Journal
JOURNAL OF NANOMATERIALS
Volume 2019, Issue -, Pages -Publisher
HINDAWI LTD
DOI: 10.1155/2019/8175803
Keywords
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Funding
- National Natural Science Foundation of China [51268026]
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Ag-coated SiO2@TiO2 (Ag-SiO2@TiO2) core-shell nanocomposites were synthesized by a two-step method, which combined hydrothermal process and photodeposition. The morphology, structure, composition, and optical properties of the Ag-coated SiO2@TiO2 nanocomposites were extensively characterized by field-emission scanning microscopy (FE-SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and Fourier-transform infrared spectra (FT-IR spectra). The anatase TiO2 nanoparticles (5-10 nm) with high surface area were loaded on SiO2 spheres (200-300 nm) in the form of SiO2@TiO2 core-shell nanoparticle with a porous shell of controlled thickness (10-30 nm). Ag nanoparticles of different mass concentrations were photodeposited on SiO2@TiO2 core-shell structure with particle sizes of about 10-20 nm. The results showed that Ag nanoparticles increased the photocatalytic activity of SiO2@TiO2 core-shell nanoparticle improved the degradation of phenol and methylene blue under UV irradiation. The experimental results showed that Ag nanoparticles with mass concentrations of 6% had the highest photocatalytic activity on SiO2@TiO2 core-shell nanoparticles.
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