Journal
CHEMSUSCHEM
Volume 9, Issue 13, Pages 1565-1569Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201600197
Keywords
alginate; carbocatalysis; graphene; hydrogenation; metal-free catalyst
Funding
- Spanish Ministry of Economy and Competitiveness [CTQ2015-69153]
- Generalidad Valenciana [Prometeo 2013-14]
- UEFISCDI through the PN-II-ID-PCE project [275/05/10/2011]
- Spanish Ministry of Economy and Competitiveness
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Graphene obtained by pyrolysis of alginate at 900 degrees C under inert atmosphere and exfoliation is used as a metal-free catalyst for reduction of nitro to amino groups with hydrogen as a reagent. The process is general for aromatic and aliphatic, conjugated and isolated nitro groups, and occurs with low selectivity over hydrogenation of carbon-carbon double bonds.
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