4.4 Article

FI Catalysts for Olefin Oligomerization and Polymerization: Production of Useful Olefin-Based Materials by Unique Catalysis

Journal

TOPICS IN CATALYSIS
Volume 57, Issue 10-13, Pages 852-877

Publisher

SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-014-0246-z

Keywords

Olefin oligomerization; Olefin polymerization; FI catalysts; Olefin-based materials; 1-Hexene

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This contribution highlights the uniqueness of FI catalysts (phenoxy-imine ligated group 4 metal complexes) for olefin coordination insertion catalysis. FI catalysts possess characteristic structural and electronic features that are different from those of group 4 metallocene catalysts. These special features in turn initiate versatile catalytic properties that result in useful olefin-based materials some of which have already been commercialized.

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