Switch in Selectivity for Formal Hydroalkylation of 1,3-Dienes and Enynes with Simple Hydrazones

Direct dehydrogenative alkyl Heck-couplings of vinylarenes with umpolung aldehydes catalyzed by nickel

(2019) Leiyang Lv et al.   Nature Communications

CuH-Catalyzed Enantioselective Ketone Allylation with 1,3-Dienes: Scope, Mechanism, and Applications

(2019) Chengxi Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Hydrothiolation: Counterion-Controlled Regioselectivity

(2019) Xiao-Hui Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

(CDC)-Rhodium-Catalyzed Hydroallylation of Vinylarenes and 1,3-Dienes with Allyl Trifluoroborates.

(2019) Justin S. Marcum et al.   ACS Catalysis

An Old Dog with New Tricks: Enjoin Wolff–Kishner Reduction for Alcohol Deoxygenation and C–C Bond Formations

(2019) Chao-Jun Li et al.   SYNLETT

Nickel-Catalyzed Regioselective Hydrobenzylation of 1,3-Dienes with Hydrazones

(2019) Leiyang Lv et al.   ACS Catalysis

Divergent Strategy in Natural Product Total Synthesis

(2018) Lei Li et al.   CHEMICAL REVIEWS

Intermolecular Metal-Catalyzed Reductive Coupling of Dienes, Allenes, and Enynes with Carbonyl Compounds and Imines

(2018) Michael Holmes et al.   CHEMICAL REVIEWS

Selective [1,4]-Hydrovinylation of 1,3-Dienes with Unactivated Olefins Enabled by Iron Diimine Catalysts

(2018) Valerie A. Schmidt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Intermolecular Pd-Catalyzed Hydroalkylation of Acyclic 1,3-Dienes with Activated Pronucleophiles

(2018) Nathan J. Adamson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-catalyzed enantioselective 1,2-borylation of 1,3-dienes

(2018) Yangbin Liu et al.   Chemical Science

Cross-Coupling of Phenol Derivatives with Umpolung Aldehydes Catalyzed by Nickel

(2018) Leiyang Lv et al.   ACS Catalysis

Catalytic Hydrothiolation: Regio- and Enantioselective Coupling of Thiols and Dienes

(2018) Xiao-Hui Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel(0)-Catalyzed Hydroalkylation of 1,3-Dienes with Simple Ketones

(2018) Lei Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Umpolung of Carbonyl Groups as Alkyl Organometallic Reagent Surrogates for Palladium-Catalyzed Allylic Alkylation

(2018) Dianhu Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular Hydroamination of 1,3-Dienes To Generate Homoallylic Amines

(2017) Xiao-Hui Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Intermolecular Addition of Aliphatic Amines to Acyclic Dienes with a Pd–PHOX Catalyst

(2017) Nathan J. Adamson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Pincer Carbodicarbene Ligands for Enantioselective Rhodium-Catalyzed Hydroarylation of Terminal and Internal 1,3-Dienes with Indoles

(2017) Justin S. Marcum et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

α-Dicationic Chelating Phosphines: Synthesis and Application to the Hydroarylation of Dienes

(2017) Lianghu Gu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium(ii)-catalyzed olefination via carbonyl reductive cross-coupling

(2017) Wei Wei et al.   Chemical Science

Umpolung Addition of Aldehydes to Aryl Imines

(2016) Ning Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Additive Effects on Asymmetric Catalysis

(2016) Liang Hong et al.   CHEMICAL REVIEWS

Transition metal-catalyzed couplings of alkynes to 1,3-enynes: modern methods and synthetic applications

(2016) Barry M. Trost et al.   CHEMICAL SOCIETY REVIEWS

Regiodivergent Catalysis: A Powerful Tool for Selective Catalysis

(2016) Nico Funken et al.   CHEMISTRY-A EUROPEAN JOURNAL

Aldehydes as alkyl carbanion equivalents for additions to carbonyl compounds

(2016) Haining Wang et al.   Nature Chemistry

Recent advances in transition-metal-catalyzed synthesis of conjugated enynes

(2016) Yujing Zhou et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Diastereoselective synthesis of vicinal tertiary and N-substituted quaternary stereogenic centers by catalytic hydroalkylation of dienes

(2016) Matthew J. Goldfogel et al.   Chemical Science

1,4-Functionalization of 1,3-Dienes With Low-Valent Iron Catalysts

(2015) Eric McNeill et al.   ACCOUNTS OF CHEMICAL RESEARCH

Synthesis of Highly Functionalized Tri- and Tetrasubstituted Alkenes via Pd-Catalyzed 1,2-Hydrovinylation of Terminal 1,3-Dienes

(2015) Vaneet Saini et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lewis Acid Activation of Carbodicarbene Catalysts for Rh-Catalyzed Hydroarylation of Dienes

(2015) Courtney C. Roberts et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

1,2-Selective Hydrosilylation of Conjugated Dienes

(2014) Sarah E. Parker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Directing Group-Controlled Regioselectivity in an Enzymatic C–H Bond Oxygenation

(2014) Solymar Negretti et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C–H/Het–H Bond Functionalizations

(2013) Lutz Ackermann   ACCOUNTS OF CHEMICAL RESEARCH

Temperature-Dependent Regioselectivity of Nucleophilic Aromatic Photosubstitution. Evidence That Activation Energy Controls Reactivity

(2013) Gene G. Wubbels et al.   JOURNAL OF ORGANIC CHEMISTRY

Controlling Site Selectivity in Palladium-Catalyzed C–H Bond Functionalization

(2012) Sharon R. Neufeldt et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Selective Synthesis

(2012) Jessada Mahatthananchai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Alkylation of 1,4-Dienes by CH Activation

(2012) Barry M. Trost et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

(2012) Percia Beatrice Arockiam et al.   CHEMICAL REVIEWS

Side-on Bound Complexes of Phenyl- and Methyl-diazene

(2012) Leslie D. Field et al.   INORGANIC CHEMISTRY

Asymmetric Hydrovinylation of 1-Vinylcycloalkenes. Reagent Control of Regio- and Stereoselectivity

(2012) Jordan P. Page et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective C-H Crotylation of Primary Alcohols via Hydrohydroxyalkylation of Butadiene

(2012) J. R. Zbieg et al.   SCIENCE

Innate and Guided C–H Functionalization Logic

(2011) Tobias Brückl et al.   ACCOUNTS OF CHEMICAL RESEARCH

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Regioselectivity of the borylation of alkanes and arenes

(2011) John F. Hartwig   CHEMICAL SOCIETY REVIEWS

Asymmetric additions to dienes catalysed by a dithiophosphoric acid

(2011) Nathan D. Shapiro et al.   NATURE

Palladium-Catalyzed Hydroarylation of 1,3-Dienes with Boronic Esters via Reductive Formation of π-Allyl Palladium Intermediates under Oxidative Conditions

(2010) Longyan Liao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Solvent effects on stereoselectivity: more than just an environment

(2009) Gianfranco Cainelli et al.   CHEMICAL SOCIETY REVIEWS

Catalytic Carbonyl Addition through Transfer Hydrogenation: A Departure from Preformed Organometallic Reagents

(2008) John F. Bower et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Diels−Alder Reactions

(2008) Sébastien Reymond et al.   CHEMICAL REVIEWS