Article
Chemistry, Applied
Xuefeng Liu, Yuantao Pei, Liang Huang, Wen Lei, Faliang Li, Yage Li, Haijun Zhang, Quanli Jia, Shaowei Zhang
Summary: In this study, a hierarchical electrocatalyst was developed for efficient hydrogen production from water. The electrocatalyst exhibited superior performance compared to most documented transition metal phosphides electrocatalysts and even Pt catalyst. The remarkable performance was attributed to the porous nature of the substrate and the special surface structure and electronic properties of the electrocatalyst.
Article
Chemistry, Applied
Xuefeng Liu, Yuantao Pei, Liang Huang, Wen Lei, Faliang Li, Yage Li, Haijun Zhang, Quanli Jia, Shaowei Zhang
Summary: This study presents a hierarchical electrocatalyst of flower-like FeNiP-LDH/CF with excellent HER performance, attributed to its special structure and component advantages, as well as satisfactory porous structure and surface electronic properties.
Article
Chemistry, Physical
Yu Zhang, Keke Xu, Bo Zhang, Shundong Guan, Xiuli Fu, Zhijian Peng
Summary: This study synthesized praseodymium-doped NiCoP nanowire arrays as electrocatalysts and found that the introduction of Pr can modulate the morphology and electrical conductivity, leading to exceptional HER performance. When the additive molar amount of Pr is 10%, the electrode exhibited the highest electrocatalytic activity.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
A. Y. Chen, H. H. Liu, P. Qi, X. F. Xie, M. T. Wang, X. Y. Wang
Summary: 3D flower-like MoS2/NiCoHC composites were synthesized using MoS2 nanospheres as precursors, showing high specific capacity and cycling stability. Moreover, the asymmetric supercapacitor with MoS2/NiCoHC as positive electrode achieved a high power density.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Electrochemistry
Malarkodi Duraivel, Saravanan Nagappan, Kang Hyun Park, Kandasamy Prabakar
Summary: This article reports a low-cost and extremely stable bifunctional electrocatalyst for overall water splitting in alkaline medium. By using a simple hydrothermal method to grow self-supported transition metal oxide/hydroxides (including nickel hydroxide, manganese dioxide, and cobalt hydroxide) on a nickel foam substrate, low overpotential and high current density were achieved. Through long-term stability tests lasting 80 hours, the superior performance of these electrodes and their ability to replace expensive noble metals were demonstrated.
ELECTROCHIMICA ACTA
(2022)
Review
Engineering, Environmental
Lutfi K. Putri, Boon-Junn Ng, Ryan Yow Zhong Yeo, Wee-Jun Ong, Abdul R. Mohamed, Siang-Piao Chai
Summary: Hydrogen fuel is considered a clean energy alternative to fossil fuels, and water electrolysis is seen as a key technology for achieving a hydrogen economy. Nickel phosphides (NixPy), among transition metal-based compounds, have emerged as low-cost and catalytically active electrocatalysts for the hydrogen evolution reaction (HER). This review provides an overview of various doping approaches and explores the effects of doping on NixPy, aiming to guide the rational design of NixPy for efficient HER catalysis.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Environmental
Seunghyun Jo, Byeol Kang, Hyunjun Oh, JunHwa Kwon, Pilsoo Choi, Ki-Yeop Cho, Joo-Hyoung Lee, KwangSup Eom
Summary: Ni-P is a promising catalytic material for the hydrogen evolution reaction (HER) due to its high catalytic activity, highly competitive cost, and practical usefulness. To achieve the best catalytic performance, it is necessary to control the P ratio in Ni-P, as the catalytic kinetics of Ni-P depend on the number of reaction sites of the positively and negatively charged Ni and negatively charged P. A facile surface-treatment based on dealloying was introduced to control the surficial P ratio with multiple CV cycles. The 20 and 10 times cycled Ni-P/ CFPs showed improved catalytic activities and higher stabilities in acid and alkaline media.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Jinhui Li, Jinlei Wang, Feixiang Jiao, Yu Lin, Yaqiong Gong
Summary: The synthesized CoP/MoO2 electrocatalyst demonstrates excellent hydrogen evolution reaction (HER) activity and long-term stability in electrolytes with different pH values. By enhancing electron transfer and exposing active sites through electronic structure engineering, new possibilities for energy conversion technologies are presented.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
Huiting Hu, Yunhua Zheng, Yao Zhu, Long Qian, Ziyu Yuan, Yuting Dai, Tao Zhang, Dongya Yang, Fengxian Qiu
Summary: In this study, cactus-like bimetallic nickel-cobalt nanosheets with a 3D nanostructure were successfully prepared, and a high-efficiency bimetallic catalyst was obtained. The catalyst showed low overpotential, fast hydrogen evolution kinetics, and excellent stability, providing a useful technique and guide for designing efficient electrocatalysts for hydrogen evolution.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Article
Chemistry, Physical
Sankar Sekar, S. Brindha Devi, S. Maruthasalamoorthy, T. Maiyalagan, Deuk Young Kim, Sejoon Lee, R. Navamathavan
Summary: In this study, reduced graphene oxide decorated-cobalt disulfide (rGO-CoS2) nanocomposites were synthesized via a one-step hydrothermal method. The nanocomposites exhibited excellent hydrogen evolution reaction (HER) activities with low overpotential and small Tafel slope, providing a promising scheme for developing efficient rGO-CoS2 electrocatalysts in future green energy technology.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Materials Science, Ceramics
Lei Zhang, Zhihui Hu, Juntong Huang, Zhi Chen, Xibao Li, Zhijun Feng, Huiyong Yang, Saifang Huang, Ruiying Luo
Summary: This work presents a facile method for preparing efficient and stable non-precious metal catalysts. By adjusting the concentration of nickel nitrate, control over the morphology, structure, and electrocatalytic activity of Mo2C is achieved. It is found that moderate nickel doping can greatly enhance the performance of the catalyst, while excessive doping has a negative effect on the catalytic activity.
JOURNAL OF ADVANCED CERAMICS
(2022)
Article
Chemistry, Physical
Guoqing Huang, Lei Zhao, Shisheng Yuan, Nan Li, Shubo Jing
Summary: A self-supporting electrode fabricated by covering iron doped mesoporous cobalt phosphide film on carbon cloth substrate (meso-FexCo1-xP/CC) was reported for hydrogen evolution reaction (HER). The electrode exhibited excellent catalytic activity and fast kinetics towards the HER in acidic and alkaline electrolytes. The superior electrocatalytic activity is attributed to the mesoporous structure with high specific surface area and doping of Fe atom.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Materials Science, Multidisciplinary
Jintang Li, Yongji Xia, Xianrui Luo, Tianle Mao, Zhenjia Wang, Zheyu Hong, Guanghui Yue
Summary: Researchers have successfully designed and synthesized a three-dimensional structured catalyst of nickel-cobalt sulfide composite decorated on carbon fiber paper, which shows high activity and stability for the oxygen evolution reaction. The excellent catalytic performance of the nanocomposite can be attributed to its large exposed active sites, firm anchoring on the substrate, improved catalytic performance by mixed valence of Ni or Co, and efficient electron and ion transmission. This study provides a simple and economical method to obtain high-performance and robust oxygen evolution reaction catalysts.
Article
Chemistry, Physical
Wenxiu Zhang, Maosheng Liu, Hui Liang, Liang Cui, Wenrong Yang, Joselito M. Razal, Jingquan Liu
Summary: This study presents a simple method for preparing high-performance electrochemical water-splitting catalysts by synthesizing Mo3S4/Co1-xS composites, which significantly enhance catalytic activity and stability in an alkaline environment.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Chemistry, Physical
Vikas Pundir, Ashish Gaur, Rajdeep Kaur, Jatin Sharma, Rajinder Kumar, Vivek Bagchi
Summary: A nano-sheet catalyst with high efficiency in water splitting was developed through the design and construction of multi-heterointerfaces, demonstrating high current density and stability in hydrogen and oxygen evolution reactions.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Physical
Lei Li, David J. Neivandt
JOURNAL OF PHYSICAL CHEMISTRY C
(2016)
Article
Materials Science, Ceramics
Jingjing Xu, Shengjuan Li, Lei Li, Leyi Chen, Yufang Zhu
CERAMICS INTERNATIONAL
(2018)
Article
Materials Science, Multidisciplinary
Lei Li, Yufang Zhu, Junhe Yang
Article
Materials Science, Paper & Wood
Lei Li, David J. Neivandt
Article
Chemistry, Physical
Shengjuan Li, Kun Wu, Lei Li, Lulu Suo, Yufang Zhu
APPLIED SURFACE SCIENCE
(2019)
Article
Polymer Science
Lei Li, Minjian Cao, Jingdan Li, Cong Wang, Shengjuan Li
Summary: In this study, alkyl ketene dimer (AKD) was used as a sizing agent for cellulose nanofibers (CNF) to improve the interfacial compatibility between CNF and PLA, enhancing the mechanical properties of the composites. The addition of CNF resulted in rough surfaces and increased strength of the composites, with the best performance achieved using 5.0 wt.% of AKD-cellulose combination.
Article
Polymer Science
Lei Li, Jingdan Li, Hao Luo, Shengjuan Li, Junhe Yang
Summary: In this study, 3D-printed TiO2/chitin/cellulose composite photocatalysts with ordered interconnected porous structures were prepared. The chitin interfered with the crystalline regeneration of cellulose and TiO2 nanoparticles were embedded on the chitin/cellulose composite surfaces, resulting in improved photocatalytic performance. The composite photocatalysts demonstrated efficient and stable degradation activities for dye in water, with the chitin content affecting the degradation efficiency.
Article
Materials Science, Multidisciplinary
Xiaohong Chen, Yujie Liu, Hang Liu, Lei Li, Yubo Liu, Ping Liu, Xinghai Yang
Summary: In this study, a poly(epsilon-caprolactone)/hydroxyapatite/simvastatin (PCL/HA/SIM) composite with a 3D hierarchical porous structure was successfully fabricated. The SEM images showed that an increase in HA content in the composite decreased the diameter of micropores on the surface. The composite scaffold exhibited superior strength compared to the pure PCL scaffold, with the maximum strength occurring at 27.3 wt% of HA. In vitro cultivation of 3T3 cells demonstrated that more HA content facilitated cell proliferation, and the addition of 0.2 wt% of SIM significantly promoted proliferation and osteogenic gene expression.
JOURNAL OF MATERIALS SCIENCE
(2023)
Article
Polymer Science
Lei Li, Pengfei Lu, Yuting Liu, Junhe Yang, Shengjuan Li
Summary: In this study, 3D bioactive glass/lignocellulose composite scaffolds were successfully fabricated by 3D-printing with NMMO as the ink solvent. The scaffolds showed uniform macropores and rough surfaces, with excellent mechanical properties and hydroxyapatite-forming capability. They also exhibited low cytotoxicity to human bone marrow mesenchymal stem cells. These 3D-printed BG/cellulose scaffolds have potential applications in bone tissue engineering.
Article
Materials Science, Multidisciplinary
GS Cheng, LD Zhang, SH Chen, Y Li, L Li, XG Zhu, Y Zhu, GT Fei, YQ Mao
JOURNAL OF MATERIALS RESEARCH
(2000)