Lessons from intramolecular singlet fission with covalently bound chromophores

Spatial separation of triplet excitons drives endothermic singlet fission

(2020) Nadezhda V. Korovina et al.   Nature Chemistry

Using Structurally Well-Defined Norbornyl-Bridged Acene Dimers to Map a Mechanistic Landscape for Correlated Triplet Formation in Singlet Fission

(2019) Alexander T. Gilligan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Emerging Design Principles for Enhanced Solar Energy Utilization with Singlet Fission

(2019) Melissa K. Gish et al.   Journal of Physical Chemistry C

Singlet Fission from Upper Excited Electronic States of Cofacial Perylene Dimer

(2019) Wenjun Ni et al.   Journal of Physical Chemistry Letters

Quintet-triplet mixing determines the fate of the multiexciton state produced by singlet fission in a terrylenediimide dimer at room temperature

(2019) Michelle Chen et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Heavy-atom effects on intramolecular singlet fission in a conjugated polymer

(2019) Andrew J. Musser et al.   JOURNAL OF CHEMICAL PHYSICS

Exergonic Intramolecular Singlet Fission of an Adamantane-Linked Tetracene Dyad via Twin Quintet Multiexcitons

(2019) Yasunori Matsui et al.   Journal of Physical Chemistry C

Intramolecular versus Intermolecular Triplet Fusion in Multichromophoric Photochemical Upconversion

(2019) Can Gao et al.   Journal of Physical Chemistry C

Sensitization of silicon by singlet exciton fission in tetracene

(2019) Markus Einzinger et al.   NATURE

Understanding the Bound Triplet-Pair State in Singlet Fission

(2019) Samuel N. Sanders et al.   Chem

Exploiting Excited-State Aromaticity To Design Highly Stable Singlet Fission Materials

(2019) Kealan J. Fallon et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ultra-fast intramolecular singlet fission to persistent multiexcitons by molecular design

(2019) Andrew B. Pun et al.   Nature Chemistry

Singlet Fission in Tetraaza-TIPS-Pentacene Oligomers: From fs Excitation to μs Triplet Decay via the Biexcitonic State

(2019) Nicolò Alagna et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Slow charge transfer from pentacene triplet states at the Marcus optimum

(2019) Natalie A. Pace et al.   Nature Chemistry

Exploiting Singlet Fission in Organic Light-Emitting Diodes

(2018) Ryo Nagata et al.   ADVANCED MATERIALS

Conformational Planarization versus Singlet Fission: Distinct Excited-State Dynamics of Cyclooctatetraene-Fused Acene Dimers

(2018) Takuya Yamakado et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Theoretical Modeling of Singlet Fission

(2018) David Casanova   CHEMICAL REVIEWS

Frontispiece: Pentacene Dimers as a Critical Tool for the Investigation of Intramolecular Singlet Fission

(2018) Constantin Hetzer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct Observation of Correlated Triplet Pair Dynamics during Singlet Fission Using Ultrafast Mid-IR Spectroscopy

(2018) Christopher Grieco et al.   Journal of Physical Chemistry C

Singlet Fission Mediated Photophysics of BODIPY Dimers

(2018) Raúl Montero et al.   Journal of Physical Chemistry Letters

Multiexciton Dynamics Depending on Intramolecular Orientations in Pentacene Dimers: Recombination and Dissociation of Correlated Triplet Pairs

(2018) Hayato Sakai et al.   Journal of Physical Chemistry Letters

Linker-Dependent Singlet Fission in Tetracene Dimers

(2018) Nadezhda V. Korovina et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enacting Two-Electron Transfer from a Double-Triplet State of Intramolecular Singlet Fission

(2018) Hyungjun Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Singlet Fission Involves an Interplay between Energetic Driving Force and Electronic Coupling in Perylenediimide Films

(2018) Aaron K. Le et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Control of Energy Flow Dynamics between Tetracene Ligands and PbS Quantum Dots by Size Tuning and Ligand Coverage

(2018) Daniel M. Kroupa et al.   NANO LETTERS

Endothermic singlet fission is hindered by excimer formation

(2018) Cameron B. Dover et al.   Nature Chemistry

Intramolecular singlet fission in a face-to-face stacked tetracene trimer

(2018) Xuemin Wang et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Dynamics of singlet fission and electron injection in self-assembled acene monolayers on titanium dioxide

(2018) Natalie A. Pace et al.   Chemical Science

Femtosecond stimulated Raman evidence for charge-transfer character in pentacene singlet fission

(2018) Stephanie M. Hart et al.   Chemical Science

Morphology-Independent Efficient Singlet Exciton Fission in Perylene Diimide Thin Films

(2018) Yaroslav V. Aulin et al.   ChemPlusChem

Singlet exciton fission in a linear tetracene tetramer

(2018) Heyuan Liu et al.   Journal of Materials Chemistry C

Evidence for Charge-Transfer Mediation in the Primary Events of Singlet Fission in a Weakly Coupled Pentacene Dimer

(2018) Bettina S. Basel et al.   Chem

New insights into the design of conjugated polymers for intramolecular singlet fission

(2018) Jiahua Hu et al.   Nature Communications

Singlet Fission in Perylenediimide Dimers

(2018) Marwa H. Farag et al.   Journal of Physical Chemistry C

Two-Dimensional Electronic Spectroscopy Reveals Excitation Energy-Dependent State Mixing during Singlet Fission in a Terrylenediimide Dimer

(2018) Aritra Mandal et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Spin density encodes intramolecular singlet exciton fission in pentacene dimers

(2018) K. C. Krishnapriya et al.   Nature Communications

Quantitative Sequential Photoenergy Conversion Process from Singlet Fission to Intermolecular Two-Electron Transfers Utilizing Tetracene Dimer

(2018) Shunta Nakamura et al.   ACS Energy Letters

Excimer Formation and Symmetry-Breaking Charge Transfer in Cofacial Perylene Dimers

(2017) Rita E. Cook et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Modeling Singlet Fission in Rylene and Diketopyrrolopyrrole Derivatives: The Role of the Charge Transfer State in Superexchange and Excimer Formation

(2017) Claire E. Miller et al.   Journal of Physical Chemistry C

Controlling Long-Lived Triplet Generation from Intramolecular Singlet Fission in the Solid State

(2017) Natalie A. Pace et al.   Journal of Physical Chemistry Letters

Simple Rule To Predict Boundedness of Multiexciton States in Covalently Linked Singlet-Fission Dimers

(2017) Vibin Abraham et al.   Journal of Physical Chemistry Letters

Tuning Singlet Fission in π-Bridge-π Chromophores

(2017) Elango Kumarasamy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Triplet Separation Drives Singlet Fission after Femtosecond Correlated Triplet Pair Production in Rubrene

(2017) Ilana Breen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Covalently Linked Tetracene Trimer: Synthesis and Singlet Exciton Fission Property

(2017) Heyuan Liu et al.   ORGANIC LETTERS

Singlet fission in pancake-bonded systems

(2017) S. Ito et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Photophysical characterization and time-resolved spectroscopy of a anthradithiophene dimer: exploring the role of conformation in singlet fission

(2017) Jacob C. Dean et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Origins of Singlet Fission in Solid Pentacene from an ab initio Green’s Function Approach

(2017) Sivan Refaely-Abramson et al.   PHYSICAL REVIEW LETTERS

Unified model for singlet fission within a non-conjugated covalent pentacene dimer

(2017) Bettina S. Basel et al.   Nature Communications

The entangled triplet pair state in acene and heteroacene materials

(2017) Chaw Keong Yong et al.   Nature Communications

Distinct properties of the triplet pair state from singlet fission

(2017) M. Tuan Trinh et al.   Science Advances

Excitation Localization/Delocalization Isomerism in a Strongly Coupled Covalent Dimer of 1,3-Diphenylisobenzofuran

(2016) Joel N. Schrauben et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Solution-Phase Singlet Fission in a Structurally Well-Defined Norbornyl-Bridged Tetracene Dimer

(2016) Jasper D. Cook et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Long-Lived Triplet Excited States of Bent-Shaped Pentacene Dimers by Intramolecular Singlet Fission

(2016) Takao Sakuma et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Intra- and Intermolecular Singlet Fission in Covalently Linked Dimers

(2016) Xintian Feng et al.   Journal of Physical Chemistry C

Slow Singlet Fission Observed in a Polycrystalline Perylenediimide Thin Film

(2016) Aaron K. Le et al.   Journal of Physical Chemistry Letters

Observation of Two Triplet-Pair Intermediates in Singlet Exciton Fission

(2016) Ryan D. Pensack et al.   Journal of Physical Chemistry Letters

Exciton Correlations in Intramolecular Singlet Fission

(2016) Samuel N. Sanders et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Observation of a Charge-Transfer State Preceding High-Yield Singlet Fission in Terrylenediimide Thin Films

(2016) Eric A. Margulies et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Singlet Fission in a Covalently Linked Cofacial Alkynyltetracene Dimer

(2016) Nadezhda V. Korovina et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamic Exchange During Triplet Transport in Nanocrystalline TIPS-Pentacene Films

(2016) Christopher Grieco et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Singlet Fission via an Excimer-Like Intermediate in 3,6-Bis(thiophen-2-yl)diketopyrrolopyrrole Derivatives

(2016) Catherine M. Mauck et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Solution-based intramolecular singlet fission in cross-conjugated pentacene dimers

(2016) Johannes Zirzlmeier et al.   Nanoscale

Enabling singlet fission by controlling intramolecular charge transfer in π-stacked covalent terrylenediimide dimers

(2016) Eric A. Margulies et al.   Nature Chemistry

Strongly exchange-coupled triplet pairs in an organic semiconductor

(2016) Leah R. Weiss et al.   Nature Physics

Quintet multiexciton dynamics in singlet fission

(2016) Murad J. Y. Tayebjee et al.   Nature Physics

On couplings and excimers: lessons from studies of singlet fission in covalently linked tetracene dimers

(2016) Xintian Feng et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Tuning the role of charge-transfer states in intramolecular singlet exciton fission through side-group engineering

(2016) Steven Lukman et al.   Nature Communications

A Direct Mechanism of Ultrafast Intramolecular Singlet Fission in Pentacene Dimers

(2016) Eric G. Fuemmeler et al.   ACS Central Science

Singlet Fission in Polypentacene

(2016) Samuel N. Sanders et al.   Chem

Photocurrent Enhanced by Singlet Fission in a Dye-Sensitized Solar Cell

(2015) Joel N. Schrauben et al.   ACS Applied Materials & Interfaces

Tuneable Singlet Exciton Fission and Triplet-Triplet Annihilation in an Orthogonal Pentacene Dimer

(2015) Steven Lukman et al.   ADVANCED FUNCTIONAL MATERIALS

Charge Transfer–Mediated Singlet Fission

(2015) N. Monahan et al.   Annual Review of Physical Chemistry

Guidance for Mutual Disposition of Chromophores for Singlet Fission

(2015) Zdenek Havlas et al.   ISRAEL JOURNAL OF CHEMISTRY

Structure and Dynamics of the 1(TT) State in a Quinoidal Bithiophene: Characterizing a Promising Intramolecular Singlet Fission Candidate

(2015) Alan D. Chien et al.   Journal of Physical Chemistry C

Beyond Shockley–Queisser: Molecular Approaches to High-Efficiency Photovoltaics

(2015) Murad J. Y. Tayebjee et al.   Journal of Physical Chemistry Letters

Intermolecular Vibrational Modes Speed Up Singlet Fission in Perylenediimide Crystals

(2015) Nicolas Renaud et al.   Journal of Physical Chemistry Letters

How Morphology Affects Singlet Fission in Crystalline Tetracene

(2015) Geoffrey B. Piland et al.   Journal of Physical Chemistry Letters

High Yield Ultrafast Intramolecular Singlet Exciton Fission in a Quinoidal Bithiophene

(2015) Oleg Varnavski et al.   Journal of Physical Chemistry Letters

Ultrafast Singlet Fission in a Push–Pull Low-Bandgap Polymer Film

(2015) Yukitomo Kasai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Quantitative Intramolecular Singlet Fission in Bipentacenes

(2015) Samuel N. Sanders et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Exciton Delocalization Drives Rapid Singlet Fission in Nanoparticles of Acene Derivatives

(2015) Ryan D. Pensack et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A design strategy for intramolecular singlet fission mediated by charge-transfer states in donor–acceptor organic materials

(2015) Erik Busby et al.   NATURE MATERIALS

Singlet fission of hot excitons in  -conjugated polymers

(2015) Y. Zhai et al.   PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES

Synthesis and photophysical properties of a “face-to-face” stacked tetracene dimer

(2015) Heyuan Liu et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Singlet fission in pentacene dimers

(2015) Johannes Zirzlmeier et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Exploring Non-Condon Effects in a Covalent Tetracene Dimer: How Important Are Vibrations in Determining the Electronic Coupling for Singlet Fission?

(2014) Ethan C. Alguire et al.   JOURNAL OF PHYSICAL CHEMISTRY A

A Simple Kinetic Model for Singlet Fission: A Role of Electronic and Entropic Contributions to Macroscopic Rates

(2014) Anatoly B. Kolomeisky et al.   Journal of Physical Chemistry C

Two Thin Film Polymorphs of the Singlet Fission Compound 1,3-Diphenylisobenzofuran

(2014) Joseph L. Ryerson et al.   Journal of Physical Chemistry C

Theoretical Investigation of Singlet Fission in Molecular Dimers: The Role of Charge Transfer States and Quantum Interference

(2014) Fatemeh Mirjani et al.   Journal of Physical Chemistry C

Direct Observation of Ultrafast Excimer Formation in Covalent Perylenediimide Dimers Using Near-Infrared Transient Absorption Spectroscopy

(2014) Kristen E. Brown et al.   Journal of Physical Chemistry Letters

Captodatively Stabilized Biradicaloids as Chromophores for Singlet Fission

(2014) Jin Wen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Singlet Fission in Thin Films of 1,3-Diphenylisobenzofuran

(2014) Joel N. Schrauben et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A transferable model for singlet-fission kinetics

(2014) Shane R. Yost et al.   Nature Chemistry

Resonant energy transfer of triplet excitons from pentacene to PbSe nanocrystals

(2014) Maxim Tabachnyk et al.   NATURE MATERIALS

Energy harvesting of non-emissive triplet excitons in tetracene by emissive PbS nanocrystals

(2014) Nicholas J. Thompson et al.   NATURE MATERIALS

Excimer formation in cofacial and slip-stacked perylene-3,4:9,10-bis(dicarboximide) dimers on a redox-inactive triptycene scaffold

(2014) Eric A. Margulies et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

The Quantum Coherent Mechanism for Singlet Fission: Experiment and Theory

(2013) Wai-Lun Chan et al.   ACCOUNTS OF CHEMICAL RESEARCH

The Dynamics of Singlet Fission in Crystalline Tetracene and Covalent Analogs

(2013) Jonathan J. Burdett et al.   ACCOUNTS OF CHEMICAL RESEARCH

Singlet Exciton Fission in a Hexacene Derivative

(2013) Jiye Lee et al.   ADVANCED MATERIALS

Recent Advances in Singlet Fission

(2013) Millicent B. Smith et al.   Annual Review of Physical Chemistry

Triplet State Formation in Photoexcited Slip-Stacked Perylene-3,4:9,10-bis(dicarboximide) Dimers on a Xanthene Scaffold

(2013) Kelly M. Lefler et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Tunable Electronic Coupling and Driving Force in Structurally Well-Defined Tetracene Dimers for Molecular Singlet Fission: A Computational Exploration Using Density Functional Theory

(2013) Paul J. Vallett et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Toward Designed Singlet Fission: Solution Photophysics of Two Indirectly Coupled Covalent Dimers of 1,3-Diphenylisobenzofuran

(2013) Justin C. Johnson et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Mapping the Relation between Stacking Geometries and Singlet Fission Yield in a Class of Organic Crystals

(2013) Nicolas Renaud et al.   Journal of Physical Chemistry Letters

Activated Singlet Exciton Fission in a Semiconducting Polymer

(2013) Andrew J. Musser et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Singlet Exciton Fission in Polycrystalline Thin Films of a Slip-Stacked Perylenediimide

(2013) Samuel W. Eaton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Crystal Engineering: From Molecule to Crystal

(2013) Gautam R. Desiraju   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Singlet exciton fission in solution

(2013) Brian J. Walker et al.   Nature Chemistry

Charge-Transfer Excitations Steer the Davydov Splitting and Mediate Singlet Exciton Fission in Pentacene

(2013) D. Beljonne et al.   PHYSICAL REVIEW LETTERS

External Quantum Efficiency Above 100% in a Singlet-Exciton-Fission-Based Organic Photovoltaic Cell

(2013) D. N. Congreve et al.   SCIENCE

Quantum Control over Single Spins in Diamond

(2013) V.V. Dobrovitski et al.   Annual Review of Condensed Matter Physics

Enhanced external quantum efficiency in an organic photovoltaic cell via singlet fission exciton sensitizer

(2012) P. D. Reusswig et al.   APPLIED PHYSICS LETTERS

Thermodynamic Limit of Exciton Fission Solar Cell Efficiency

(2012) Murad J. Y. Tayebjee et al.   Journal of Physical Chemistry Letters

Efficient Singlet Fission Discovered in a Disordered Acene Film

(2012) Sean T. Roberts et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Harvesting Singlet Fission for Solar Energy Conversion: One- versus Two-Electron Transfer from the Quantum Mechanical Superposition

(2012) Wai-Lun Chan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Quantum Beats in Crystalline Tetracene Delayed Fluorescence Due to Triplet Pair Coherences Produced by Direct Singlet Fission

(2012) Jonathan J. Burdett et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The energy barrier in singlet fission can be overcome through coherent coupling and entropic gain

(2012) Wai-Lun Chan et al.   Nature Chemistry

The dependence of singlet exciton relaxation on excitation density and temperature in polycrystalline tetracene thin films: Kinetic evidence for a dark intermediate state and implications for singlet fission

(2011) Jonathan J. Burdett et al.   JOURNAL OF CHEMICAL PHYSICS

Competition between Singlet Fission and Charge Separation in Solution-Processed Blend Films of 6,13-Bis(triisopropylsilylethynyl)pentacene with Sterically-Encumbered Perylene-3,4:9,10-bis(dicarboximide)s

(2011) Charusheela Ramanan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ultrafast Dynamics of Exciton Fission in Polycrystalline Pentacene

(2011) Mark W. B. Wilson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Singlet Exciton Fission in Nanostructured Organic Solar Cells

(2011) Priya J. Jadhav et al.   NANO LETTERS

Dimers of Anthrathiophene and Anthradithiophene Derivatives: Synthesis and Characterization

(2011) Jean-Yves Balandier et al.   ORGANIC LETTERS

Photophysics of pentacene thin films: The role of exciton fission and heating effects

(2011) Akshay Rao et al.   PHYSICAL REVIEW B

Observing the Multiexciton State in Singlet Fission and Ensuing Ultrafast Multielectron Transfer

(2011) W.-L. Chan et al.   SCIENCE

Singlet Fission

(2010) Millicent B. Smith et al.   CHEMICAL REVIEWS

Maximizing Singlet Fission in Organic Dimers: Theoretical Investigation of Triplet Yield in the Regime of Localized Excitation and Fast Coherent Electron Transfer†

(2010) Eric C. Greyson et al.   JOURNAL OF PHYSICAL CHEMISTRY B

High-Yield Singlet Fission in a Zeaxanthin Aggregate Observed by Picosecond Resonance Raman Spectroscopy

(2010) Chen Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High Triplet Yield from Singlet Fission in a Thin Film of 1,3-Diphenylisobenzofuran

(2010) Justin C. Johnson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enhanced Triplet Formation in Polycrystalline Tetracene Films by Femtosecond Optical-Pulse Shaping

(2010) Erik M. Grumstrup et al.   PHYSICAL REVIEW LETTERS

Ultrafast singlet and triplet dynamics in microcrystalline pentacene films

(2009) Henning Marciniak et al.   PHYSICAL REVIEW B

Excited Singlet States of Covalently Bound, Cofacial Dimers and Trimers of Perylene-3,4:9,10-bis(dicarboximide)s

(2008) Jovan M. Giaimo et al.   JOURNAL OF PHYSICAL CHEMISTRY A