Journal
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
Volume 228, Issue -, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.saa.2019.117819
Keywords
Saricicek howardite; Phase composition; X-ray diffraction; Magnetization measurements; Mossbauer spectroscopy
Categories
Funding
- Ministry of Science and Higher Education of the Russian Federation [3.1959.2017/4.6]
- Act 211 of the Government of the Russian Federation [02.A03.21.0006]
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The meteorite Saricicek, a 2015 howardite fall in Turkey, was analyzed using various physical techniques. Both the interior and the fusion crust were studied by optical and scanning electron microscopy with energy dispersive spectroscopy, X-ray diffraction, magnetization measurements and Mossbauer spectroscopy. The main and minor iron-bearing phases such as orthopyroxene, Ca-poor and Ca-rich clinopyroxene, chromite with hercynite, Fe2+ and Fe3+ ilmenite, troilite, alpha-Fe(Ni, Co), alpha(2)-Fe(Ni, Co) and gamma-Fe(Ni, Co) phases were identified. The ratios of Fe2+ occupancies in the M1 and M2 sites in the silicate phases as well as the equilibrium Fe2+ and Mg2+ cations distribution temperatures (T-eq) for orthopyroxene were estimated using X-ray diffraction and Mossbauer spectroscopy, which appeared to be in a good agreement: for example, T-eq were 886 and 878 K, respectively. The glass-like fusion crust of Saricicek consists of orthopyroxene with ferrous and ferric compounds that are likely products of combustion and melting. (C) 2019 Elsevier B.V. All rights reserved.
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