Journal
ACS OMEGA
Volume 5, Issue 19, Pages 11035-11042Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsomega.0c00860
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Funding
- JSPS KAKENHI [JP19F18322, JP18H01154]
- National Science Center [UMO-2018/30/A/ST3/00323]
- Vietnam National Foundation for Science and Technology Development (NAFOSTED) [103.01-2019.318]
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We develop the elastically collective nonlinear Langevin equation theory of bulk relaxation of glass-forming liquids to investigate molecular mobility under compression conditions. The applied pressure restricts more molecular motion and therefore significantly slows down the molecular dynamics when increasing the pressure. We quantitatively determine the temperature and pressure dependence of the structural relaxation time. To validate our model, dielectric spectroscopy experiments for three rigid and nonpolymeric supramolecules are carried out at ambient and elevated pressures. The numerical results quantitatively agree with experimental data.
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