Organocatalytic Enantioselective Synthesis of Tetrasubstituted α-Amino Allenoates by Dearomative γ-Addition of 2,3-Disubstituted Indoles to β,γ-Alkynyl-α-imino Esters

Remote Stereocontrolled Construction of Vicinal Axially Chiral Tetrasubstituted Allenes and Heteroatom-Functionalized Quaternary Carbon Stereocenters

(2019) Pei Zhang et al.   ORGANIC LETTERS

Catalytic Regio- and Enantioselective Proton Migration from Skipped Enynes to Allenes

(2019) Xiao-Feng Wei et al.   Chem

Catalytic enantioselective construction of axial chirality in 1,3-disubstituted allenes

(2019) Shihua Song et al.   Nature Communications

Phosphoric Acid Catalyzed Asymmetric [2+2] Cyclization/Penicillin-Penillonic Acid Rearrangement

(2018) Ming Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral phosphoric acid catalysis: from numbers to insights

(2018) Rajat Maji et al.   CHEMICAL SOCIETY REVIEWS

Regio- and stereospecific Friedel–Crafts alkylation of indoles with spiro-epoxyoxindoles

(2018) Guofeng Li et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective aza-Friedel–Crafts reaction of furan with α-ketimino esters induced by a conjugated double hydrogen bond network of chiral bis(phosphoric acid) catalysts

(2018) Manabu Hatano et al.   Chemical Science

Catalytic Kinetic Resolution of Spiro-Epoxyoxindoles with 1-Naphthols: Switchable Asymmetric Tandem Dearomatization/Oxa-Michael Reaction and Friedel–Crafts Alkylation of 1-Naphthols at the C4 Position

(2018) Gongming Zhu et al.   ACS Catalysis

Access to α,γ-Diamino Diacid Derivatives via Organocatalytic Asymmetric 1,4-Addition of Azlactones and Dehydroalanines

(2018) Junxian Yang et al.   ORGANIC LETTERS

Chiral Phosphoric Acid Catalyzed Intramolecular Dearomative Michael Addition of Indoles to Enones

(2017) Yong Zhou et al.   ORGANIC LETTERS

Organocatalytic synthesis of chiral tetrasubstituted allenes from racemic propargylic alcohols

(2017) Deyun Qian et al.   Nature Communications

Chiral Allenes via Alkynylogous Mukaiyama Aldol Reaction

(2016) Aurélien Tap et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalyst-controlled switch of regioselectivity in the asymmetric allylic alkylation of oxazolones with MBHCs

(2016) Gongming Zhu et al.   CHEMICAL COMMUNICATIONS

Chiral phosphoric acid catalyzed enantioselective 1,3-dipolar cycloaddition reaction of azlactones

(2016) Zhenhua Zhang et al.   CHEMICAL COMMUNICATIONS

Additive Effects on Asymmetric Catalysis

(2016) Liang Hong et al.   CHEMICAL REVIEWS

Chiral Phosphoric Acid Catalyzed Asymmetric Oxidative Dearomatization of Naphthols with Quinones

(2016) Gongming Zhu et al.   ORGANIC LETTERS

Enantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut–Currier reaction of allenoates

(2016) Weijun Yao et al.   Nature Communications

Enantioselective Dearomative Arylation of Isoquinolines

(2016) Ming Zhang et al.   ACS Catalysis

Enantioselective Construction of Spiroindolines with Three Contiguous Stereogenic Centers and Chiral Tryptamine Derivatives via Reactive Spiroindolenine Intermediates

(2015) Chun-Xiang Zhuo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C-Selective and Diastereoselective Alkyl Addition to β,γ-Alkynyl-α-imino Esters with Zinc(II)ate Complexes

(2015) Manabu Hatano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Highly Substituted Racemic and Enantioenriched Allenylsilanes via Copper-Catalyzed Hydrosilylation of (Z)-2-Alken-4-ynoates with Silylboronate

(2015) Min Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Cyclization Reactions of Allenes in the Presence of Unsaturated Carbon–Carbon Bonds

(2014) Juntao Ye et al.   ACCOUNTS OF CHEMICAL RESEARCH

Organocatalytic Asymmetric Arylative Dearomatization of 2,3-Disubstituted Indoles Enabled by Tandem Reactions

(2014) Yu-Chen Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Enantioselective Electrophilic Activation of Allenamides: Stereoselective Dearomatization of Indoles

(2014) Ciro Romano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates

(2014) Dixit Parmar et al.   CHEMICAL REVIEWS

Diastereo- and Enantioselective Addition of Anilide-Functionalized Allenoates to N-Acylimines Catalyzed by a Pyridylalanine-Based Peptide

(2014) Curren T. Mbofana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conquering three-carbon axial chirality of allenes

(2014) Juntao Ye et al.   Organic Chemistry Frontiers

Allenamides: A Powerful and Versatile Building Block in Organic Synthesis

(2013) Ting Lu et al.   CHEMICAL REVIEWS

A Room-Temperature Catalytic Asymmetric Synthesis of Allenes with ECNU-Phos

(2013) Yuli Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Asymmetric β-Hydride Elimination en Route to Chiral Allenes

(2013) Ian T. Crouch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Enantioselective Synthesis of 2,3-Allenoates by Intermolecular Addition of Nitroalkanes to Activated Enynes

(2013) Hui Qian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phase-transfer-catalysed asymmetric synthesis of tetrasubstituted allenes

(2013) Takuya Hashimoto et al.   Nature Chemistry

Regioselective Tandem N-Alkylation/C-Acylation of β,γ-Alkynyl α-Imino Esters

(2013) Isao Mizota et al.   ORGANIC LETTERS

Recent Advances in the Catalytic Syntheses of Allenes: A Critical Assessment

(2013) Robynne K. Neff et al.   ACS Catalysis

Allenes in Molecular Materials

(2012) Pablo Rivera-Fuentes et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Decarboxylative Amination: Synthesis of Axially Chiral Allenyl Amines

(2012) Baoqiang Wan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Allenes in Catalytic Asymmetric Synthesis and Natural Product Syntheses

(2012) Shichao Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalyzed Isomerization of α-Substituted Alkynoates into Trisubstituted Allenoates by Dynamic Kinetic Resolution

(2012) Tsubasa Inokuma et al.   ChemCatChem

Synthesis of Conjugated Allenes through Copper-Catalyzed γ-Selective and Stereospecific Coupling between Propargylic Phosphates and Aryl- or Alkenylboronates

(2012) Mingyu Yang et al.   ORGANIC LETTERS

Catalytic Asymmetric Synthesis of Optically Active Allenes from Terminal Alkynes

(2012) Juntao Ye et al.   ORGANIC LETTERS

Copper-Catalyzed Enantioselective Synthesis of Axially Chiral Allenes

(2012) Hailing Li et al.   ORGANIC LETTERS

Chiral Brønsted acids in enantioselective carbonyl activations – activation modes and applications

(2011) Magnus Rueping et al.   CHEMICAL SOCIETY REVIEWS

General Approach to Allenes through Copper-Catalyzed γ-Selective and Stereospecific Coupling between Propargylic Phosphates and Alkylboranes

(2011) Hirohisa Ohmiya et al.   ORGANIC LETTERS

Asymmetric Synthesis of Trisubstituted Allenes: Copper-Catalyzed Alkylation and Arylation of Propargylic Phosphates

(2011) Mycah R. Uehling et al.   ORGANIC LETTERS

Chemoenzymatic Dynamic Kinetic Resolution of Axially Chiral Allenes

(2010) Jan Deska et al.   CHEMISTRY-A EUROPEAN JOURNAL

Kinetic Resolution of Racemic 2,3-Allenoates by Organocatalytic Asymmetric 1,3-Dipolar Cycloaddition

(2010) Jie Yu et al.   ORGANIC LETTERS

Electrophilic Addition and Cyclization Reactions of Allenes

(2009) Shengming Ma   ACCOUNTS OF CHEMICAL RESEARCH

Discovery of tetrahydro-cyclopenta[b]indole as selective LXRs modulator

(2009) Hassen Ratni et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Silver(i)-mediated highly enantioselective synthesis of axially chiral allenes under thermal and microwave-assisted conditions

(2009) Vanessa Kar-Yan Lo et al.   CHEMICAL COMMUNICATIONS

Benchmark Energetic Data in a Model System for Grubbs II Metathesis Catalysis and Their Use for the Development, Assessment, and Validation of Electronic Structure Methods

(2009) Yan Zhao et al.   Journal of Chemical Theory and Computation

Density Functionals with Broad Applicability in Chemistry

(2008) Yan Zhao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Binaphthol-derived phosphoric acid as a versatile catalyst for enantioselective carbon–carbon bond forming reactions

(2008) Masahiro Terada   CHEMICAL COMMUNICATIONS

Molecular Modeling of Complex Chemical Systems

(2008) Donald G. Truhlar   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct and Stereospecific Synthesis of Allenes via Reduction of Propargylic Alcohols with Cp2Zr(H)Cl

(2008) Xiaotao Pu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-Catalyzed Highly Enantioselective Synthesis of Axially Chiral Allenes

(2008) Vanessa Kar-Yan Lo et al.   ORGANIC LETTERS

Asymmetric Transfer Hydrogenation of β,γ-Alkynyl α-Imino Esters by a Brønsted Acid

(2008) Qiang Kang et al.   ORGANIC LETTERS