Biodegradable Polymers: A Review on the Use of Schiff-Base Metal Complexes as Catalysts for the Ring Opening Polymerization (ROP) of Cyclic Esters

Unbridged bidentate aluminum complexes supported by diaroylhydrazone ligands: Synthesis, structure and catalysis in polymerization of ε ‐caprolactone and lactides

(2020) Kun Nie et al.   APPLIED ORGANOMETALLIC CHEMISTRY

Amino acid complexes with tin as a new class of catalysts with high reactivity and low toxicity towards biocompatible aliphatic polyesters

(2020) Maomao He et al.   POLYMER JOURNAL

Use of Titanium Complexes Bearing Diphenolate or Calix[n]arene Ligands in α-Olefin Polymerization and the ROP of Cyclic Esters

(2020) Orlando Santoro et al.   Catalysts

Bimetallic Aluminum Complexes Bearing Binaphthyl-Based Iminophenolate Ligands as Catalysts for the Synthesis of Polyesters

(2020) Federica Santulli et al.   ORGANOMETALLICS

Robust Guanidine Metal Catalysts for the Ring‐Opening Polymerization of Lactide under Industrially Relevant Conditions

(2020) Pascal M. Schäfer et al.   ChemPlusChem

L2Zn and LZnX complexes bearing half-salphen ligands and their catalysis of ring-opening polymerization of ε -caprolactone

(2020) Di Zhu et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Homoleptic, bis-ligated magnesium complexes for ring-opening polymerization of lactide and lactones: Synthesis, structure, polymerization behavior and mechanism studies

(2019) Xiao-Lu Chen et al.   APPLIED ORGANOMETALLIC CHEMISTRY

Ring-Opening Polymerization of (Macro)Lactones by Highly Active Mononuclear Salen-Aluminum Complexes Bearing Cyclic β -Ketoiminato Ligand

(2019) Hai-Chao Huang et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Binuclear Schiff-base zinc(II) complexes: Synthesis, crystal structures and reactivity toward ring opening polymerization of rac-lactide

(2019) Darío M. González et al.   POLYHEDRON

Mononuclear zinc(II) Schiff base complexes as catalysts for the ring-opening polymerization of lactide

(2019) Martin Fuchs et al.   EUROPEAN POLYMER JOURNAL

Synthesis and structure characterization of homoleptic lanthanide complexes stabilized by Schiff-base ligands and their application in the polymerization of ε-caprolactone

(2018) Bo Cen et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Improvement in titanium complexes supported by Schiff bases in ring-opening polymerization of cyclic esters: ONO-tridentate Schiff bases

(2018) Hsiu-Wei Ou et al.   POLYMER

Synthesis, characterization, and catalytic activity of lithium complexes bearing NNO-tridentate Schiff base ligands toward ring-opening polymerization of l -lactide

(2018) Wei-Yi Lu et al.   POLYMER

ROS-responsive poly(ε-caprolactone) with pendent thioether and selenide motifs

(2018) Li Yu et al.   Polymer Chemistry

Salen, salan and salalen iron(iii) complexes as catalysts for CO2/epoxide reactions and ROP of cyclic esters

(2018) Mariachiara Cozzolino et al.   DALTON TRANSACTIONS

Synthesis and characterization of salen-Ti(IV) complex and application in the controllable polymerization of D, L-lactide

(2018) Xiang Li et al.   PLoS One

Copolymerization of cyclic esters, epoxides and anhydrides: evidence of the dual role of the monomers in the reaction mixture

(2018) Florence Isnard et al.   Catalysis Science & Technology

Iron(III) Salalen Complexes for the Polymerisation of Lactide

(2018) Oliver J. Driscoll et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

New Coordination Modes for Modified Schiff Base Ti(IV) Complexes and Their Control over Lactone Ring-Opening Polymerization Activity

(2018) Christopher B. Durr et al.   INORGANIC CHEMISTRY

Mononuclear Salen–Sodium Ion Pairs as Catalysts for Isoselective Polymerization of rac-Lactide

(2018) Yaqin Cui et al.   INORGANIC CHEMISTRY

Ring opening polymerization and copolymerization of L‐lactide and ɛ‐caprolactone by bis ‐ligated magnesium complexes

(2018) Reile M. Slattery et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Synthesis, characterization and polymerisation studies of cadmium(II) complexes containing N,N′,X-tridentate X-substituted (X = N, O) 2-iminomethylpyridines

(2018) Jaegyeong Lee et al.   POLYHEDRON

N,O-Amino-phenolate Mg(II) and Zn(II) Schiff base complexes: Synthesis and application in ring-opening polymerization of ε-caprolactone and lactides

(2018) Wisdom A. Munzeiwa et al.   INORGANICA CHIMICA ACTA

ZnII Chlorido Complexes with Aliphatic, Chiral Bisguanidine Ligands as Catalysts in the Ring-Opening Polymerisation of rac -Lactide Using FT-IR Spectroscopy in Bulk

(2017) Angela Metz et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis of ZnII and AlIII Complexes of Diaminocyclohexane-Derived Ligands and Their Exploitation for the Ring Opening Polymerisation of rac -Lactide

(2017) Sarah M. Kirk et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Organoaluminium Complexes Derived from Anilines or Schiff Bases for the Ring-Opening Polymerization of ε-Caprolactone, δ-Valerolactone andrac-Lactide

(2017) Xue Wang et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A Comparison of Gallium and Indium Alkoxide Complexes as Catalysts for Ring-Opening Polymerization of Lactide

(2017) Alexandre B. Kremer et al.   INORGANIC CHEMISTRY

Well-Designed Unsymmetrical Salphen-Al Complexes: Synthesis, Characterization, and Ring-Opening Polymerization Catalysis

(2017) Wenlong Luo et al.   ORGANOMETALLICS

Aluminum Alkyl Complexes Bearing Salicylaldiminato Ligands: Versatile Initiators in the Ring-Opening Polymerization of Cyclic Esters

(2017) Tiziana Fuoco et al.   Catalysts

Dizinc Lactide Polymerization Catalysts: Hyperactivity by Control of Ligand Conformation and Metallic Cooperativity

(2016) Arnaud Thevenon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aluminium salalens vs. salans: “Initiator Design” for the isoselective polymerisation of rac-lactide

(2016) Paul McKeown et al.   CHEMICAL COMMUNICATIONS

Polymerization of lactide and synthesis of block copolymer catalyzed by copper (II) Schiff base complex

(2016) Anita Routaray et al.   CHINESE CHEMICAL LETTERS

Aminopiperidine based complexes for lactide polymerisation

(2016) P. McKeown et al.   DALTON TRANSACTIONS

Manganese coordination chemistry of bis(imino)phenoxide derived [2 + 2] Schiff-base macrocyclic ligands

(2016) Wenxue Yang et al.   DALTON TRANSACTIONS

Structural studies of Schiff-base [2 + 2] macrocycles derived from 2,2′-oxydianiline and the ROP capability of their organoaluminium complexes

(2016) Wenxue Yang et al.   DALTON TRANSACTIONS

Aluminum alkyl complexes: synthesis, structure, and application in ROP of cyclic esters

(2016) Yun Wei et al.   DALTON TRANSACTIONS

Bimetallic salen aluminum complexes: cooperation between reactive centers in the ring-opening polymerization of lactides and epoxides

(2016) Florence Isnard et al.   DALTON TRANSACTIONS

Synthesis of Sodium Complexes Supported with NNO-Tridentate Schiff Base Ligands and Their Applications in the Ring-Opening Polymerization of l-Lactide

(2016) Hsiu-Wei Ou et al.   INORGANIC CHEMISTRY

Nickel(II) complex catalyzed ring-opening polymerization of lactide

(2016) Anita Routaray et al.   POLYHEDRON

Synthesis, characterization and catalytic activity of zinc complex for ring-opening polymerization of lactide

(2016) Somanath Mantri et al.   POLYMER INTERNATIONAL

Group 4 alkoxide complexes containing [NNO]-type scaffold: synthesis, structural characterization and polymerization studies

(2016) Dipa Mandal et al.   RSC Advances

Gallium and indium complexes containing the bis(imino)phenoxide ligand: synthesis, structural characterization and polymerization studies

(2015) Swarup Ghosh et al.   DALTON TRANSACTIONS

Ring-opening polymerization of rac-lactide and α-methyltrimethylene carbonate catalyzed by magnesium and zinc complexes derived from binaphthyl-based iminophenolate ligands

(2015) Miao Huang et al.   DALTON TRANSACTIONS

Synthesis of cyclic polyesters: effects of alkoxy side chains in salicylaldiminato tin(ii) complexes

(2015) Phonpimon Wongmahasirikun et al.   DALTON TRANSACTIONS

Macrocyclic Dizinc(II) Alkyl and Alkoxide Complexes: Reversible CO2 Uptake and Polymerization Catalysis Testing

(2015) Charles Romain et al.   INORGANIC CHEMISTRY

Scandium and Yttrium Phosphasalen Complexes as Initiators for Ring-Opening Polymerization of Cyclic Esters

(2015) Clare Bakewell et al.   INORGANIC CHEMISTRY

Synthesis and Immortal ROP ofL-Lactide Using Copper Complex

(2015) Anita Routaray et al.   Journal of Macromolecular Science Part A-Pure and Applied Chemistry

Metal and Ligand-Substituent Effects in the Immortal Polymerization of rac-Lactide with Li, Na, and K Phenoxo-imine Complexes

(2015) Francisco M. García-Valle et al.   ORGANOMETALLICS

Overcoming aggregation in indium salen catalysts for isoselective lactide polymerization

(2015) D. C. Aluthge et al.   Chemical Science

Synthesis and characterization of rare-earth metal complexes supported by a new pentadentate Schiff base and their application in heteroselective polymerization of rac-lactide

(2015) Yu Cui et al.   Catalysis Science & Technology

Preparation of biocompatible, biodegradable and sustainable polylactides catalyzed by aluminum complexes bearing unsymmetrical dinaphthalene-imine derivatives via ring-opening polymerization of lactides

(2015) Bo Gao et al.   Catalysis Science & Technology

Mono- and tetra-nuclear copper complexes bearing bis(imino)phenoxide derived ligands: catalytic evaluation for benzene oxidation and ROP of ε-caprolactone

(2015) Xue Wang et al.   RSC Advances

Solvent-free ring opening polymerization of ε-caprolactone and electrical properties of polycaprolactone blended BiFeO3 nanocomposites

(2015) Somasundaram Saravanamoorthy et al.   RSC Advances

Chiral (1,2)-Diphenylethylene-Salen Complexes of Triel Metals: Coordination Patterns and Mechanistic Considerations in the Isoselective ROP of Lactide

(2014) Nicolas Maudoux et al.   CHEMISTRY-A EUROPEAN JOURNAL

Vanadyl complexes bearing bi-dentate phenoxyimine ligands: synthesis, structural studies and ethylene polymerization capability

(2014) Jing Ma et al.   DALTON TRANSACTIONS

Tri- and tetra-dentate imine vanadyl complexes: synthesis, structure and ethylene polymerization/ring opening polymerization capability

(2014) Jing Ma et al.   DALTON TRANSACTIONS

Gradient Isotactic Multiblock Polylactides from Aluminum Complexes of Chiral Salalen Ligands

(2014) Alessia Pilone et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

FI Catalysts for Olefin Oligomerization and Polymerization: Production of Useful Olefin-Based Materials by Unique Catalysis

(2014) Terunori Fujita et al.   TOPICS IN CATALYSIS

Highly stereoselective bimetallic complexes for lactide and ε-caprolactone polymerization

(2014) Xuan Pang et al.   RSC Advances

Synthesis and structures of tridentate ketoiminate zinc complexes bearing trifluoromethyl substituents that act as l-lactide ring opening polymerization initiators

(2013) Nomaan M. Rezayee et al.   DALTON TRANSACTIONS

Aluminium salalen complexes based on 1,2-diaminocyclohexane and their exploitation for the polymerisation of rac-lactide

(2013) Stuart L. Hancock et al.   DALTON TRANSACTIONS

Synthesis of binuclear phenoxyimino organoaluminum complexes and their use as the catalyst precursors for efficient ring-opening polymerisation of ε-caprolactone

(2013) Hong-Ling Han et al.   DALTON TRANSACTIONS

Living ring-opening homo- and copolymerisation of ε-caprolactone andl-lactide by cyclic β-ketiminato aluminium complexes

(2013) Yan Liu et al.   DALTON TRANSACTIONS

Non-toxic catalysts for ring-opening polymerizations of biodegradable polymers at room temperature for biohybrid materials

(2013) Cordula S. Hege et al.   GREEN CHEMISTRY

Synthesis and characterization of calcium complexes: Efficient catalyst for ring-opening polymerization of L-lactide

(2013) Mon-Wei Hsiao et al.   INORGANIC CHEMISTRY COMMUNICATIONS

Synthesis and Structure of Homo- and Heterometallic Lithium–Magnesium Complexes and Their Reactivity in the ROP of rac-Lactide

(2013) Carlos Gallegos et al.   ORGANOMETALLICS

{Phenoxy-imine}aluminum versus -indium Complexes for the Immortal ROP of Lactide: Different Stereocontrol, Different Mechanisms

(2013) Mickael Normand et al.   ORGANOMETALLICS

The contemporary role of ε-caprolactone chemistry to create advanced polymer architectures

(2013) Adam L. Sisson et al.   POLYMER

Attractive interactions in olefin polymerization mediated by post-metallocene catalysts with fluorine-containing ancillary ligands

(2013) Akihiko Iwashita et al.   Catalysis Science & Technology

Ring-opening polymerization of rac-lactide and ε-caprolactone using zinc and calcium salicylaldiminato complexes

(2012) Joshua B. L. Gallaway et al.   CANADIAN JOURNAL OF CHEMISTRY

Cellular uptake studies of two hexanuclear, carboxylate bridged, zinc ring structures using fluorescence microscopy

(2012) Carl Redshaw et al.   CHEMICAL COMMUNICATIONS

A highly active and site selective indium catalyst for lactide polymerization

(2012) Dinesh C. Aluthge et al.   CHEMICAL COMMUNICATIONS

Tridentate ligands and beyond in group IV metal α-olefin homo-/co-polymerization catalysis

(2012) Carl Redshaw et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of cyclic polylactide catalysed by bis(salicylaldiminato)tin(ii) complexes

(2012) Parichat Piromjitpong et al.   DALTON TRANSACTIONS

Dimethylaluminium aldiminophenolates: synthesis, characterization and ring-opening polymerization behavior towards lactides

(2012) Wenjuan Zhang et al.   DALTON TRANSACTIONS

Synthesis, characterization and catalytic activity of lithium and sodium iminophenoxide complexes towards ring-opening polymerization of l-lactide

(2012) Wei-Yi Lu et al.   DALTON TRANSACTIONS

Dinuclear aluminum complexes supported by amino- or imino-phenolate ligands: synthesis, structures, and ring-opening polymerization catalysis of rac-lactide

(2012) Xiao-Feng Yu et al.   DALTON TRANSACTIONS

Control of thermal properties and hydrolytic degradation in poly(lactic acid) polymer stars through control of isospecificity of polymer arms

(2012) Donald J. A. Cameron et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Aluminum salen and salan complexes in the ring-opening polymerization of cyclic esters: Controlled immortal and copolymerization ofrac-β-butyrolactone andrac-lactide

(2012) Edward D. Cross et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Yttrium Phosphasalen Initiators for rac-Lactide Polymerization: Excellent Rates and High Iso-Selectivities

(2012) Clare Bakewell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preparation and Characterization of Aluminum Alkoxides Coordinated on salen-Type Ligands: Highly Stereoselective Ring-Opening Polymerization of rac-Lactide

(2012) Hsiao-Li Chen et al.   ORGANOMETALLICS

Synthesis, Structure, and Reactivity of Homodinuclear Lanthanide Complexes Bearing Salen-type Schiff-base Ligand

(2012) Wenfeng Lv et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Vanadium(iii) phenoxyimine complexes for ethylene or ε-caprolactone polymerization: mononuclear versus binuclear pre-catalysts

(2012) Lucy Clowes et al.   Catalysis Science & Technology

Bulk solvent-free melt ring-opening polymerization of L-lactide catalyzed by Cu(II) and Cu(II)-Nd(III) complexes of the Salen-type Schiff-base ligand

(2011) Lei-Lei Chen et al.   APPLIED ORGANOMETALLIC CHEMISTRY

Redox control of a polymerization catalyst by changing the oxidation state of the metal center

(2011) Erin M. Broderick et al.   CHEMICAL COMMUNICATIONS

FI Catalysts for Olefin Polymerization—A Comprehensive Treatment

(2011) Haruyuki Makio et al.   CHEMICAL REVIEWS

Salalen aluminium complexes and their exploitation for the ring opening polymerisation of rac-lactide

(2011) Emma L. Whitelaw et al.   DALTON TRANSACTIONS

Methylaluminium 8-quinolinolates: synthesis, characterization and use in ring-opening polymerization (ROP) of ε-caprolactone

(2011) Wen-Hua Sun et al.   DALTON TRANSACTIONS

Bulk solvent-free melt ring-opening polymerization (ROP) of L-lactide catalyzed by Ni(II) and Ni(II)–Ln(III) complexes based on the acyclic Salen-type Schiff-base ligand

(2011) Liqin Ding et al.   INORGANIC CHEMISTRY COMMUNICATIONS

Synthesis, characterization and catalytic activity of Salen–(sodium)2 and (Salen)2–lanthanum–sodium complexes

(2011) Lihui Yao et al.   INORGANICA CHIMICA ACTA

Controllable bulk solvent-free melt ring-opening polymerization (ROP) of l-lactide catalyzed by Ni(II) and Ni(II)–Ln(III) complexes based on the Salen-type Schiff-base ligand

(2011) Wen-Juan Jin et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

The use of Cu and Zn salicylaldimine complexes as catalyst precursors in ring opening polymerization of lactides: ligand effects on polymer characteristics

(2010) Suraj Bhunora et al.   APPLIED ORGANOMETALLIC CHEMISTRY

Ring-Opening Polymerization of Lactides Catalyzed by Natural Amino-Acid Based Zinc Catalysts

(2010) Donald J. Darensbourg et al.   INORGANIC CHEMISTRY

Group 4 Salalen Complexes and Their Application for the Ring-Opening Polymerization ofrac-Lactide

(2010) Emma L. Whitelaw et al.   INORGANIC CHEMISTRY

Zinc(II) Silsesquioxane Complexes and Their Application for the Ring-Opening Polymerization ofrac-Lactide

(2010) Carlo Di Iulio et al.   INORGANIC CHEMISTRY

Bimetallic copper(II) and zinc(II) complexes of acyclic Schiff base ligands derived from amino acids

(2010) Abdessamad Arbaoui et al.   INORGANICA CHIMICA ACTA

Conformationally Flexible Dimeric Salphen Complexes for Bifunctional Catalysis

(2010) Sergei I. Vagin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Ring-Opening Polymerization ofrac-Lactides Catalyzed by Chiral and Achiral Aluminum Half-Salen Complexes†

(2010) Donald J. Darensbourg et al.   ORGANOMETALLICS

Metal catalysts for ε-caprolactone polymerisation

(2010) Abdessamad Arbaoui et al.   Polymer Chemistry

Bulk ring-opening polymerization (ROP) of L-lactide catalyzed by Ni(ii) and Ni(ii)-Sm(iii) complexes based on a salen-type schiff-base ligand

(2010) Guoqi Xiao et al.   Polymer Chemistry

The return of a forgotten polymer—Polycaprolactone in the 21st century

(2010) Maria Ann Woodruff et al.   PROGRESS IN POLYMER SCIENCE

Synthetic polymer scaffolds for tissue engineering

(2009) Elsie S. Place et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of polycaprolactone: a review

(2009) Marianne Labet et al.   CHEMICAL SOCIETY REVIEWS

Zinc(II) Homogeneous and Heterogeneous Species and Their Application for the Ring-Opening Polymerisation ofrac-Lactide

(2009) Matthew D. Jones et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

New insights into the lactide polymerisation with neutral N-donor stabilised zinc complexes: Comparison of imidazolin-2-imine vs. guanidine complexes

(2009) Janna Börner et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Aluminum and Yttrium Complexes of an Unsymmetrical Mixed Fluorous Alkoxy/Phenoxy-Diimino Ligand: Synthesis, Structure, and Ring-Opening Polymerization Catalysis

(2009) Ali Alaaeddine et al.   ORGANOMETALLICS

Multinuclear alkylaluminium macrocyclic Schiff base complexes: influence of procatalyst structure on the ring opening polymerisation of ε-caprolactone

(2008) Abdessamad Arbaoui et al.   CHEMICAL COMMUNICATIONS

Enolic Schiff Base Aluminum Complexes and Their Catalytic Stereoselective Polymerization of Racemic Lactide

(2008) Xuan Pang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Robust chiral zirconium alkoxide initiators for the room-temperature stereoselective ring-opening polymerisation of rac-lactide

(2008) Amanda J. Chmura et al.   DALTON TRANSACTIONS

Ring-opening polymerization of various cyclic esters by Al complex catalysts containing a series of phenoxy-imine ligands: Effect of the imino substituents for the catalytic activity

(2008) Naruhito Iwasa et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Ring-Opening Polymerization of Cyclic Monomers by Complexes Derived from Biocompatible Metals. Production of Poly(lactide), Poly(trimethylene carbonate), and Their Copolymers

(2008) Donald J. Darensbourg et al.   MACROMOLECULES

Polymers from Renewable Resources: A Perspective for a Special Issue of Polymer Reviews

(2008) Charlotte Williams et al.   Polymer Reviews