Functional Group Interconversion: Decarbonylative Borylation of Esters for the Synthesis of Organoboronates

Nickel-Catalyzed Decarbonylative Borylation of Amides: Evidence for Acyl C−N Bond Activation

(2016) Jiefeng Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Decarbonylative Silylation of Esters by Combined Nickel and Copper Catalysis for the Synthesis of Arylsilanes and Heteroarylsilanes

(2016) Lin Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis Acid Assisted Nickel-Catalyzed Cross-Coupling of Aryl Methyl Ethers by C−O Bond-Cleaving Alkylation: Prevention of Undesired β-Hydride Elimination

(2016) Xiangqian Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Activation of Acyl C−O Bonds of Methyl Esters

(2016) Liana Hie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Preparing (Multi)Fluoroarenes as Building Blocks for Synthesis: Nickel-Catalyzed Borylation of Polyfluoroarenes via C–F Bond Cleavage

(2016) Jing Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Scalable, Metal- and Additive-Free, Photoinduced Borylation of Haloarenes and Quaternary Arylammonium Salts

(2016) Adelphe M. Mfuh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Decarbonylative Borylation and Silylation of Esters

(2016) Xinghui Pu et al.   ACS Catalysis

Nickel-Catalyzed Csp2–Csp3 Cross-Coupling via C–O Bond Activation

(2016) Lin Guo et al.   ACS Catalysis

Nickel catalyzed dealkoxylative Csp2–Csp3 cross coupling reactions – stereospecific synthesis of allylsilanes from enol ethers

(2015) Lin Guo et al.   CHEMICAL COMMUNICATIONS

Making Dimethylamino a Transformable Directing Group by Nickel-Catalyzed CN Borylation

(2015) Hua Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reaction Mechanism of the Anomalous Formal Nucleophilic Borylation of Organic Halides with Silylborane: Combined Theoretical and Experimental Studies

(2015) Ryohei Uematsu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ipso-Borylation of Aryl Ethers via Ni-Catalyzed C–OMe Cleavage

(2015) Cayetana Zarate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni/Cu-Catalyzed Defluoroborylation of Fluoroarenes for Diverse C–F Bond Functionalizations

(2015) Takashi Niwa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Borylation of Aryl Fluorides via C–F Cleavage

(2015) Xiang-Wei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decarbonylative organoboron cross-coupling of esters by nickel catalysis

(2015) Kei Muto et al.   Nature Communications

Metal catalyzed cross-coupling of aryl and benzyl methyl sulfides: nickel catalyzed Caryl–Csp3 and Csp3–Csp3 bond formations

(2015) Matthias Leiendecker et al.   Organic Chemistry Frontiers

Metal-Catalyzed Dealkoxylative CarylC sp 3 Cross-Coupling-Replacement of Aromatic Methoxy Groups of Aryl Ethers by Employing a Functionalized Nucleophile

(2014) Matthias Leiendecker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Reductive and Borylative Cleavage of Aromatic Carbon–Nitrogen Bonds in N-Aryl Amides and Carbamates

(2014) Mamoru Tobisu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Application of Cooperative Iron/Copper Catalysis to a Palladium-Free Borylation of Aryl Bromides with Pinacolborane

(2014) Flavien Labre et al.   ORGANIC LETTERS

Design, Generation, and Synthetic Application of Borylzincate: Borylation of Aryl Halides and Borylzincation of Benzynes/Terminal Alkyne

(2013) Yuki Nagashima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Scope of the Two-Step, One-Pot Palladium-Catalyzed Borylation/Suzuki Cross-Coupling Reaction Utilizing Bis-Boronic Acid

(2012) Gary A. Molander et al.   JOURNAL OF ORGANIC CHEMISTRY

Anomalous Reactivity of Silylborane: Transition-Metal-Free Boryl Substitution of Aryl, Alkenyl, and Alkyl Halides with Silylborane/Alkoxy Base Systems

(2012) Eiji Yamamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decarbonylative C–H Coupling of Azoles and Aryl Esters: Unprecedented Nickel Catalysis and Application to the Synthesis of Muscoride A

(2012) Kazuma Amaike et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-Metal-Free Borylation of Aryltriazene Mediated by BF3·OEt2

(2012) Chuan Zhu et al.   ORGANIC LETTERS

Rhodium-Catalyzed Cross-Coupling Reactions of Carboxylate and Organoboron Compounds via Chelation-Assisted C–C Bond Activation

(2012) Jingjing Wang et al.   ORGANOMETALLICS

Carboxylates as sources of carbon nucleophiles and electrophiles: comparison of decarboxylative and decarbonylative pathways

(2012) Wojciech I. Dzik et al.   Chemical Science

Use of Hemilabile N,N Ligands in Nitrogen-Directed Iridium-Catalyzed Borylations of Arenes

(2011) Abel Ros et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Borylation of Aryl Mesylates and Tosylates and Their Applications in One-Pot Sequential Suzuki-Miyaura Biaryl Synthesis

(2011) Wing Kin Chow et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rh-CatalyzedOrtho-Selective C–H Borylation ofN-Functionalized Arenes with Silica-Supported Bridgehead Monophosphine Ligands

(2011) Soichiro Kawamorita et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Oxidative ortho-C–H Borylation of Arenes

(2011) Hui-Xiong Dai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(I)-Catalyzed Borylation of Nitriles through the Cleavage of Carbon–Cyano Bonds

(2011) Mamoru Tobisu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Monophosphorus Ligands for Palladium-Catalyzed Miyaura Borylation

(2011) Wenjun Tang et al.   ORGANIC LETTERS

NiCl2(PMe3)2-Catalyzed Borylation of Aryl Chlorides

(2011) Tetsuya Yamamoto et al.   ORGANIC LETTERS

Direct Conversion of Arylamines to Pinacol Boronates: A Metal-Free Borylation Process

(2010) Fanyang Mo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Borylation of Aryl and Alkenyl Carbamates through Ni-Catalyzed CO Activation

(2010) Kun Huang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Neopentylglycolborylation ofortho-Substituted Aryl Halides Catalyzed by NiCl2-Based Mixed-Ligand Systems

(2010) Costel Moldoveanu et al.   JOURNAL OF ORGANIC CHEMISTRY

An Opportunity for Mg-Catalyzed Grignard-Type Reactions: Direct Coupling of Benzylic Halides with Pinacolborane with 10 mol % of Magnesium

(2010) Christine Pintaric et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Neopentylglycolborylation of Aryl Mesylates and Tosylates Catalyzed by Ni-Based Mixed-Ligand Systems Activated with Zn

(2010) Daniela A. Wilson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed, Direct Boronic Acid Synthesis from Aryl Chlorides: A Simplified Route to Diverse Boronate Ester Derivatives

(2010) Gary A. Molander et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Facile Route to Aryl Boronates: Room-Temperature, Copper-Catalyzed Borylation of Aryl Halides with Alkoxy Diboron Reagents

(2009) Christian Kleeberg et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Catalyzed Reactions of Organoboronic Acids and Esters

(2008) Norio Miyaura   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN