Sono-sorption efficiencies and equilibrium removal of triphenylmethane (crystal violet) dye from aqueous solution by activated charcoal

In this present work, the sorption of crystal violet (CV) pigment from laden aqueous solution carried out via ultrasound-assisted. The sorption of CV on activated charcoal was performed in the existence and absence of ultrasound. Using of combined ultrasound/activated charcoal process gave high CV decolorization than using sorption or sonolysis alone because of the synergistic process achieved in this combined system. Experiments were performed at different initial pigment concentration and temperature. The sorption isotherms were achieved by the Freundlich, Langmuir, D-R and Temkin isotherm model. The sorption of CV onto activated charcoal demonstrated more suitable for Langmuir than the Freundlich isotherm model. The maximum monolayer sorption capacity was 50.1 mg/g. The thermodynamic parameters, namely the entropy, Gibbs free energy and enthalpy of the CV sorption process were determined. The enthalpy and free energy indicate an exothermic, feasible and spontaneous process. It has been shown that the proposed combined ultrasound/activated charcoal process may be useable in the treatment of pigment solution from textile wastewater. (C) 2019 Elsevier Ltd. All rights reserved.