Journal
ACS OMEGA
Volume 4, Issue 4, Pages 7884-7890Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsomega.9b00777
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Funding
- Ministry of Science and Technology of Taiwan (MOST-Taiwan) [MOST 106-221-E-007-098-MY3]
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Meldrum's acid (MA) is utilized as a monomer to polymerize with diisocyanates to result in polyamides, containing MA moieties at polymer chains. This reaction is also employed to prepare isocyanate-terminated polyamide segments which are utilized as a precursor for preparation of MA-containing polyurethanes. Based on the thermolysis reaction of MA groups, followed by ketene dimerization reaction, the reactive polyamides and polyurethanes show self-cross-linkable features. The cross-linked polyurethanes exhibit good film formability, thermal stability, and mechanical properties. A new MA-based polymerization method and a novel synthesis route for preparation of reactive polyamides and polyurethanes are demonstrated.
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