Switching between Copper‐Catalysis and Photocatalysis for Tunable Halofluoroalkylation and Hydrofluoroalkylation of 1,6‐Enynes toward 1‐Indenones

Recent applications of radical cascade reaction in the synthesis of functionalized 1-indenones

(2019) Yinli Zhang et al.   CHINESE CHEMICAL LETTERS

Stereoselective synthesis of sulfonated 1-indenones via radical-triggered multi-component cyclization of β-alkynyl propenones

(2018) Zheng-Jia Shen et al.   CHEMICAL COMMUNICATIONS

Halogen-bond-mediated atom transfer radical addition of perfluoroalkyl iodides to alkynes under visible light irradiation

(2018) Xiaoyang Sun et al.   JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY

Stereoselective cobalt-catalyzed halofluoroalkylation of alkynes

(2018) Guojiao Wu et al.   Chemical Science

The Different Faces of Photoredox Catalysts: Visible-Light-Mediated Atom Transfer Radical Addition (ATRA) Reactions of Perfluoroalkyl Iodides with Styrenes and Phenylacetylenes

(2018) Thomas Rawner et al.   ACS Catalysis

Visible-light-induced methylsulfonylation/bicyclization of C(sp3)-tethered 1,7-enynes using a DMSO/H2O system

(2018) Min-Hua Huang et al.   Organic Chemistry Frontiers

Visible-light photocatalytic bicyclization of β-alkynyl propenones for accessing diastereoenriched syn-fluoren-9-ones

(2018) Zheng-Jia Shen et al.   CHEMICAL COMMUNICATIONS

Recent advances in radical transformations of internal alkynes

(2018) Min-Hua Huang et al.   CHEMICAL COMMUNICATIONS

Pd(II)-Catalyzed Carbonyl-Directing Activation of Alkenes: Selective Fluorosulfonylation and Aminosulfonylation of 1,7-Enynes

(2018) Yi-Long Zhu et al.   JOURNAL OF ORGANIC CHEMISTRY

Substrate-Controlled Generation of 3-Sulfonylated 1-Indenones and 3-Arylated (Z)-Indenes via Cu-Catalyzed Radical Cyclization Cascades of o-Alkynylbenzonitriles

(2018) Xiao-Tong Zhu et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Radical Cascade Cyclization To Access 3-Sulfonated Indenones with the AIE Phenomenon

(2018) Kai Sun et al.   JOURNAL OF ORGANIC CHEMISTRY

Cu-Catalyzed Aminodifluoroalkylation of Alkynes and α-Bromodifluoroacetamides

(2017) Yunhe Lv et al.   JOURNAL OF ORGANIC CHEMISTRY

Fine Design of Photoredox Systems for Catalytic Fluoromethylation of Carbon–Carbon Multiple Bonds

(2016) Takashi Koike et al.   ACCOUNTS OF CHEMICAL RESEARCH

Benzophenonevs. Copper/Benzophenone in Light-Promoted Atom Transfer Radical Additions (ATRAs): Highly Effective Iodoperfluoroalkylation of Alkenes/Alkynes and Mechanistic Studies

(2016) Redouane Beniazza et al.   ADVANCED SYNTHESIS & CATALYSIS

Next Generation of Fluorine-Containing Pharmaceuticals, Compounds Currently in Phase II–III Clinical Trials of Major Pharmaceutical Companies: New Structural Trends and Therapeutic Areas

(2016) Yu Zhou et al.   CHEMICAL REVIEWS

Visible light photoredox-controlled reactions of N-radicals and radical ions

(2016) Jia-Rong Chen et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of 2-Sulfenylindenones via One-Pot Tandem Meyer–Schuster Rearrangement and Radical Cyclization of Arylpropynols with Disulfides

(2016) Xing-Song Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Photoredox Catalysis in Organic Chemistry

(2016) Megan H. Shaw et al.   JOURNAL OF ORGANIC CHEMISTRY

C–H Difluoroalkylation of Aldehyde Hydrazones with Functionalized Difluoromethyl Bromides under Copper Catalysis

(2016) Alexis Prieto et al.   ACS Catalysis

Thiyl-Radical-Catalyzed Photoreductive Hydrodifluoroacetamidation of Alkenes with Hantzsch Ester as a Multifunctional Reagent

(2016) Wenhao Huang et al.   ACS Catalysis

Radical Decarboxylative Functionalizations Enabled by Dual Photoredox Catalysis

(2016) Hanchu Huang et al.   ACS Catalysis

Efficient Cu-catalyzed Atom Transfer Radical Addition Reactions of Fluoroalkylsulfonyl Chlorides with Electron-deficient Alkenes Induced by Visible Light

(2015) Xiao-Jun Tang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoredox-Catalyzed Stereoselective Conversion of Alkynes into Tetrasubstituted Trifluoromethylated Alkenes

(2015) Ren Tomita et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Progress toward the Introduction of Functionalized Difluoromethylated Building Blocks onto C(sp2) and C(sp) Centers

(2015) Marie-Charlotte Belhomme et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Fluorine-Containing Phosphodiesterase 10A (PDE10A) Inhibitors and the In Vivo Evaluation of F-18 Labeled PDE10A PET Tracers in Rodent and Nonhuman Primate

(2015) Junfeng Li et al.   JOURNAL OF MEDICINAL CHEMISTRY

Applications of Fluorine in Medicinal Chemistry

(2015) Eric P. Gillis et al.   JOURNAL OF MEDICINAL CHEMISTRY

Gold-Catalyzed Ammonium Acetate Assisted Cascade Cyclization of 2-Alkynylarylketones

(2015) Maciej E. Domaradzki et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Selective Pd-Catalyzed Intermolecular Fluorosulfonylation of Styrenes

(2015) Zheliang Yuan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

MeOTf-Induced Carboannulation of Isothiocyanates and Aryl Alkynes with C═S Bond Cleavage: Access to Indenones

(2015) Peng Zhao et al.   ORGANIC LETTERS

Palladium-Catalyzed Radical Cascade Iododifluoromethylation/Cyclization of 1,6-Enynes with Ethyl Difluoroiodoacetate

(2015) Yu-Qi Wang et al.   ORGANIC LETTERS

Copper-Catalyzed trans-Carbohalogenation of Terminal Alkynes with Functionalized Tertiary Alkyl Halides

(2015) Chao Che et al.   ORGANIC LETTERS

cis-Specific Hydrofluorination of Alkenylarenes under Palladium Catalysis through an Ionic Pathway

(2014) Enrico Emer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed 1,2-Addition of Perfluoroalkyl Iodides to Alkynes and Alkenes

(2014) Tao Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

MeOTf-induced carboannulation of arylnitriles and aromatic alkynes: a new metal-free strategy to construct indenones

(2014) Xiaoyu Yan et al.   CHEMICAL COMMUNICATIONS

Copper-Catalyzed C–H Functionalization Reactions: Efficient Synthesis of Heterocycles

(2014) Xun-Xiang Guo et al.   CHEMICAL REVIEWS

Copper-Catalyzed Oxidative Cyclization of 1,5-Enynes with Concomitant C–C Bond Cleavage: An Unexpected Access to 3-Formyl-1-indenone Derivatives

(2014) Jian Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

6-Perfluoroalkylated Phenanthridines via Radical Perfluoroalkylation of Isonitriles

(2014) Bo Zhang et al.   ORGANIC LETTERS

Controlled Trifluoromethylation Reactions of Alkynes through Visible-Light Photoredox Catalysis

(2013) Naeem Iqbal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The TV in Your Pocket: Development of Liquid-Crystal Materials for the New Millennium

(2013) Matthias Bremer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)

(2013) Jiang Wang et al.   CHEMICAL REVIEWS

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

The influence of fluorine in asymmetric catalysis

(2013) Dominique Cahard et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Allylic C–H Fluorination

(2013) Marie-Gabrielle Braun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium(III)-Catalyzed Fluorination of Arylboronic Acid Derivatives

(2013) Anthony R. Mazzotti et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Mediated Fluorination of Arylboronate Esters. Identification of a Copper(III) Fluoride Complex

(2013) Patrick S. Fier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Direct Annulation of Aldehydes with Alkynes Leading to Indenones: Proceeding through in Situ Directing Group Formation and Removal

(2013) Shuyou Chen et al.   ORGANIC LETTERS

Rhodium/Copper-Catalyzed Annulation of Benzimides with Internal Alkynes: Indenone Synthesis through Sequential CH and CN Cleavage

(2012) Bi-Jie Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Magnetite-loaded fluorine-containing polymeric micelles for magnetic resonance imaging and drug delivery

(2012) Xiaolong Li et al.   BIOMATERIALS

Ring Expansion of Cyclic β-Amino Alcohols Induced by Diethylaminosulfur Trifluoride: Synthesis of Cyclic Amines with a Tertiary Fluorine at C3

(2012) Bruno Anxionnat et al.   JOURNAL OF ORGANIC CHEMISTRY

Silver-Catalyzed Decarboxylative Fluorination of Aliphatic Carboxylic Acids in Aqueous Solution

(2012) Feng Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible Light-Mediated Atom Transfer Radical Addition via Oxidative and Reductive Quenching of Photocatalysts

(2012) Carl-Johan Wallentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermolecular Atom Transfer Radical Addition to Olefins Mediated by Oxidative Quenching of Photoredox Catalysts

(2011) John D. Nguyen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Manganese(iii)-mediated direct phosphonation of arylalkenes and arylalkynes

(2010) Xiang-Qiang Pan et al.   CHEMICAL COMMUNICATIONS

Silver-Catalyzed Late-Stage Fluorination

(2010) Pingping Tang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhenium-Catalyzed Synthesis of Indenones by Novel Dehydrative Trimerization of Aryl Aldehydes via C−H Bond Activation

(2010) Yoichiro Kuninobu et al.   ORGANIC LETTERS

Enantioselective α-Trifluoromethylation of Aldehydes via Photoredox Organocatalysis

(2009) David A. Nagib et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Many Roles for Fluorine in Medicinal Chemistry

(2008) William K. Hagmann   JOURNAL OF MEDICINAL CHEMISTRY

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS