Journal
MRS COMMUNICATIONS
Volume 9, Issue 3, Pages 910-915Publisher
SPRINGER HEIDELBERG
DOI: 10.1557/mrc.2019.88
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Funding
- Japan Society for the Promotion of Science (JSPS KAKENHI) [JP15H04127]
- Japan Society for Promotion of Science (JSPS), Japan
- State of North Carolina
- [JP17F17380]
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We report on the structural evolution of diamond-like carbon (DLC) films by the nanosecond pulsed laser annealing process. DLC film is coated on cemented carbide (WC-Co) by cathodic arc ion plating, which is then annealed by ArF laser (193 nm, 20 ns) at different laser fluences (0.9-1.7 J/cm(2)). Upon laser annealing, Raman spectra divulge higher sp(3) fractions accompanied by a blue shift in the G-peak position, which indicates the changes of sp(2) sites from rings to chains. At higher fluence (>1.2 J/cm(2)), the film converts into reduced graphene oxide confirmed by its Raman-active vibrational modes: D, G, and 2D.
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