Enantioselective Synthesis of Multisubstituted Allenes by Cooperative Cu/Pd-Catalyzed 1,4-Arylboration of 1,3-Enynes

Asymmetric Borylative Propargylation of Ketones Catalyzed by a Copper(I) Complex

(2019) Xu-Cheng Gan et al.   ORGANIC LETTERS

Chiral Bifunctional Phosphine Ligand Enabling Gold-Catalyzed Asymmetric Isomerization of Alkyne to Allene and Asymmetric Synthesis of 2,5-Dihydrofuran

(2019) Xinpeng Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Carbofluoroalkylation of 1,3-Enynes to Access Structurally Diverse Fluoroalkylated Allenes

(2019) Kai-Fan Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Preparation of Chiral Allenes through Pd-Catalyzed Intermolecular Hydroamination of Conjugated Enynes: Enantioselective Synthesis Enabled by Catalyst Design

(2019) Nathan J. Adamson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Enantioselective Thiocarbonylation of Styrenes

(2019) Xihong Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper Hydride Catalyzed Enantioselective Synthesis of Axially Chiral 1,3-Disubstituted Allenes

(2019) Liela Bayeh-Romero et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tetrasubstituted allenes via the palladium-catalysed kinetic resolution of propargylic alcohols using a supporting ligand

(2019) Wei-Feng Zheng et al.   Nature Catalysis

Divergent Synthesis of CF3 -Substituted Allenyl Nitriles by Ligand-Controlled Radical 1,2- and 1,4-Addition to 1,3-Enynes

(2018) Fei Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Trisubstituted Allenyl–B(pin) Compounds by Phosphine–Cu-Catalyzed 1,3-Enyne Hydroboration. Insights Regarding Stereochemical Integrity of Cu–Allenyl Intermediates

(2018) Youming Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Construction of Fluoroalkyl Tertiary Alcohols through a Three-Component Reaction of (Bpin)2, 1,3-Enynes, and Fluoroalkyl Ketones Catalyzed by a Copper(I) Complex

(2018) Xu-Cheng Gan et al.   ORGANIC LETTERS

Enantioselective Copper-Catalyzed Methylboration of Alkenes

(2018) Bin Chen et al.   ORGANIC LETTERS

Catalytic, Enantioselective Synthesis of Allenyl Boronates

(2018) De-Wei Gao et al.   ACS Catalysis

Copper-catalyzed asymmetric hydroboration of 1,3-enynes with pinacolborane to access chiral allenylboronates

(2018) Hui Leng Sang et al.   Organic Chemistry Frontiers

Copper-Catalyzed Radical 1,4-Difunctionalization of 1,3-Enynes with Alkyl Diacyl Peroxides and N-Fluorobenzenesulfonimide

(2018) Xiaotao Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective Arylboration of Isoprene and Its Derivatives by Pd/Cu Cooperative Catalysis

(2017) Kevin B. Smith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic synthesis of chiral tetrasubstituted allenes from racemic propargylic alcohols

(2017) Deyun Qian et al.   Nature Communications

Modular Synthesis of Enantioenriched 1,1,2-Triarylethanes by an Enantioselective Arylboration and Cross-Coupling Sequence

(2017) Bin Chen et al.   ACS Catalysis

Recent advances in catalytic asymmetric synthesis of allenes

(2017) Wen-Dao Chu et al.   Catalysis Science & Technology

Catalytic Enantioselective Arylboration of Alkenylarenes

(2016) Kaitlyn M. Logan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Hydroarylation of Vinylarenes Using a Synergistic Combination of CuH and Pd Catalysis

(2016) Stig D. Friis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-Catalyzed Stereospecific Synthesis of Allenes from Propargylic Benzoates and Arylboronic Acids

(2016) Jonathan Ruchti et al.   ORGANIC LETTERS

Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones

(2016) Y. Yang et al.   SCIENCE

Copper-Catalyzed Enantioselective 1,6-Boration ofpara-Quinone Methides and Efficient Transformation ofgem-Diarylmethine Boronates to Triarylmethanes

(2015) Yazhou Lou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

General CuBr2-catalyzed highly enantioselective approach for optically active allenols from terminal alkynols

(2015) Xin Huang et al.   CHEMICAL COMMUNICATIONS

Copper-Catalyzed Asymmetric Three-Component Borylstannation: Enantioselective Formation of CSn Bond

(2015) Tao Jia et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Cu/Pd Cooperative Catalysis for Enantioselective Allylboration of Alkenes

(2015) Tao Jia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Highly Substituted Racemic and Enantioenriched Allenylsilanes via Copper-Catalyzed Hydrosilylation of (Z)-2-Alken-4-ynoates with Silylboronate

(2015) Min Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Asymmetric Pinacolboryl Addition of N-Boc-imines Using a Chiral Sulfoxide–Phosphine Ligand

(2015) Ding Wang et al.   ORGANIC LETTERS

A C–H bond activation-based catalytic approach to tetrasubstituted chiral allenes

(2015) Shangze Wu et al.   Nature Communications

Palladium-Catalyzed Cyclization Reactions of Allenes in the Presence of Unsaturated Carbon–Carbon Bonds

(2014) Juntao Ye et al.   ACCOUNTS OF CHEMICAL RESEARCH

An asymmetric [3+2] cycloaddition of alkynes with oxiranes by selective C–C bond cleavage of epoxides: highly efficient synthesis of chiral furan derivatives

(2014) Weiliang Chen et al.   CHEMICAL COMMUNICATIONS

Diastereo- and Enantioselective Reactions of Bis(pinacolato)diboron, 1,3-Enynes, and Aldehydes Catalyzed by an Easily Accessible Bisphosphine–Cu Complex

(2014) Fanke Meng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Arylboration of Alkenes by Cooperative Palladium/Copper Catalysis

(2014) Kazuhiko Semba et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conquering three-carbon axial chirality of allenes

(2014) Juntao Ye et al.   Organic Chemistry Frontiers

Organocatalytic Enantioselective Synthesis of 2,3-Allenoates by Intermolecular Addition of Nitroalkanes to Activated Enynes

(2013) Hui Qian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phase-transfer-catalysed asymmetric synthesis of tetrasubstituted allenes

(2013) Takuya Hashimoto et al.   Nature Chemistry

Allenes in Catalytic Asymmetric Synthesis and Natural Product Syntheses

(2012) Shichao Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalyzed Isomerization of α-Substituted Alkynoates into Trisubstituted Allenoates by Dynamic Kinetic Resolution

(2012) Tsubasa Inokuma et al.   ChemCatChem

Synthesis of Conjugated Allenes through Copper-Catalyzed γ-Selective and Stereospecific Coupling between Propargylic Phosphates and Aryl- or Alkenylboronates

(2012) Mingyu Yang et al.   ORGANIC LETTERS

Enantioselective Enzymatic Desymmetrization of Prochiral Allenic Diols

(2011) Chicco Manzuna Sapu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

How easy are the syntheses of allenes?

(2011) Shichao Yu et al.   CHEMICAL COMMUNICATIONS

Transition Metal Catalyzed Cycloisomerizations of 1,n-Allenynes and -Allenenes

(2011) Corinne Aubert et al.   CHEMICAL REVIEWS

General Approach to Allenes through Copper-Catalyzed γ-Selective and Stereospecific Coupling between Propargylic Phosphates and Alkylboranes

(2011) Hirohisa Ohmiya et al.   ORGANIC LETTERS

Asymmetric Synthesis of Trisubstituted Allenes: Copper-Catalyzed Alkylation and Arylation of Propargylic Phosphates

(2011) Mycah R. Uehling et al.   ORGANIC LETTERS

Rhodium-Catalyzed Enantioselective 1,6-Addition of Arylboronic Acids to Enynamides: Asymmetric Synthesis of Axially Chiral Allenylsilanes

(2010) Takahiro Nishimura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Kinetic Resolution of Racemic 2,3-Allenoates by Organocatalytic Asymmetric 1,3-Dipolar Cycloaddition

(2010) Jie Yu et al.   ORGANIC LETTERS

Homologation and alkylation of boronic esters and boranes by 1,2-metallate rearrangement of boron ate complexes

(2009) Stephen P. Thomas et al.   CHEMICAL RECORD

Enzymatic kinetic resolution of primary allenic alcohols. Application to the total synthesis and stereochemical assignment of striatisporolide A

(2009) Jan Deska et al.   ORGANIC & BIOMOLECULAR CHEMISTRY