Recent Advances in Carbonylative Difunctionalization of Alkenes

Copper-Catalyzed Carbonylative Synthesis of β-Homoprolines from N-Fluoro-sulfonamides

(2020) Youcan Zhang et al.   ORGANIC LETTERS

Palladium-Catalyzed Regioselective Carbonylative Coupling/Amination of Aryl Iodides with Unactivated Alkenes: Efficient Synthesis of β-Aminoketones

(2019) Jin-Bao Peng et al.   ACS Catalysis

Mechanism and Origin of Stereoselectivity of Pd-Catalyzed Cascade Annulation of Aryl Halide, Alkene, and Carbon Monoxide via C–H Activation

(2019) Xia Fan et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Synthesis of 2-Oxindole Spirofused Lactones and Lactams by Heck/Carbonylative Cylization Sequences: Method Development and Applications

(2019) Huaanzi Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium‐Catalyzed Tunable Carbonylative Synthesis of Enones and Benzofulvenes

(2019) Jin‐Bao Peng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cross-Coupling of Heteroatomic Electrophiles

(2019) Katerina M. Korch et al.   CHEMICAL REVIEWS

Selectivity controllable divergent synthesis of α,β-unsaturated amides and maleimides from alkynes and nitroarenes via palladium-catalyzed carbonylation

(2019) Jin-Bao Peng et al.   JOURNAL OF CATALYSIS

Palladium-Catalyzed Carbonylative Dearomatization of Indoles

(2019) Hai Wang et al.   ORGANIC LETTERS

Bis‐Alkoxycarbonylation of Acrylic Esters and Amides for the Synthesis of 2‐Alkoxycarbonyl or 2‐Carbamoyl Succinates

(2019) Diego Olivieri et al.   ADVANCED SYNTHESIS & CATALYSIS

A 16-step synthesis of the isoryanodane diterpene (+)-perseanol

(2019) Arthur Han et al.   NATURE

Ni-Catalyzed Reductive Arylacylation of Alkenes toward Carbonyl-Containing Oxindoles

(2019) Sheng Xu et al.   ORGANIC LETTERS

Palladium-Catalyzed Oxidative Carbonylative Coupling of Arylallenes, Arylboronic Acids, and Nitroarenes

(2019) Hui-Qing Geng et al.   ORGANIC LETTERS

Radical-Mediated Difunctionalization of Styrenes

(2019) Xiazhen Bao et al.   SYNTHESIS-STUTTGART

Palladium-catalyzed four-component carbonylation of allenes, alcohols and nitroarenes

(2019) Hui-Qing Geng et al.   JOURNAL OF CATALYSIS

Copper-Catalyzed Borocarbonylative Coupling of Internal Alkynes with Unactivated Alkyl Halides: Modular Synthesis of Tetrasubstituted β-Borylenones

(2018) Li-Jie Cheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand- and Solvent-Controlled Regio- and Chemodivergent Carbonylative Reactions

(2018) Jin-Bao Peng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N,N-Chiral Ligands Enabling Palladium-catalyzed Enantioselective Intramolecular Heck-Matsuda Carbonylation Reactions by Sequential Migratory and CO Insertions

(2018) Carlos Roque Duarte Correia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A copper-catalyzed carbonylative four-component reaction of ethene and aliphatic olefins

(2018) Yahui Li et al.   CHEMICAL COMMUNICATIONS

First-Row Transition-Metal-Catalyzed Carbonylative Transformations of Carbon Electrophiles

(2018) Jin-Bao Peng et al.   CHEMICAL REVIEWS

Recent Advances in Transition Metal-Catalysed Three-Component Difunctionalization of Alkenes

(2018) Tieqiao Chen et al.   Chemistry-An Asian Journal

Strategies toward Dicarbofunctionalization of Unactivated Olefins by Combined Heck Carbometalation and Cross-Coupling

(2018) Ramesh Giri et al.   JOURNAL OF ORGANIC CHEMISTRY

Total Synthesis of (±)-Cephanolides B and C via a Palladium-Catalyzed Cascade Cyclization and Late-Stage sp3 C–H Bond Oxidation

(2018) Lun Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Natural product syntheses via carbonylative cyclizations

(2018) Kaiqing Ma et al.   NATURAL PRODUCT REPORTS

Palladium-Catalyzed Ring-Forming Alkene Aminoaroylation of Unsaturated Hydrazones and Sulfonamides

(2018) Jun Chen et al.   ORGANIC LETTERS

Radical Carbonylation Mediated by Continuous-Flow Visible-Light Photocatalysis: Access to 2,3-Dihydrobenzofurans

(2018) Nenad Micic et al.   ORGANIC LETTERS

Palladium-Catalyzed Regioselective Cyclocarbonylation of N -(3-Phenylprop-2-ynyl)anilines with Carbon Monoxide and Alcohols for the Synthesis of Quinoline-3-carboxylic Esters

(2018) Wei Zhang et al.   Asian Journal of Organic Chemistry

Diastereospecific Bis-alkoxycarbonylation of 1,2-Disubstituted Olefins Catalyzed by Aryl α-Diimine Palladium(II) Catalysts

(2018) Diego Olivieri et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed Intermolecular Arylcarbonylation of Unactivated Alkenes: Incorporation of Bulky Aryl Groups at Room Temperature

(2018) Xiang Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Arylation/Heteroarylation of Indoles: Access to 2,3-Functionalized Indolines

(2018) Nicolas Zeidan et al.   ORGANIC LETTERS

The Chemistry of CO: Carbonylation

(2018) Jin-Bao Peng et al.   Chem

Palladium-Catalyzed Intermolecular Azidocarbonylation of Alkenes via a Cooperative Strategy

(2017) Ming Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Access to Perfluoroalkyl-Substituted Enones and Indolin-2-ones via Multicomponent Pd-Catalyzed Carbonylative Reactions

(2017) Hongfei Yin et al.   JOURNAL OF ORGANIC CHEMISTRY

Natural Product Synthesis via Palladium-Catalyzed Carbonylation

(2017) Yu Bai et al.   JOURNAL OF ORGANIC CHEMISTRY

Efficient C(sp3)–H Bond Arylation of Tetrahydroisoquinolines with Knochel-Type Arylzinc Reagents under Oxidative Conditions

(2017) Zhihua Peng et al.   SYNLETT

Recent developments in the use of aza-Heck cyclizations for the synthesis of chiral N-heterocycles

(2017) Nicholas J. Race et al.   Chemical Science

Pd(ii)-Catalyzed oxidative dearomatization of indoles: substrate-controlled synthesis of indolines and indolones

(2017) Xinxin Fang et al.   Organic Chemistry Frontiers

Palladium(II)-Catalyzed Oxidative Difunctionalization of Alkenes: Bond Forming at a High-Valent Palladium Center

(2016) Guoyin Yin et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Cooperative Strategy for the Highly Selective Intermolecular Oxycarbonylation Reaction of Alkenes using a Palladium Catalyst

(2016) Ming Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Carbonylative Four-Component Synthesis of Thiochromenones: The Advantages of a Reagent Capsule

(2016) Chaoren Shen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Advances in Synthetic Applications of Hypervalent Iodine Compounds

(2016) Akira Yoshimura et al.   CHEMICAL REVIEWS

Pd(0)-Catalyzed Dearomative Diarylation of Indoles

(2016) David A. Petrone et al.   CHEMISTRY-A EUROPEAN JOURNAL

Total Synthesis of (−)-Spinosyn A via Carbonylative Macrolactonization

(2016) Yu Bai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Manganese-Catalyzed Carboacylations of Alkenes with Alkyl Iodides

(2016) Caitlin M. McMahon et al.   ORGANIC LETTERS

Carbonylations of Alkenes in the Total Synthesis of Natural Compounds

(2016) Ivana Fleischer et al.   SYNTHESIS-STUTTGART

Palladium-Catalyzed Intermolecular Aminocarbonylation of Alkenes: Efficient Access of β-Amino Acid Derivatives

(2015) Jiashun Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Regio- and Enantioselective Alkoxycarbonylative Amination of Terminal Allenes Catalyzed by a Spiroketal-Based Diphosphine/Pd(II) Complex

(2015) Jiawang Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Arylative Dearomatization of Indoles via Pd-Catalyzed Intramolecular Reductive Heck Reactions

(2015) Chong Shen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-Catalyzed Construction of Quinolin-2(1H)-ones via C–H Bond Activation of Simple Anilines with CO and Alkynes

(2015) Xinyao Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Umpolung Approach to Alkene Carboamination: Palladium Catalyzed 1,2-Amino-Acylation, -Carboxylation, -Arylation, -Vinylation, and -Alkynylation

(2015) Adele Faulkner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dearomative Indole Bisfunctionalization via a Diastereoselective Palladium-Catalyzed Arylcyanation

(2015) David A. Petrone et al.   ORGANIC LETTERS

Palladium-Catalyzed Carbonylative Cyclization of Aryl Alkenes/Alkenols: A New Reaction Mode for the Synthesis of Electron-Rich Chromanes

(2015) Shuang Li et al.   ORGANIC LETTERS

Recent advances in the transition metal catalyzed carbonylation of alkynes, arenes and aryl halides using CO surrogates

(2015) Prashant Gautam et al.   Catalysis Science & Technology

Carbonylation Reactions of Alkyl Iodides through the Interplay of Carbon Radicals and Pd Catalysts

(2014) Shuhei Sumino et al.   ACCOUNTS OF CHEMICAL RESEARCH

Transition-Metal-Catalyzed Carbonylation Reactions of Olefins and Alkynes: A Personal Account

(2014) Xiao-Feng Wu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Selective Aryl α-Diimine/Palladium-Catalyzed Bis-Alkoxy- carbonylation of Olefins for the Synthesis of Substituted Succinic Diesters

(2014) Francesco Fini et al.   ADVANCED SYNTHESIS & CATALYSIS

Metal-Free, Room-Temperature, Radical Alkoxycarbonylation of Aryldiazonium Salts through Visible-Light Photoredox Catalysis

(2014) Wei Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbonylations of Alkenes with CO Surrogates

(2014) Lipeng Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Vicinal Difunctionalization of Alkenes with Iodine(III) Reagents and Catalysts

(2014) R. Martín Romero et al.   Chemistry-An Asian Journal

A Novel Double Carbonylation Reaction of Aryl Halides: Selective Synthesis of 5-Arylfuranones

(2013) Johannes Schranck et al.   CHEMISTRY-A EUROPEAN JOURNAL

Domino Carbopalladation-Carbonylation: Investigation of Substrate Scope

(2012) Brinton Seashore-Ludlow et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Bis(alkoxycarbonylation) Reaction of Cyclic Olefins Catalyzed by Palladium in the Presence of Copper(I) Triflate

(2012) Takahiro Aratani et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Applied Hydroformylation

(2012) Robert Franke et al.   CHEMICAL REVIEWS

Efficient Construction of Fused Indolines with a 2-Quaternary Center via an Intramolecular Heck Reaction with a Low Catalyst Loading

(2012) Lei Zhao et al.   ORGANIC LETTERS

Progress in Carbonylative-Heck Reactions of Aryl Bromides: Catalysis and DFT Studies

(2011) Xiao-Feng Wu et al.   ChemCatChem

Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications

(2011) Richard I. McDonald et al.   CHEMICAL REVIEWS

Palladium-catalyzed carbonylative coupling reactions between Ar–X and carbon nucleophiles

(2011) Xiao-Feng Wu et al.   CHEMICAL SOCIETY REVIEWS

Vicinal C-Functionalization of Alkenes. Pd/Light-Induced Multicomponent Coupling Reactions Leading to Functionalized Esters and Lactones

(2011) Akira Fusano et al.   ORGANIC LETTERS

Carbonylative Heck Reactions Using CO Generatedex Situin a Two-Chamber System

(2011) Philippe Hermange et al.   ORGANIC LETTERS

A Thiourea-Oxazoline Library with Axial Chirality: Ligand Synthesis and Studies of the Palladium-Catalyzed Enantioselective Bis(methoxycarbonylation) of Terminal Olefins

(2010) Ying-Xiang Gao et al.   ADVANCED SYNTHESIS & CATALYSIS

Multicomponent Cascade Reactions: A Novel and Expedient Approach to Functionalized Indoles by an Unprecedented Nucleophilic Addition-Heterocyclization-Oxidative Alkoxycarbonylation Sequence

(2010) Bartolo Gabriele et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed Coupling Reactions: Carbonylative Heck Reactions To Give Chalcones

(2010) Xiao-Feng Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Development of a General Palladium-Catalyzed Carbonylative Heck Reaction of Aryl Halides

(2010) Xiao-Feng Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Domino Carbopalladation−Carbonylation: Generating Quaternary Stereocenters while Controlling β-Hydride Elimination

(2010) Brinton Seashore-Ludlow et al.   ORGANIC LETTERS

Diaryliodonium Salts: A Journey from Obscurity to Fame

(2009) Eleanor���A. Merritt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Intramolecular Oxidative Aminocarbonylation of Alkenylureas Catalyzed by Palladium−Spiro Bis(isoxazoline) Complexes

(2009) Tetsuya Tsujihara et al.   JOURNAL OF ORGANIC CHEMISTRY

Multicatalytic Synthesis of α-Pyrrolidinyl Ketones via a Tandem Palladium(II)/Indium(III)-Catalyzed Aminochlorocarbonylation/Friedel−Crafts Acylation Reaction

(2009) Tim A. Cernak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis at the molecular frontier

(2009) Paul A. Wender et al.   NATURE

Chemistry of Polyvalent Iodine

(2008) Viktor V. Zhdankin et al.   CHEMICAL REVIEWS

Mechanistic approaches to palladium-catalyzed alkene difunctionalization reactions

(2008) Katrina H. Jensen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY