4.8 Article

Enhancing fuel transport in air-breathing microfluidic fuel cells by immersed fuel micro-jet

Journal

JOURNAL OF POWER SOURCES
Volume 445, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.jpowsour.2019.227326

Keywords

Microfluidic fuel cells; Fuel concentration boundary layer; Fuel transport; Immersed micro-jet; Cell performance

Funding

  1. International Cooperation and Exchange of the National Natural Science Foundation of China [51620105011]
  2. National Natural Science Foundation of China [51776026]
  3. Program for Back-up Talent Development of Chongqing University [cqu2017hbrc1B06]
  4. Innovation Support Foundation for Returned Overseas Scholars, Chongqing, China [cx2017058]
  5. Fundamental Research Funds for the Central Universities [2018CDXYDL0001]
  6. High Level Foreign Experts program - Ministry of Science and Technology, P.R. China [G20190022001]

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Air-breathing microfluidic fuel cells with flow-over planar anodes can facilitate system integration but suffer from the fuel concentration boundary layer over the anode, which significantly hinders the fuel transport and limit cell performance. A novel approach is proposed to actively replenish the fuel concentration boundary layer by immersed fuel micro-jet, where part of the fresh fuel is jetted perpendicular to the anode, enabling targeted fuel transfer enhancement. The immersed fuel micro jet is visualized by fluorescence microscopy, and the micro-jet can reach and flow along the anode at optimal condition. The same cell architecture is tested in both the flow-over and micro-jet modes. The electrochemical measurement and preliminary modelling results indicate that the fuel transfer limitation can be largely mitigated by fuel micro-jet, and the cell performance is enhanced accordingly. The micro-jet located at the middle of flow channel can balance the trade-off between replenishment and benefitted anode area. The effect of total fuel flow rate and micro-jet/lateral flow rate ratio on the fuel transport and cell performance are also discussed in detail. As compared with the flow-over mode, the maximum performance improvement of 40.9% is achieved by the immersed fuel micro-jet, and the optimal power density reaches 119.3 mW cm(-3).

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