Activation, Deactivation and Reversibility Phenomena in Homogeneous Catalysis: A Showcase based on the Chemistry of Rhodium/Phosphine Catalysts.

Dehydropolymerization of H3B·NMeH2 Using a [Rh(DPEphos)]+ Catalyst: The Promoting Effect of NMeH2

(2019) Gemma M. Adams et al.   ACS Catalysis

Highly Enantioselective Rhodium-Catalyzed Cross-Addition of Silylacetylenes to Cyclohexadienone-Tethered Internal Alkynes

(2019) Chang-Lin Duan et al.   ORGANIC LETTERS

Catalytic Generation of Rhodium Silylenoid for Alkene–Alkyne–Silylene [2 + 2 + 1] Cycloaddition

(2019) Toshimichi Ohmura et al.   ORGANIC LETTERS

Oxidative addition of CH 2 Cl 2 to neutral dimeric rhodium diphosphine complexes

(2018) Alberto Mannu et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Chemo-, Regio-, and Enantioselective Rhodium-Catalyzed Allylation of Triazoles with Internal Alkynes and Terminal Allenes

(2018) Dino Berthold et al.   ORGANIC LETTERS

Direct Conversion of Ethyl Ketone to Alkyl Ketone via Chelation-Assisted Rhodium(I)-Catalyzed Carbon–Carbon Bond Cleavage: Ligands Play an Important Role in the Inhibition of β-Hydrogen Elimination

(2018) Shutao Wu et al.   ORGANOMETALLICS

Hydrogenation of itaconic acid in micellar solutions: catalyst recycling with cloud point extraction?

(2018) Marcel Schmidt et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Rhodium-Catalyzed Tandem Addition–Cyclization–Rearrangement of Alkynylhydrazones with Organoboronic Acids

(2018) Kyoungmin Choi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Hydrothiolation: Regio- and Enantioselective Coupling of Thiols and Dienes

(2018) Xiao-Hui Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Monomerisation of [Rh2(1,3-bis-(diphenylphosphino)-propane)2(μ2-Cl)2] detected by pulsed gradient spin echo spectroscopy and 31P NMR monitoring of metathesis experiments

(2018) Alberto Mannu et al.   JOURNAL OF CHEMICAL RESEARCH

A Matter of Life(time) and Death

(2018)   ACS Catalysis

Palladium- and Rhodium-Catalyzed Dynamic Kinetic Resolution of Racemic Internal Allenes Towards Chiral Pyrazoles

(2018) Bernhard Breit et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Thioether-Directed Peri-Selective C–H Arylation under Rhodium Catalysis: Synthesis of Arene-Fused Thioxanthenes

(2018) Sanghun Moon et al.   ORGANIC LETTERS

Nondirected C-H Alkenylation of Arenes with Alkenes under Rhodium Catalysis

(2018) Koushik Ghosh et al.   CHEMISTRY LETTERS

Oxidative Addition of Aryl Halides to Cationic Bis(phosphane)rhodium Complexes: Application in C-C Bond Formation

(2017) Anja König et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Chemo-, Regio-, and Enantioselective Rhodium-Catalyzed Allylation of Pyridazinones with Terminal Allenes

(2017) Shaista Parveen et al.   ORGANIC LETTERS

Rhodium/Lewis Acid Catalyzed Regioselective Addition of 1,3-Dicarbonyl Compounds to Internal Alkynes

(2017) Wei-Feng Zheng et al.   ORGANOMETALLICS

An Enantioselective Cascade Cyclopropanation Reaction Catalyzed by Rhodium(I): Asymmetric Synthesis of Vinylcyclopropanes

(2016) Òscar Torres et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium-Catalyzed [2+2+2] Cycloadditions of Diynes with Morita-Baylis-Hillman Adducts: A Stereoselective Entry to Densely Functionalized Cyclohexadiene Scaffolds

(2016) Martí Fernández et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Synthesis of Protected Cyclohexenylamines and Cyclohexenols by Rhodium-Catalyzed [2+2+2] Cycloaddition

(2016) Koji Masutomi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Exploiting Distal Reactivity of Coumarins: A Rhodium-Catalyzed Vinylogous Asymmetric Ring-Opening Reaction

(2016) Charles C. J. Loh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Enantioselective Silylation of Cyclopropyl C−H Bonds

(2016) Taegyo Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rh(I)-Catalyzed Insertion of Allenes into C–C Bonds of Benzocyclobutenols

(2016) Chunliang Zhao et al.   ORGANIC LETTERS

Rhodium-Catalyzed Asymmetric [2 + 2 + 2] Cycloaddition of α,ω-Diynes with Unsymmetrical 1,2-Disubstituted Alkenes

(2016) Yukimasa Aida et al.   ORGANIC LETTERS

Rhodium-Catalyzed C–H Bond Functionalization with Amides by Double C–H/C–N Bond Activation

(2016) Guangrong Meng et al.   ORGANIC LETTERS

Rhodium-Catalyzed Cyclization of 2-Ethynylanilines in the Presence of Isocyanates: Approach toward Indole-3-carboxamides

(2016) Akiho Mizukami et al.   ORGANIC LETTERS

Rhodium-Catalyzed Asymmetric [2 + 2 + 2] Cycloaddition of 1,6-Enynes with Cyclopropylideneacetamides

(2016) Soichi Yoshizaki et al.   ORGANIC LETTERS

Selective C–Cl Bond Oxidative Addition of Chloroarenes to a POP–Rhodium Complex

(2016) Sheila G. Curto et al.   ORGANOMETALLICS

Rhodium-catalyzed asymmetric synthesis of silicon-stereogenic silicon-bridged arylpyridinones

(2016) Ryo Shintani et al.   Chemical Science

Rhodium-Catalyzed Addition of Alkyltrifluoroborate Salts to Imines

(2015) Sumin Lee et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Rhodium-Catalyzed Addition of Thiols to Allenes: Synthesis of Branched Allylic Thioethers and Sulfones

(2015) Adrian B. Pritzius et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Investigations into Metal Leaching from Polystyrene-Supported Rhodium Catalysts

(2015) Christian Fischer et al.   ChemCatChem

Direct Synthesis of Chiral 3-Arylsuccinimides by Rhodium-Catalyzed Enantioselective Conjugate Addition of Arylboronic Acids to Maleimides

(2015) Balraj Gopula et al.   CHEMISTRY-A EUROPEAN JOURNAL

Looking Back on 35 Years of Industrial Catalysis

(2015) Hans-Ulrich Blaser   CHIMIA

Aryl carbon–chlorine (Ar–Cl) and aryl carbon–fluorine (Ar–F) bond cleavages by rhodium porphyrins

(2015) Ying Ying Qian et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Enantioselective Redox-Neutral Rh-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids Toward Branched Allylic Esters

(2015) Philipp Koschker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(I)-Catalyzed Asymmetric Carbene Insertion into B–H Bonds: Highly Enantioselective Access to Functionalized Organoboranes

(2015) Diao Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Amidation of N-Boc- and N-Cbz-Protected Amines via Rhodium-Catalyzed Coupling of Arylboroxines and Carbamates

(2015) Diane S. W. Lim et al.   ORGANIC LETTERS

Oxidative Addition of Chlorohydrocarbons to a Rhodium Tris(pyrazolyl)borate Complex

(2015) Yunzhe Jiao et al.   ORGANOMETALLICS

Heterogeneous Catalyst Deactivation and Regeneration: A Review

(2015) Morris Argyle et al.   Catalysts

Deactivation in Homogeneous Transition Metal Catalysis: Causes, Avoidance, and Cure

(2014) Robert H. Crabtree   CHEMICAL REVIEWS

New Pentacoordinated Rhodium Species as Unexpected Products during the In Situ Generation of Dimeric Diphosphine-Rhodium Neutral Catalysts

(2014) Antje Meißner et al.   CHEMISTRY-A EUROPEAN JOURNAL

Quantitative UV/Vis Spectroscopic Investigations of the In Situ Synthesis of Neutral μ2-Chloro-Bridged Dinuclear (Diphosphine)rhodium Complexes

(2014) Christian Fischer et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis and Characterization of Cationic Synphos-Rhodium Complexes

(2014) Antje Meißner et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Rhodium-Catalyzed Chemo- and Regioselective Decarboxylative Addition of β-Ketoacids to Allenes: Efficient Construction of Tertiary and Quaternary Carbon Centers

(2014) Changkun Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fate of Aryl/Amido Complexes of Rhodium(III) Supported by a POCOP Pincer Ligand: C–N Reductive Elimination, β-Hydrogen Elimination, and Relevance to Catalysis

(2014) Samuel D. Timpa et al.   ORGANOMETALLICS

Rhodium diphosphine complexes: a case study for catalyst activation and deactivation

(2014) Antje Meißner et al.   Catalysis Science & Technology

Enantioselective Synthesis of Planar-Chiral Carba-Paracyclophanes: Rhodium-Catalyzed [2+2+2] Cycloaddition of Cyclic Diynes with Terminal Monoynes

(2013) Tatsuya Araki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Synthesis of Allylic Alcohols and Derivatives and their Applications in Organic Synthesis

(2013) Alexandre Lumbroso et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atroposelective [2+2+2] cycloadditions catalyzed by a rhodium(i)–chiral phosphate system

(2013) Mylène Augé et al.   CHEMICAL COMMUNICATIONS

Development of an Improved Rhodium Catalyst forZ-Selective Anti-Markovnikov Addition of Carboxylic Acids to Terminal Alkynes

(2013) Siping Wei et al.   CHEMISTRY-A EUROPEAN JOURNAL

Formation of Trinuclear Rhodium-Hydride Complexes [{Rh(PP*)H}3- (μ2-H)3(μ3-H)][anion]2-During Asymmetric Hydrogenation?

(2013) C. Kohrt et al.   CHEMISTRY-A EUROPEAN JOURNAL

C–Cl activation of the weakly coordinating anion [B(3,5-Cl2C6H3)4]− at a Rh(i) centre in solution and the solid-state

(2013) Sebastian D. Pike et al.   DALTON TRANSACTIONS

Highly Enantioselective Rhodium-Catalyzed [2+2+2] Cycloaddition of Diynes to Sulfonimines

(2013) Muriel Amatore et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Investigations of the Rhodium Catalyzed Propargylic CH Activation

(2013) Urs Gellrich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Regio-, Diastereo-, and Enantioselective [2+2+2] Cycloaddition of 1,6-Enynes with Acrylamides

(2012) Koji Masutomi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Intramolecular Cyclization of Naphthol- or Phenol-Linked 1,6-Enynes Through the Cleavage and Formation of sp2CO Bonds

(2012) Norifumi Sakiyama et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Investigations into the Formation and Stability of Cationic Rhodium Diphosphane η6-Arene Complexes

(2012) Christian Fischer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Molecular Vibration Spectroscopy Studies on Novel Trinuclear Rhodium-7-Hydride Complexes of the General Type {[Rh(PP*)X]3(μ2-X)3(μ3-X)}(BF4)2 (X = H, D)

(2012) Christina Kohrt et al.   INORGANIC CHEMISTRY

Determination of Gas Concentrations in Liquids by Nuclear Magnetic Resonance: Hydrogen in Organic Solvents

(2012) Mario Baseda Krüger et al.   JOURNAL OF CHEMICAL AND ENGINEERING DATA

Halide bridged trinuclear rhodium complexes and their inhibiting influence on catalysis

(2012) Angelika Preetz et al.   Catalysis Science & Technology

Rhodium-Catalyzed Aerobic Coupling between Aldehydes and Arenesulfinic Acid Salts: A Novel Synthesis of Aryl Ketones

(2011) Honghua Rao et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium-Catalyzed Intermolecular [2+2+2] Cross-Trimerization of Aryl Ethynyl Ethers and Carbonyl Compounds To Produce Dienyl Esters

(2011) Yuta Miyauchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Influence of Substituents in Diphosphine Ligands on the Hydrogenation Activity and Selectivity of the Corresponding Rhodium Complexes as Exemplified by ButiPhane

(2011) Christian Fischer et al.   ChemCatChem

Captured at last: a catalyst–substrate adduct and a Rh-dihydride solvate in the asymmetric hydrogenation by a Rh-monophosphine catalyst

(2011) Ilya D. Gridnev et al.   CHEMICAL COMMUNICATIONS

Unravelling the Reaction Path of Rhodium-MonoPhos-Catalysed Olefin Hydrogenation

(2011) Elisabetta Alberico et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Asymmetric [2+2+2] Cyclization of 1,6-Enynes and Aldehydes

(2011) Mana Ishida et al.   CHEMISTRY-A EUROPEAN JOURNAL

Trinuclear rhodium hydride complexes

(2011) Christian Fischer et al.   DALTON TRANSACTIONS

Catalysis of Kumada–Tamao–Corriu coupling by a (POCOP)Rh pincer complex

(2011) Samuel D. Timpa et al.   DALTON TRANSACTIONS

Total Synthesis of Bryostatin 7viaC–C Bond-Forming Hydrogenation

(2011) Yu Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Neutral Atom-Economic Rhodium-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids Toward Branched Allylic Esters

(2011) Alexandre Lumbroso et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Branched Allylic Esters via Rhodium-Catalyzed Coupling of Allenes with Carboxylic Acids

(2011) Philipp Koschker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cationic Rhodium-BINAP Complexes: Full Characterization of Solvate- and Arene-Bridged Dimeric Species

(2011) Angelika Preetz et al.   ORGANOMETALLICS

Competition Studies of Oxidative Addition of Aryl Halides to the (PNP)Rh Fragment

(2011) Mayank Puri et al.   ORGANOMETALLICS

Rhodium catalyzed hydrogenation reactions in aqueous micellar systems as green solvents

(2011) M. Schwarze et al.   RSC Advances

Asymmetric Ring Opening of Benzo-7-oxabicyclo[2.2.1]heptadienes with Cationic Rhodium Complexes

(2010) Angelika Preetz et al.   ADVANCED SYNTHESIS & CATALYSIS

Reactivity of the Latent 12-Electron Fragment [Rh(PiBu3)2]+ with Aryl Bromides: ArylBr and Phosphine Ligand CH Activation

(2010) Nell S. Townsend et al.   CHEMISTRY-A EUROPEAN JOURNAL

Unusual deactivation in the asymmetric hydrogenation of itaconic acid

(2010) T. Schmidt et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Rhodium-Catalyzed Selectiveanti-Markovnikov Addition of Carboxylic Acids to Alkynes

(2010) Alexandre Lumbroso et al.   ORGANIC LETTERS

BINAP: rhodium–diolefin complexes in asymmetric hydrogenation

(2010) Angelika Preetz et al.   TETRAHEDRON-ASYMMETRY

Unusual Deactivation in the Asymmetric Hydrogenation of Itaconic Acid

(2009) Thomas Schmidt et al.   ADVANCED SYNTHESIS & CATALYSIS

Kinetic and mechanistic investigations in homogeneous catalysis using operando UV/vis spectroscopy

(2009) Christian Fischer et al.   CATALYSIS TODAY

Mechanism of enantioselection in Rh-catalyzed asymmetric hydrogenation. The origin of utmost catalytic performance

(2009) Ilya D. Gridnev et al.   CHEMICAL COMMUNICATIONS

Rh(I)-Catalyzed CO Gas-Free Carbonylative Cyclization Reactions of Alkynes with 2-Bromophenylboronic Acids Using Formaldehyde

(2009) Tsumoru Morimoto et al.   ORGANIC LETTERS

Asymmetric Hydrogenation. Dimerization of Solvate Complexes: Synthesis and Characterization of Dimeric [Rh(DIPAMP)]22+, a Valuable Catalyst Precursor

(2009) Angelika Preetz et al.   ORGANOMETALLICS

Trinuclear Rhodium Complexes and Their Relevance for Asymmetric Hydrogenation

(2008) Angelika Preetz et al.   Chemistry-An Asian Journal

Single and Double CCl-Activation of Methylene Chloride by P,N-ligand Coordinated Rhodium Complexes

(2008) Benoît Blank et al.   Chemistry-An Asian Journal

Chelation-Assisted Carbon-Halogen Bond Activation by a Rhodium(I) Complex

(2008) Shanshan Chen et al.   INORGANIC CHEMISTRY

Reagent-Controlled Regiodivergent Resolution of Unsymmetrical Oxabicyclic Alkenes Using a Cationic Rhodium Catalyst

(2008) Robert Webster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Amine-Assisted C−Cl Bond Activation of Aryl Chlorides by a (Phebox)Rh-Chloro Complex

(2008) Jun-ichi Ito et al.   ORGANOMETALLICS

Dihydrogen Loss from a 14-Electron Rhodium(III) Bis-Phosphine Dihydride To Give a Rhodium(I) Complex That Undergoes Oxidative Addition with Aryl Chlorides

(2008) Thomas M. Douglas et al.   ORGANOMETALLICS

Rhodium-Complex-Catalyzed Asymmetric Hydrogenation: Transformation of Precatalysts into Active Species

(2007) Angelika Preetz et al.   CHEMISTRY-A EUROPEAN JOURNAL