Journal
MATERIALS LETTERS
Volume 273, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.matlet.2020.127915
Keywords
Niobium pentoxide; Hydrogen peroxide; Heterogeneous photocatalysis; Visible light; Phenolic compounds photooxidation
Funding
- Sao Paulo Research Foundation (FAPESP) [2018/09723-9]
- National Council for Scientific and Technological Development (CNPq) [2018-5/131782]
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Peroxo-Nb2O5 photocatalyst with visible-light activity was fabricated via a one-pot hydrothermal oxygen peroxide method for the first time. The one-pot synthesis employing different H2O2 concentrations promoted simultaneous crystallization and surface groups formation that impacted the photocatalytic efficiency. It was demonstrated that the presence of peroxo groups acted as charge mediators in a photooxidative process since the samples did not present any band gap shift to visible. The catalyst reutilization indicated that the photocatalytic effect is not temporary, reinforcing the chemical role of peroxo groups as charge mediators. (C) 2020 Elsevier B.V. All rights reserved.
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