Excess‐Li Localization Triggers Chemical Irreversibility in Li‐ and Mn‐Rich Layered Oxides

Unified picture of anionic redox in Li/Na-ion batteries

(2019) Mouna Ben Yahia et al.   NATURE MATERIALS

Mastering Surface Reconstruction of Metastable Spinel Oxides for Better Water Oxidation

(2019) Yan Duan et al.   ADVANCED MATERIALS

Dynamic imaging of crystalline defects in lithium-manganese oxide electrodes during electrochemical activation to high voltage

(2019) Qianqian Li et al.   Nature Communications

Effect of composition on the structure of lithium- and manganese-rich transition metal oxides

(2018) Alpesh Khushalchand Shukla et al.   Energy & Environmental Science

Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries

(2018) Gaurav Assat et al.   Nature Energy

Understanding voltage decay in lithium-excess layered cathode materials through oxygen-centred structural arrangement

(2018) Seungjun Myeong et al.   Nature Communications

Evolution of redox couples in Li- and Mn-rich cathode materials and mitigation of voltage fade by reducing oxygen release

(2018) Enyuan Hu et al.   Nature Energy

Activating lattice oxygen redox reactions in metal oxides to catalyse oxygen evolution

(2017) Alexis Grimaud et al.   Nature Chemistry

Evidence for anionic redox activity in a tridimensional-ordered Li-rich positive electrode β-Li2IrO3

(2017) Paul E. Pearce et al.   NATURE MATERIALS

Fundamental interplay between anionic/cationic redox governing the kinetics and thermodynamics of lithium-rich cathodes

(2017) Gaurav Assat et al.   Nature Communications

Direct observation of layered-to-spinel phase transformation in Li2MnO3 and the spinel structure stabilised after the activation process

(2017) Keiji Shimoda et al.   Journal of Materials Chemistry A

Simultaneous anionic and cationic redox

(2017) Sung-Kyun Jung et al.   Nature Energy

Quantitative Analysis of Transition-Metal Migration Induced Electrochemically in Lithium-Rich Layered Oxide Cathode and Its Contribution to Properties at High and Low Temperatures

(2016) Ikuma Takahashi et al.   Journal of Physical Chemistry C

Crystal and electronic structure analysis and thermodynamic stabilities for electrochemically or chemically delithiated Li 1.2−x Mn 0.54 Ni 0.13 Co 0.13 O 2

(2016) Naoya Ishida et al.   JOURNAL OF POWER SOURCES

The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials

(2016) Dong-Hwa Seo et al.   Nature Chemistry

Charge-compensation in 3d-transition-metal-oxide intercalation cathodes through the generation of localized electron holes on oxygen

(2016) Kun Luo et al.   Nature Chemistry

Gas–solid interfacial modification of oxygen activity in layered oxide cathodes for lithium-ion batteries

(2016) Bao Qiu et al.   Nature Communications

Li- and Mn-Rich Cathode Materials: Challenges to Commercialization

(2016) Jianming Zheng et al.   Advanced Energy Materials

Direct observation of reversible oxygen anion redox reaction in Li-rich manganese oxide, Li2MnO3, studied by soft X-ray absorption spectroscopy

(2016) Masatsugu Oishi et al.   Journal of Materials Chemistry A

Probing the Degradation Mechanism of Li2MnO3 Cathode for Li-Ion Batteries

(2015) Pengfei Yan et al.   CHEMISTRY OF MATERIALS

A new active Li–Mn–O compound for high energy density Li-ion batteries

(2015) M. Freire et al.   NATURE MATERIALS

Unravelling structural ambiguities in lithium- and manganese-rich transition metal oxides

(2015) Alpesh Khushalchand Shukla et al.   Nature Communications

The origins and mechanism of phase transformation in bulk Li2MnO3: first-principles calculations and experimental studies

(2015) Jin-Myoung Lim et al.   Journal of Materials Chemistry A

Evolution of Lattice Structure and Chemical Composition of the Surface Reconstruction Layer in Li1.2Ni0.2Mn0.6O2 Cathode Material for Lithium Ion Batteries

(2014) Pengfei Yan et al.   NANO LETTERS

Structural and Chemical Evolution of the Layered Li-Excess Li x MnO3 as a Function of Li Content from First-Principles Calculations

(2014) Eunseok Lee et al.   Advanced Energy Materials

Recent progress in Li-rich layered oxides as cathode materials for Li-ion batteries

(2014) Jianhua Yan et al.   RSC Advances

High Performance Li2Ru1–yMnyO3 (0.2 ≤ y ≤ 0.8) Cathode Materials for Rechargeable Lithium-Ion Batteries: Their Understanding

(2013) M. Sathiya et al.   CHEMISTRY OF MATERIALS

Nanoscale Phase Separation, Cation Ordering, and Surface Chemistry in Pristine Li1.2Ni0.2Mn0.6O2 for Li-Ion Batteries

(2013) Meng Gu et al.   CHEMISTRY OF MATERIALS

Correlation Between Oxygen Vacancy, Microstrain, and Cation Distribution in Lithium-Excess Layered Oxides During the First Electrochemical Cycle

(2013) Christopher R. Fell et al.   CHEMISTRY OF MATERIALS

The Li-Ion Rechargeable Battery: A Perspective

(2013) John B. Goodenough et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible anionic redox chemistry in high-capacity layered-oxide electrodes

(2013) M. Sathiya et al.   NATURE MATERIALS

Understanding the Rate Capability of High-Energy-Density Li-Rich Layered Li1.2 Ni0.15 Co0.1 Mn0.55 O2 Cathode Materials

(2013) Xiqian Yu et al.   Advanced Energy Materials

Formation of the Spinel Phase in the Layered Composite Cathode Used in Li-Ion Batteries

(2012) Meng Gu et al.   ACS Nano

Critical Role of Oxygen Evolved from Layered Li–Excess Metal Oxides in Lithium Rechargeable Batteries

(2012) Jihyun Hong et al.   CHEMISTRY OF MATERIALS

Detailed Studies of a High-Capacity Electrode Material for Rechargeable Batteries, Li2MnO3−LiCo1/3Ni1/3Mn1/3O2

(2011) Naoaki Yabuuchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrical Energy Storage for the Grid: A Battery of Choices

(2011) B. Dunn et al.   SCIENCE

Challenges for Rechargeable Li Batteries†

(2009) John B. Goodenough et al.   CHEMISTRY OF MATERIALS

Building better batteries

(2008) M. Armand et al.   NATURE