4.7 Article

Bifunctional NiAlFe LDH-coated membrane for oil-in-water emulsion separation and photocatalytic degradation of antibiotic

Journal

SCIENCE OF THE TOTAL ENVIRONMENT
Volume 751, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.scitotenv.2020.141660

Keywords

LDH; Oil-in-water emulsion separation; Underwater superoleophobicity; Photocatalytic degradation; Antibiotic

Funding

  1. National Natural Science Foundation of China [21808019, 41772240]
  2. Natural Science Foundation of Jiangsu [BK20180958, BK20181048]

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The NiAlFe LDH/PDA/PVDF membrane with superior wettability and hierarchical rough structure effectively separates oil-in-water emulsions and serves as a photocatalysis paper for antibiotic residue treatment with excellent photocatalytic activity and stability.
A new NiAlFe layered double hydroxide/polydopamine/polyvinylidene fluoride (NiAlFe LDH/PDA/PVDF) membrane was fabricated by in-situ growth of LDH on the PDA modified PVDF membrane. The as-prepared membrane possesses a nano/microscale rough structural surface and displays the superior wettability of superhydrophilicity in air and underwater superoleophobicity. Combining the favourable features of superwettability and hierarchical rough structure, the NiAlFe LDH/PDA/PVDF membrane could effectively separate a series of oil-in-water emulsions with high efficiency (>99%) and high permeation flux (925-1913 L m(-2)h(-1) bar(-1)). Besides, owing to the light harvest ability of NiAlFe LDH, the relevant membrane also can be applied as a photocatalysis paper for the light-driven treatment of antibiotic residue in aqueous solution. Inwhich, NiAlFe LDH/PDA/PVDF membrane can effectively degrade typical antibiotic tetracycline within 20 min under UV light irradiation, exhibiting excellent photocatalytic activity. In addition, cyclic experiments demonstrate that NiAlFe LDH/PDA/PVDF membrane has excellent stability and reusability both in oil-in-water emulsion separation and photocatalytic reaction. In general, the findings of this research demonstrate that photo-response LDH modified membranes have potential multiple applications in wastewater treatment. (C) 2020 Elsevier B.V. All rights reserved.

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