Arene-Free Ruthenium(II/IV)-Catalyzed Bifurcated Arylation for Oxidative C−H/C−H Functionalizations

para-Selective C-H Olefination of Aniline Derivatives via Pd/S,O-Ligand Catalysis

(2019) Kananat Naksomboon et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidatively Induced Reductive Elimination: Exploring the Scope and Catalyst Systems with Ir, Rh, and Ru Complexes

(2019) Jinwoo Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Micellar Catalysis for Ruthenium(II)-Catalyzed C−H Arylation: Weak-Coordination-Enabled C−H Activation in H2O

(2019) Santhivardhana Reddy Yetra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoredox Catalysis for Building C–C Bonds from C(sp2)–H Bonds

(2018) Chang-Sheng Wang et al.   CHEMICAL REVIEWS

Cyclometallated ruthenium catalyst enables late-stage directed arylation of pharmaceuticals

(2018) Marco Simonetti et al.   Nature Chemistry

Selective formation of γ-lactams via C–H amidation enabled by tailored iridium catalysts

(2018) Seung Youn Hong et al.   SCIENCE

Insights into mechanism and selectivity in ruthenium(ii)-catalysed ortho-arylation reactions directed by Lewis basic groups

(2018) Jamie McIntyre et al.   Catalysis Science & Technology

Transient Directing Groups for Transformative C–H Activation by Synergistic Metal Catalysis

(2018) Parthasarathy Gandeepan et al.   Chem

3d Transition Metals for C–H Activation

(2018) Parthasarathy Gandeepan et al.   CHEMICAL REVIEWS

Ruthenium(II) Catalysis/Noncovalent Interaction Synergy for Cross-Dehydrogenative Coupling of Arene Carboxylic Acids

(2018) Suman Dana et al.   ACS Catalysis

Iridium-catalysed arylation of C–H bonds enabled by oxidatively induced reductive elimination

(2017) Kwangmin Shin et al.   Nature Chemistry

Recent Developments in Ruthenium-Catalyzed C–H Arylation: Array of Mechanistic Manifolds

(2017) Pradeep Nareddy et al.   ACS Catalysis

ortho -C−H Arylation of Benzoic Acids with Aryl Bromides and Chlorides Catalyzed by Ruthenium

(2016) Agostino Biafora et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium(ii)-catalyzed C–H functionalizations on benzoic acids with aryl, alkenyl and alkynyl halides by weak-O-coordination

(2016) Ruhuai Mei et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Transformations of Alkyl C–H Bonds

(2016) Jian He et al.   CHEMICAL REVIEWS

The medicinal chemist's toolbox for late stage functionalization of drug-like molecules

(2016) Tim Cernak et al.   CHEMICAL SOCIETY REVIEWS

Ruthenium-Catalyzed Ortho C–H Arylation of Aromatic Nitriles with Arylboronates and Observation of Partial Para Arylation

(2016) Yuta Koseki et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct (Hetero)arylation Polymerization: Trends and Perspectives

(2016) Thomas Bura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ru-Catalyzed C–H Arylation of Fluoroarenes with Aryl Halides

(2016) Marco Simonetti et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed C–H Arylation of Diverse Aryl Carboxylic Acids with Aryl and Heteroaryl Halides

(2016) Liangbin Huang et al.   ORGANIC LETTERS

A New Catalytic System for Ru-Catalyzed C–H Arylation Reactions and Its Application in the Practical Syntheses of Pharmaceutical Agents

(2016) Masahiko Seki   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Mechanistic insight into ruthenium catalysed meta-sulfonation of 2-phenylpyridine

(2016) Patricia Marcé et al.   Catalysis Science & Technology

Undirected, Homogeneous C–H Bond Functionalization: Challenges and Opportunities

(2016) John F. Hartwig et al.   ACS Central Science

Robust Ruthenium(II)-Catalyzed C–H Arylations: Carboxylate Assistance for the Efficient Synthesis of Angiotensin-II-Receptor Blockers

(2015) Lutz Ackermann   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Ruthenium(II)-Catalyzed C–H Arylation of Azoarenes by Carboxylate Assistance

(2015) Jonathan Hubrich et al.   ACS Catalysis

Ruthenium-catalyzed ortho-arylation of acetanilides with aromatic boronic acids: an easy route to prepare phenanthridines and carbazoles

(2014) Ravi Kiran Chinnagolla et al.   CHEMICAL COMMUNICATIONS

Ruthenium(II)-Catalyzed Oxidative CH Alkenylations of Sulfonic Acids, Sulfonyl Chlorides and Sulfonamides

(2014) Wenbo Ma et al.   CHEMISTRY-A EUROPEAN JOURNAL

Triazole-Assisted Ruthenium-Catalyzed CH Arylation of Aromatic Amides

(2014) Hamad H. Al Mamari et al.   CHEMISTRY-A EUROPEAN JOURNAL

Sequential Ruthenium(II)-Acetate Catalyzed C–H Bond Diarylation in NMP or Water and Hydrosilylation of Imines

(2014) Bin Li et al.   TOPICS IN CATALYSIS

Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C–H/Het–H Bond Functionalizations

(2013) Lutz Ackermann   ACCOUNTS OF CHEMICAL RESEARCH

Direct Synthesis of Pyrroles by Dehydrogenative Coupling of β-Aminoalcohols with Secondary Alcohols Catalyzed by Ruthenium Pincer Complexes

(2013) Dipankar Srimani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium(II)-catalysed Functionalisation of CH Bonds via a Six-membered Cyclometallate: Monoarylation of Aryl 2-pyridyl Ketones

(2013) Bin Li et al.   ChemCatChem

Direct CH bond Arylation in Water Promoted by (O,O)- and (O,N)-Chelate Ruthenium(II) Catalysts

(2013) Keisham S. Singh et al.   ChemCatChem

sp2 C–H bond activation in water and catalytic cross-coupling reactions

(2013) Bin Li et al.   CHEMICAL SOCIETY REVIEWS

Rhodium or Ruthenium-Catalyzed Oxidative CH/CH Cross-Coupling: Direct Access to Extended π-Conjugated Systems

(2012) Jiaxing Dong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

(2012) Percia Beatrice Arockiam et al.   CHEMICAL REVIEWS

Ruthenium(0)-Catalyzed sp3 C–H Bond Arylation of Benzylic Amines Using Arylboronates

(2012) Navid Dastbaravardeh et al.   ORGANIC LETTERS

Ruthenium-catalyzed direct arylation of C–H bonds in aromatic amides containing a bidentate directing group: significant electronic effects on arylation

(2012) Yoshinori Aihara et al.   Chemical Science

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Recent developments in natural product synthesis using metal-catalysed C–H bond functionalisation

(2011) Lindsay McMurray et al.   CHEMICAL SOCIETY REVIEWS

Direct Arylation as a Synthetic Tool for the Synthesis of Thiophene-Based Organic Electronic Materials

(2011) Derek J. Schipper et al.   CHEMISTRY OF MATERIALS

Autocatalysis for C–H Bond Activation by Ruthenium(II) Complexes in Catalytic Arylation of Functional Arenes

(2011) Emmanuel Ferrer Flegeau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Direct C–H Bond Arylations of Heteroarenes

(2011) Lutz Ackermann et al.   ORGANIC LETTERS

Sequential Catalysis for the Production of Sterically Hindered Amines: Ru(II)-Catalyzed C–H Bond Activation and Hydrosilylation of Imines

(2011) Bin Li et al.   ACS Catalysis

CH Bond Functionalization in Water Catalyzed by Carboxylato Ruthenium(II) Systems

(2010) Percia B. Arockiam et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C—H Bond Activation in Transition Metal Species from a Computational Perspective

(2010) David Balcells et al.   CHEMICAL REVIEWS

Mechanistic Insight into Direct Arylations with Ruthenium(II) Carboxylate Catalysts

(2010) Lutz Ackermann et al.   ORGANIC LETTERS

Chelation-assisted carbonylation reactions catalyzed by Rh and Ru complexes

(2010) Naoto Chatani et al.   PURE AND APPLIED CHEMISTRY

Ruthenium-Catalyzed C-H Bond Functionalizations of 1,2,3-Triazol-4-yl-Substituted Arenes: Dehydrogenative Couplings Versus Direct Arylations

(2010) Lutz Ackermann et al.   SYNTHESIS-STUTTGART

Ruthenium-Catalyzed Oxidative Homo-Coupling of 2-Arylpyridines

(2009) Xiangyu Guo et al.   ADVANCED SYNTHESIS & CATALYSIS

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cross-Dehydrogenative Coupling (CDC): Exploring C−C Bond Formations beyond Functional Group Transformations

(2008) Chao-Jun Li   ACCOUNTS OF CHEMICAL RESEARCH

Ruthenium-Catalyzed Oxidative Cross-Coupling of Chelating Arenes and Cycloalkanes

(2008) Guojun Deng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Arylation of Arene C−H Bonds by Cooperative Action of NHCarbene−Ruthenium(II) Catalyst and Carbonate via Proton Abstraction Mechanism

(2008) Ismail Özdemir et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Analysis of the Concerted Metalation-Deprotonation Mechanism in Palladium-Catalyzed Direct Arylation Across a Broad Range of Aromatic Substrates

(2008) Serge I. Gorelsky et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nitrogen-Directed Ortho-Selective Homocoupling of Aromatic Compounds Catalyzed by Ruthenium Complexes

(2008) Shuichi Oi et al.   ORGANIC LETTERS

[RuCl3(H2O)n]-catalyzed direct arylations

(2008) Lutz Ackermann et al.   TETRAHEDRON