4.7 Article

Direct synthesis, characterization, and reverse electrodialysis applications of MoS2 thin film on aluminum foil

Journal

MATERIALS CHARACTERIZATION
Volume 164, Issue -, Pages -

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.matchar.2020.110361

Keywords

Al foil; Electrode; Gross power density; Resistance; MoS2; Reverse electrodialysis

Funding

  1. Technology Development Program to Solve Climate Changes of the National Research Foundation (NRF) - Ministry of Science and ICT [2017M1A2A2047366]
  2. National Research Foundation of Korea [2017M1A2A2047366] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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This study reports the direct synthesis of MoS2 thin film on Al foil by chemical vapor deposition in a closed reactor. The electrochemical properties of the thin film were analyzed using reverse electrodialysis between salt water and fresh water. Microscopic and spectroscopic analyses revealed the porous and defective surface morphologies and layered crystalline structure of the MoS2 thin film. In cross-sectional TEM images, the MoS2 thin film was random and obliquely layered on the surface of Al foil native oxide. According to electrochemical tests, the maximum gross power density of MoS2/Al was approximately 34 W/m(2), 54% higher than that of the as-received Al and 78% superior to the bulk MoS2 disk. The results confirmed that MoS2 was uniformly coated on the Al foil. MoS2/Al is a superior and inexpensive cathode for reverse electrodialysis, representing a new energy application of MoS2.

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