Article
Multidisciplinary Sciences
Yan Su, Ken-ichi Otake, Jia-Jia Zheng, Satoshi Horike, Susumu Kitagawa, Cheng Gu
Summary: Efficient separation of water isotopologues at room temperature has been achieved by constructing porous coordination polymers with flip-flop molecular motions to regulate the diffusion rates of water isotopologues. This method shows promise for high-performance vapor separation.
Article
Chemistry, Multidisciplinary
Haoyun Hu, Guihua Ruan, Xiangqiong Jiang, Hong Pan, Zhuqiang Wu, Yipeng Huang
Summary: A convenient, sustainable, and efficient method for the fabrication of monodispersed porous carbon material was developed, improving the adsorption capacity of solid phase extraction columns and playing a crucial role in sample pretreatment.
NEW JOURNAL OF CHEMISTRY
(2022)
Article
Engineering, Chemical
Donglai Mao, John M. Griffin, Richard Dawson, Alasdair Fairhurst, Gaurav Gupta, Nuno Bimbo
Summary: This review compares the performance of commonly-studied porous materials used for adsorption at low temperatures, considering test conditions and identifying high performing materials for future research directions.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Chemistry, Multidisciplinary
Xiaoying Lin, Weipeng Zeng, Yilan Chen, Ting Su, Qinhua Zhong, Linzhu Gong, Yamin Liu
Summary: A porous carbon material UiO-66-C was synthesized by carbonization of metal-organic frameworks UiO-66 under inert gas atmosphere. The physicochemical properties and adsorption performance of UiO-66-C were well characterized. The results showed that UiO-66-C exhibited high specific surface area and excellent adsorption capacity for tetracycline.
Article
Chemistry, Physical
Ying Yu, Lifeng Yang, Bin Tan, Jianbo Hu, Qingju Wang, Xili Cui, Huabin Xing
Summary: This study successfully achieved the challenging separation of C5 olefins using two novel adsorbents, demonstrating unprecedented separation and recycling performance. The experimental results validated the excellent separation performance of these two adsorbents for C5 olefins, while regeneration tests showed easy desorption.
Article
Chemistry, Multidisciplinary
Zhaofu Zhang, Yajing Zheng, Zilong Dou, Mengnan Gu, Mengxiao Sun, Jian Song, Nan Gao, Fengchao Cui, Yuyang Tian, Guangshan Zhu
Summary: Porous aromatic frameworks (PAFs) are versatile porous materials with promising functionality, but the synthesis of PAFs with desired properties is challenging. In this study, a multivariate inspired strategy was employed to successfully synthesize PAFs with highly porous and hierarchical structures. The PAFs obtained through this strategy exhibited both hierarchical structures and high specific surface areas. Furthermore, lipase was loaded onto one of the multivariate PAFs, showing high loading content and favorable catalytic activity and stability.
ACS CENTRAL SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Tadashi Hyodo, Masahide Tominaga, Kentaro Yamaguchi
Summary: The adamantane-bearing macrocycle exhibited permanent intrinsic porosity and adsorbed small organic compounds in a single-crystal-to-single-crystal manner. Guest uptake by porous crystals led to the structural transformation of the supramolecular organic framework, resulting in changes in the shape and size of one-dimensional pores.
Article
Chemistry, Inorganic & Nuclear
Albert Rosado, Oriol Vallcorba, Blanca Vazquez-Lasa, Luis Garcia-Fernandez, Rosa Ana Ramirez-Jimenez, Maria Rosa Aguilar, Ana M. Lopez-Periago, Concepcion Domingo, Jose A. Ayllon
Summary: A new bioMOF called CaSyr-1 is prepared using an ethanol-based strategy, with features of full biocompatibility, high surface area (>1000 m(2) g(-1)), and a micropore diameter close to mesopore values. This bioMOF shows reversible adsorption of CO2 and can encapsulate bioactive ingredients, enabling the development of triple therapeutic entities involving Ca2+, syringic acid, and a drug.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Engineering, Environmental
Haihao Peng, Weiping Xiong, Zhaohui Yang, Jiao Cao, Meiying Jia, Yinping Xiang, Qi Hu, Zhengyong Xu
Summary: Metal-organic frameworks (MOFs) are promising materials for antibiotics removal, but limited by poor recyclability. In this study, a three-dimensional hierarchical porous ZIF-L/foaming gelatin aerogels (ZIF-L/FGA200) was successfully prepared, showing high removal efficiency towards tetracycline. The ZIF-L/FGA200 also demonstrated excellent recyclability after multiple adsorption-desorption cycles.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Multidisciplinary
Ruihe Yu, Lin Liu, Liying Yin, Yege Jing, Ning Zhang, Hang Bian, Guangshan Zhu
Summary: The growth of porous aromatic frameworks (PAFs) on the surface of polymer brushes is achieved for the first time. The confined environment provided by the polymer brushes leads to the formation of nanosized and homogeneous spherical PAFs. The size of PAFs can be controlled by adjusting reaction time, grafting density, and concentration of 4-bromobenzene.
Article
Engineering, Environmental
Biswa Nath Bhadra, Sung Hwa Jhung
Summary: A novel tricomponent composite material has been developed, which can be used as a precursor to prepare stable micro/nano tungsten nitride@porous carbon nanocomposites with excellent catalytic performance by controlling the loading amount of melamine. The obtained materials show remarkable potential for oxidative desulfurization of liquid fuel.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Physical
Ping Cheng, Xiaohan Wang, Josua Markus, Md Abdul Wahab, Silvia Chowdhury, Ruijing Xin, Saad M. Alshehri, Yoshio Bando, Yusuke Yamauchi, Yusuf Valentino Kaneti
Summary: This work introduces coordinated water into Ni-BTC nanorods, resulting in their transformation to Ni-BTC nanofibres. The carbonization of the NiBTC nanofibres at 600 degrees C leads to the formation of carbon nanotube-decorated porous nickel/carbon hybrid with enlarged pores. The Ni/C-600 hybrid exhibits higher adsorption capacity and better recyclability compared to the original Ni-BTC nanorods.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Applied
Jing Wang, Yuelin Wang, Ye Liang, Jicheng Zhou, Licheng Liu, Shirong Huang, Jinjun Cai
Summary: The study developed nitrogen-doped carbons through changing glucose mass in a hydrothermal system and investigated their removal performance for Rhodamine B. The results showed that these carbon materials exhibited high adsorption capacity, fast kinetics, and good wettability, making them suitable for water treatment.
MICROPOROUS AND MESOPOROUS MATERIALS
(2021)
Article
Energy & Fuels
Tingyan Lu, Jiali Bai, Jiamei Huang, Qiyun Yu, Muslum Demir, Murat Kilic, Bilge Nazli Altay, Linlin Wang, Xin Hu
Summary: This study introduces a self-activating synthesis method for fabricating self-S-doped porous carbon adsorbents. The activating temperature was found to control the textural and elemental compositions of the prepared carbons, with the optimal S-doped porous carbon exhibiting good CO2 uptake capacities and stability.
Article
Chemistry, Multidisciplinary
Ulrich Legrand, Pierre-Luc Girard-Lauriault, Jean-Luc Meunier, Richard Boudreault, Jason Robert Tavares
Summary: Study finds that open porosity has the greatest influence on improving sorbent kinetics. Converting sorbent kinetics data into daily water capture yields shows that there is an optimal open porosity for each sorbent, and thinner layers with moderate open porosity outperform thicker layers with high open porosity, indicating that high maximum water uptake and fast single-particle kinetics are not necessarily predictive of high daily water yield.
Article
Chemistry, Multidisciplinary
Zhifeng Xin, Zibo Yuan, Jingjing Liu, Xinjian Wang, Kejing Shen, Yifa Chen, Ya-Qian Lan
Summary: Metal-doped carbon materials, such as Cu cluster embedded porous nanofibers, show promise as electrocatalysts for CO2 reduction reaction (CO2 RR). In this study, highly porous nanofibers with uniformly dispersed Cu clusters were prepared through the carbonization of electro-spun MOF/PAN nanofibers. The best catalyst, MCP-500, exhibited high catalytic performance for CO2 RR, with a Faradaic efficiency of CO as high as 98% at -0.8 V. The superior performance could be attributed to the synergistic effect between the layered graphene skeleton and uniformly dispersed Cu clusters.
CHINESE CHEMICAL LETTERS
(2023)
Article
Chemistry, Multidisciplinary
Xue Dong, Zhifeng Xin, Dong He, Jia-Ling Zhang, Ya-Qian Lan, Qian-Feng Zhang, Yifa Chen
Summary: In this study, fullerene molecules were successfully introduced into the pore-channels of a Co-porphyrin based MOF through a facile strategy. The resulting hybrid materials exhibited higher electron-transfer ability, enhanced CO2 adsorption-enthalpy and CO2 electroreduction activity. This strategy provides new insights into the development of powerful MOF-based hybrid materials for high-efficiency CO2 electroreduction.
CHINESE CHEMICAL LETTERS
(2023)
Article
Engineering, Environmental
Jie Wang, Xiaojie Ma, Ming Chen, Yuchang Li, Jie Han, Boou Li, Qiuhua Wei, Wenwen Xin, Xiaoping Kang, Jinglin Wang, Bo Wang
Summary: This study demonstrates the superiority of light-responsive metal-organic frameworks (MOFs) in pathogen inactivation. The integration of MOFs with prussian blue (PB) and zeolitic imidazolate framework (ZIF-8) enhances the production of reactive oxygen species (ROS) and initiates the Fenton reaction, leading to efficient pathogen elimination. Additionally, the unique photothermal effect of PB promotes intracellular ROS penetration, further improving the inactivation efficiency. Composite materials based on MOFs show great potential in preventing life-threatening microbial infections.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Shan Li, Jian-Hui Wang, Long-Zhang Dong, Yu Zhang, Xiao-Man Yao, Yifa Chen, Shun -Li Li, Ya-Qian Lan
Summary: A hybrid nanosheets based on Ru nanoparticles, Fe-TAPP, and graphene oxide (GO) was designed through a one-pot self-assembly strategy. The Ru/Fe-TAPP@GO nanosheets exhibited ultra-low overpotential, high specific capacity, and fully reversible discharge/charge property, making them a promising cathode catalyst for Li-CO2 batteries.
CHINESE CHEMICAL LETTERS
(2023)
Article
Engineering, Environmental
Yuhua Cao, Xiang Li, Gang Yu, Bo Wang
Summary: This study presents the design and synthesis of finely-tuned hierarchically porous materials based on water-stable metal-organic frameworks (MOFs). The as-synthesized materials show significantly improved adsorption capacity and uptake rate for pharmaceuticals. The study systematically investigates the adsorption performance of various pharmaceuticals and competitor compounds in natural wastewater. The findings contribute to enhancing the removal of micropollutants and provide fundamental insights into the porosity-performance relationships.
JOURNAL OF HAZARDOUS MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Lixuan Xu, Yiwei Li, Yuqiang Fang, Huijun Zheng, Wujun Shi, Cheng Chen, Ding Pei, Donghui Lu, Makoto Hashimoto, Meixiao Wang, Lexian Yang, Xiao Feng, Haijun Zhang, Fuqiang Huang, Qikun Xue, Ke He, Zhongkai Liu, Yulin Chen
Summary: The evolution of physical properties in 2D materials from monolayer to bulk introduces unique effects due to dimension confinement and provides a tuning knob for applications. The novel 2M-TMDs, consisting of translationally stacked 1T'-monolayers, exhibit tunable inverted bandgaps and interlayer coupling, making them promising as building blocks for various topological phases. By using advanced spectroscopy and calculations, a topology hierarchy is revealed, showing different topological insulator states in 2M-WSe2, MoS2, MoSe2, and 2M-WS2 due to band inversion amplitude and interlayer coupling. These 2M-TMDs are proposed as parent compounds for exotic phases and have great potential in quantum electronics due to their flexibility in patterning with 2D materials.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Xin Huang, Shuyi Jiang, Dou Ma, Jing Xie, Xiao Feng, Bo Wang
Summary: In this study, a robust ultramicroporous metal-organic framework (MET-Fe) is proposed for separating 1-butene isomers through molecular exclusion. The pore aperture size of MET-Fe precisely matches the kinetic diameters of the isomers, as confirmed by static and kinetic adsorption experiments and theoretical calculations. Dynamic breakthrough experiments further demonstrate the excellent separation performance, easy regeneration, and remarkable reusability of MET-Fe under both dry and humid conditions.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Review
Chemistry, Multidisciplinary
Chao Sun, Dafei Sheng, Bo Wang, Xiao Feng
Summary: Water scarcity is a growing concern due to population growth and industrialization worldwide. Sorption-based atmospheric water harvesting (SAWH) using covalent organic frameworks (COFs) as sorbents shows promise in addressing this issue. This mini-review provides an overview of different types of COFs, their structural characteristics, and the diverse chemistries used in their construction. Recent advances in COF-based sorbents for atmospheric water harvesting are summarized, including strategies for controlling sorption properties and optimizing thermodynamics and dynamics. Prospects and challenges for improving the efficiency of COF-based SAWH systems are also discussed.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Gang Liu, Yifa Chen, Yulu Chen, Yanqi Shi, Meiyu Zhang, Guodong Shen, Pengfei Qi, Jikun Li, Delong Ma, Fei Yu, Xianqiang Huang
Summary: This study presents a promising strategy of indirect electrocatalytic conversion for the production of value-added chemicals for industrial rubber from cheap organic raw materials. A series of di-copper-substituted phosphotungstate-based foams were fabricated and successfully applied in the synthesis of sulfenamides and disulfides. The optimal catalyst exhibited excellent performance in producing H2 and constructing S-N/S-S bonds.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Rui Liu, Mingzi Sun, Xiangjian Liu, Zunhang Lv, Xinyu Yu, Jinming Wang, Yarong Liu, Liuhua Li, Xiao Feng, Wenxiu Yang, Bolong Huang, Bo Wang
Summary: Developing efficient and stable hydrogen production catalysts for electrochemical water splitting is challenging. This study proposes a heterostructure-induced-strategy to optimize the metal-support interaction and improve the electroactivity of Ru-Ni3N/NiO catalysts.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Xuechun Jing, Mengxi Zhang, Zhenjie Mu, Pengpeng Shao, Yuhao Zhu, Jie Li, Bo Wang, Xiao Feng
Summary: Covalent organic frameworks (COFs) provide an exceptional platform for constructing membrane nanochannels with tunable pore sizes and tailored functionalities. This study introduces a prenucleation and slow growth approach to synthesize COF membranes with highly oriented mesoporous channels and high surface area. Functional moieties are anchored to the pore walls via click reactions and coordinated with Cu ions for remarkable H-2/CO2 separation performance.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Review
Chemistry, Multidisciplinary
Dafei Sheng, Xinlin Li, Chao Sun, Junwen Zhou, Xiao Feng
Summary: Separation membranes are essential in the functioning of artificial organs. The COVID-19 pandemic has underscored their importance in the medical community. However, there are challenges in membrane technology, such as clearing toxins and improving blood compatibility. This review discusses the mechanisms, performance, and biocompatibility of separation membranes in artificial organs, as well as the opportunities and challenges for next-generation membrane technology.
MATERIALS CHEMISTRY FRONTIERS
(2023)
Article
Chemistry, Multidisciplinary
Longlong Fan, Qinghong Geng, Lian Ma, Chengming Wang, Jun-Xuan Li, Wei Zhu, Ruiwen Shao, Wei Li, Xiao Feng, Yusuke Yamauchi, Cuiling Li, Lei Jiang
Summary: In this study, three-dimensional ordered porous cuprous oxide cuboctahedra were designed and synthesized, and exhibited outstanding electrochemical CO2-to-C2+ conversion. The ordered pores effectively confined and accumulated *CO adsorption during the reduction of CO2, facilitating efficient dimerization for the formation of C2+ products. The 3DOP structure also induced a higher local pH value, enhancing the C-C coupling reaction and suppressing competing H2 evolution.
Article
Chemistry, Multidisciplinary
Gang Liu, Yifa Chen, Yulu Chen, Yanqi Shi, Meiyu Zhang, Guodong Shen, Pengfei Qi, Jikun Li, Delong Ma, Fei Yu, Xianqiang Huang
Summary: This study explores the conversion of cheap organic raw materials into valuable chemicals for industrial rubber production through indirect electrocatalysis. By fabricating di-copper-substituted phosphotungstate-based foams, the researchers achieved successful synthesis of sulfenamides and disulfides. The optimal catalyst PW10Cu2@CMC showed excellent electrocatalytic performance and enabled scale-up production, with the resulting products serving as high-performance rubber vulcanization accelerators.
ADVANCED MATERIALS
(2023)
Article
Engineering, Chemical
Xin Mi, Xiang Li, Chong-Chen Wang, Bo Wang
Summary: In this study, cerium-based UiO-66 and MOF-808 were used to preferentially remove harmful chemicals at trace amounts in water with high environmental risk. The results showed that cerium-oxygen clusters effectively adsorbed the target chemicals through both chemical and physical mechanisms. The study also found that the length of alkyl chains in perfluoroalkyl carboxylic acids strongly correlated with the adsorption capacity. Additionally, the study demonstrated the complete decomposition of aromatic NSAIDs under solar light irradiation using reactive species generated by the cerium-oxygen clusters.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)