Carboamination of Unactivated Alkenes through Three-Component Radical Conjugate Addition

Copper-catalyzed remote C(sp3)–H azidation and oxidative trifluoromethylation of benzohydrazides

(2019) Xu Bao et al.   Nature Communications

A Redox-Active Nickel Complex that Acts as an Electron Mediator in Photochemical Giese Reactions

(2019) Thomas van Leeuwen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoredox-Catalyzed Site-Selective α-C(sp3 )−H Alkylation of Primary Amine Derivatives

(2019) Melissa A. Ashley et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalyst-Free Deaminative Functionalizations of Primary Amines by Photoinduced Single-Electron Transfer

(2019) Jingjing Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–H Alkylation via Multisite-Proton-Coupled Electron Transfer of an Aliphatic C–H Bond

(2019) Carla M. Morton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Radical Aminotrifluoromethylation of Alkenes

(2019) Haiwen Xiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light-Mediated Decarboxylative Radical Additions to Vinyl Boronic Esters: Rapid Access to γ-Amino Boronic Esters

(2018) Adam Noble et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Amidyl Radicals by Oxidation of α-Amido-oxy Acids: Transition-Metal-Free Amidofluorination of Unactivated Alkenes

(2018) Heng Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A General Strategy for Aliphatic C–H Functionalization Enabled by Organic Photoredox Catalysis

(2018) Kaila A. Margrey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Generation and Alkylation of α-Carbamyl Radicals via Organic Photoredox Catalysis

(2018) Joshua B. McManus et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conjugate Addition of Perfluoroarenes to α,β-Unsaturated Carbonyls Enabled by an Alkoxide-Hydrosilane System: Implication of a Radical Pathway

(2018) Weilong Xie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoredox-Induced Radical Relay toward Functionalized β-Amino Alcohol Derivatives

(2018) Xiao-De An et al.   ORGANIC LETTERS

Photoredox-catalyzed C(sp 2 )–N coupling reactions

(2018) Xiao-De An et al.   TETRAHEDRON LETTERS

Photoinduced Remote Functionalization of Amides and Amines Using Electrophilic Nitrogen Radicals

(2018) Sara P. Morcillo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular Carboamination of Unactivated Alkenes

(2018) Yu Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Alkene Difunctionalization via Imidate Radicals

(2018) Kohki M. Nakafuku et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multicomponent synthesis of tertiary alkylamines by photocatalytic olefin-hydroaminoalkylation

(2018) Aaron Trowbridge et al.   NATURE

Copper-catalyzed methylative difunctionalization of alkenes

(2018) Xu Bao et al.   Nature Communications

A general deoxygenation approach for synthesis of ketones from aromatic carboxylic acids and alkenes

(2018) Muliang Zhang et al.   Nature Communications

Ti-Catalyzed Radical Alkylation of Secondary and Tertiary Alkyl Chlorides Using Michael Acceptors

(2018) Xiangyu Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Forging C(sp3)–C(sp3) Bonds with Carbon-Centered Radicals in the Synthesis of Complex Molecules

(2018) Spencer P. Pitre et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Intermolecular Carboamination of Unactivated Alkenes via Directed Aminopalladation

(2017) Zhen Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu-Catalyzed Three-Component Carboamination of Alkenes

(2017) Samuel N. Gockel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Carboamination of Olefins: Synthesis of Amines and Disubstituted β-Amino Acids

(2017) Bo Qian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Copper-Catalyzed Intermolecular Aminoarylation of Styrenes: Efficient Access to Optical 2,2-Diarylethylamines

(2017) Dinghai Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fe-Catalyzed C–C Bond Construction from Olefins via Radicals

(2017) Julian C. Lo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A mild catalytic system for radical conjugate addition of nitrogen heterocycles

(2017) R. A. Aycock et al.   Chemical Science

Oxidative 1,2-carboamination of alkenes with alkyl nitriles and amines toward γ-amino alkyl nitriles

(2017) Yan-Yun Liu et al.   Nature Communications

Photochemical Generation of Nitrogen-Centered Amidyl, Hydrazonyl, and Imidyl Radicals: Methodology Developments and Catalytic Applications

(2017) Markus D. Kärkäs   ACS Catalysis

Fragment Coupling with Tertiary Radicals Generated by Visible-Light Photocatalysis

(2016) Christopher R. Jamison et al.   ACCOUNTS OF CHEMICAL RESEARCH

Unnatural Amino Acid Synthesis Enabled by the Regioselective Cobalt(III)-Catalyzed Intermolecular Carboamination of Alkenes

(2016) Andreas Lerchen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Barton Decarboxylation and Giese Reactions: A Practical Take on Classic Transforms

(2016) Tian Qin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Markovnikov free radical addition reactions, a sleeping beauty kissed to life

(2016) Reinhard W. Hoffmann   CHEMICAL SOCIETY REVIEWS

New amination strategies based on nitrogen-centered radical chemistry

(2016) Tao Xiong et al.   CHEMICAL SOCIETY REVIEWS

Visible light photoredox-controlled reactions of N-radicals and radical ions

(2016) Jia-Rong Chen et al.   CHEMICAL SOCIETY REVIEWS

Photoredox Catalysis in Organic Chemistry

(2016) Megan H. Shaw et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic, Enantioselective Addition of Alkyl Radicals to Alkenes via Visible-Light-Activated Photoredox Catalysis with a Chiral Rhodium Complex

(2016) Haohua Huo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Amide-directed photoredox-catalysed C–C bond formation at unactivated sp3 C–H bonds

(2016) John C. K. Chu et al.   NATURE

Catalytic alkylation of remote C–H bonds enabled by proton-coupled electron transfer

(2016) Gilbert J. Choi et al.   NATURE

Rhodium(III) Catalyzed Carboamination of Alkenes Triggered by C–H Activation of N-Phenoxyacetamides under Redox-Neutral Conditions

(2016) Zhiyong Hu et al.   ORGANIC LETTERS

Metal-Catalyzed β-Functionalization of Michael Acceptors through Reductive Radical Addition Reactions

(2015) Jan Streuff et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silicates as Latent Alkyl Radical Precursors: Visible-Light Photocatalytic Oxidation of Hypervalent Bis-Catecholato Silicon Compounds

(2015) Vincent Corcé et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Intermolecular Aminocarbonylation of Alkenes: Efficient Access of β-Amino Acid Derivatives

(2015) Jiashun Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Conjugate Additions of α-Amino Radicals via Cooperative Photoredox and Lewis Acid Catalysis

(2015) Laura Ruiz Espelt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling

(2015) Christopher C. Nawrat et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Alkene Carboaminations Enabled by Oxidative Proton-Coupled Electron Transfer

(2015) Gilbert J. Choi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-catalysed syn-carboamination of alkenes via a transient directing group

(2015) Tiffany Piou et al.   NATURE

Iron-Catalyzed Convergent Radical Cyclization of Aldehydes with Two Alkenes to 3,4-Dihydropyrans

(2015) Leiyang Lv et al.   ORGANIC LETTERS

Direct β-Alkylation of Aldehydes via Photoredox Organocatalysis

(2014) Jack A. Terrett et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Practical and Catalytic Reductive Olefin Coupling

(2014) Julian C. Lo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carboxylic Acids as A Traceless Activation Group for Conjugate Additions: A Three-Step Synthesis of (±)-Pregabalin

(2014) Lingling Chu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Functionalized olefin cross-coupling to construct carbon–carbon bonds

(2014) Julian C. Lo et al.   NATURE

N-Aminopyridinium Salts as Precursors for N-Centered Radicals – Direct Amidation of Arenes and Heteroarenes

(2014) Tobias W. Greulich et al.   ORGANIC LETTERS

Photoredox-Induced Three-Component Azido- and Aminotrifluoromethylation of Alkenes

(2014) Guillaume Dagousset et al.   ORGANIC LETTERS

Copper-Catalyzed Intermolecular Aminocyanation and Diamination of Alkenes

(2013) Hongwei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Photoredox-Catalyzed Meerwein Addition Reaction: Intermolecular Amino-Arylation of Alkenes

(2013) Durga Prasad Hari et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

Visible-Light Photoredox Catalysis

(2012) Jun Xuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Mediated Utilization of α-Aminoalkyl Radicals: Addition to Electron-Deficient Alkenes Using Photoredox Catalysts

(2012) Yoshihiro Miyake et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Functionalized Tetrahydrofurans from Alkenols and Olefins/Alkynes via Aerobic Oxidation−Radical Addition Cascades

(2011) Patrick Fries et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible light photoredox catalysis: applications in organic synthesis

(2010) Jagan M. R. Narayanam et al.   CHEMICAL SOCIETY REVIEWS

Visible light photocatalysis as a greener approach to photochemical synthesis

(2010) Tehshik P. Yoon et al.   Nature Chemistry

Radical and Radical-Ionic Multicomponent Processes

(2009) Edouard Godineau et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent progress in the generation and use of nitrogen-centred radicals

(2008) Samir Z. Zard   CHEMICAL SOCIETY REVIEWS