Journal
MOLECULAR CATALYSIS
Volume 467, Issue -, Pages 150-160Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.mcat.2019.02.004
Keywords
DeNO(x); NH3-SCR; Hydrotalcite; Mixed oxide; Morphology
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Funding
- National Natural Science Foundation of the China [21073131]
- Shanxi Provincial [201601D10207]
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In this work, NiO phase was decorated by titanium species to achieve NiTi mixed oxides acting as NH3-SCR catalysts, (NiTi-IMP, NiTi-SOL and NiTi-LDO) which were fabricated via solution-impregnation, one-pot sol-gel and urea homogeneous precipitation methods followed by a calcination process. The microstructure and morphology features as well as the inherent morphology-activity relationship of resultant samples were fully characterized by XRD, BET, SEM, TEM/HRTEM, XPS, ICP-AES, NH3-TPD and H-2-TPR. The results pronouncedly affirmed that the NiTi-LDO behaved the optimum SCR performance, affording a desiring efficiency (over 90% NO conversion within the temperature region of 240-360 degrees C), preferable N-2 selectivity (nearby 95% at the whole test temperature zone), superior catalytic stability and SO2/H2O resistance. The improvement of catalytic performance could be attributed to the assistance of hydrotalcite-like precursor possessing special morphology structure, and the subsequently generated favorable interfacial interaction as well as the atomic-level dispersion of active component during the calcination process.
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