Article
Engineering, Chemical
Jacob Strimaitis, Samuel Adjepong Danquah, Clifford F. Denize, Sangram K. Pradhan, Messaoud Bahoura
Summary: Researchers incorporated synthesized GO and rGO in AC electrodes and found that they moderately enhance the rate resistance and capacity. However, the overall ineffectiveness of GO and rGO is attributed to their isolation and infrequent distribution method.
Article
Chemistry, Inorganic & Nuclear
Suleyman Kerli, Shiva Bhardwaj, Wang Lin, Ram K. Gupta
Summary: In this study, graphene oxide was synthesized using the Hummers method and reduced graphene oxide was obtained via the hydrothermal method. Silver-doped Reduced Graphene Oxide/Polyaniline (Ag-doped rGO/PANI) composites were then synthesized. Physical and electrochemical properties of the composites were analyzed, and the material containing approximately 17% silver-doped reduced graphene oxide exhibited the best performance in terms of stability and specific capacitance.
JOURNAL OF ORGANOMETALLIC CHEMISTRY
(2023)
Article
Chemistry, Physical
Congxu Xuan, Xinyu Li, Zhun Wang, Hao Wu, Tao Tang, Jianfeng Wen, Ming Li, Jianrong Xiao
Summary: The strategy of embedding PANI into RGO/HCNT skeleton was designed to prepare a high-performance supercapacitor with remarkable gravimetric capacitance and cycling stability. The assembled flexible SC based on CRCP showed considerable electrochemical performance with high specific capacitance and energy density at 1A g(-1), while maintaining good performance stability at large bending angles.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Materials Science, Paper & Wood
Yuanji Ye, Yongkang Zhu, Peidi Zhou, Mingcen Weng
Summary: As a new type of smart device, soft actuators have gained attention for their simple structure, fast response, and wide range of applications. However, most soft actuators are driven by a single stimulus and lack versatile functionalities. To address this issue, a multi-functional and integrated actuator based on PANI@CNT-CNF composites is proposed. This actuator can respond to humidity and light, making it suitable for biomimetic applications and has the ability of energy storage. Furthermore, an integrated actuator that combines actuation and energy storage is designed and demonstrated to have potential for applications in smart devices.
Article
Energy & Fuels
Marwa Ben Hadj Said, Khaled Charradi, Zakarya Ahmed, Hubert Cachet, Catherine Debiemme-Chouvy, Qana A. Alsulami, Sami Boufi, Sherif M. A. S. Keshk, Radhouane Chtourou
Summary: A ternary composite electrode consisting of graphene oxide, cellulose hydrogel, and polyaniline was synthesized and electrochemically characterized. It showed significantly enhanced cycling stability and improved capacitance, indicating a synergistic effect of cellulose hydrogel on PANi-GO.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2022)
Article
Nanoscience & Nanotechnology
Qiaohang Guo, Congwei Li, Kaihuai Yang, Peidi Zhou, Nengbin Hua, Mingcen Weng
Summary: In this study, a smart gripper with a self-powered temperature-sensing function was designed and fabricated using polyaniline/reduced graphene oxide/carbon nanotube (PANI/RGO/CNT) composites. The composites exhibited a low coefficient of thermal expansion and negative temperature resistivity, allowing for the construction of a multifunctional bilayer actuator with a temperature-sensing function. Additionally, the PANI/RGO/CNT composite possessed a large-area capacitance, enabling the integration of energy storage modules into the actuator. Based on the structure and actuation mechanism of the bilayer actuators, a smart gripper with a self-powered temperature-sensing function was proposed.
ACS APPLIED NANO MATERIALS
(2023)
Article
Chemistry, Physical
Anjana Baby, Sachin Sunny, J. Vigneshwaran, Sibi Abraham, Sujin Jose, Waseem Sharaf Saeed, Mohan Reddy Pallavolu, Jayesh Cherusseri, Sreeja Puthenveetil Balakrishnan
Summary: Electronically conducting polymers (ECPs)/carbon nanomaterial-based polyaniline electrodes have attracted significant interest in the field of supercapacitors due to their exceptional electrochemical properties. In this study, a PANI-grafted graphene oxide (GO)-azopyridine (Azo) nanocomposite was synthesized and utilized as electrodes for fabricating supercapacitors. The nanocomposite exhibited a high gravimetric capacitance of 426 F g(-1) and excellent cycling stability. An asymmetric supercapacitor constructed with PANI/GO-Azo as the positive electrode delivered a high energy density of 12.45 W h kg(-1) with a power density of 274.9 W kg(-1). These findings highlight the promising potential of the PANI/GO-Azo nanocomposite electrode for next-generation supercapacitors.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Energy & Fuels
Jnanendra Upadhyay, Rajiv Borah, Trishna Moyi Das, Jitu Mani Das
Summary: This study focuses on the development of flexible and compact supercapacitor materials with high energy density and high-power density. By embedding ruthenium oxide nanoparticles and polyaniline nanofibers in reduced graphene oxide, the researchers were able to maximize the electric double layer capacitance and integrate the pseudo-capacitance of the materials within the ternary nanocomposites. The resulting materials exhibited improved charge-transfer kinetics and achieved high capacitance and energy density in a flexible symmetric solid-state device.
JOURNAL OF ENERGY STORAGE
(2023)
Article
Chemistry, Physical
Misganu Chewaka Fite, Toyoko Imae
Summary: The study evaluated the effects of adding conductive materials (PA or Cdots) to supercapacitors made of nitrogen-doped graphene oxide (NG) and magnetic nanoparticles (Fe3O4). It was found that composites with a small amount of Cdots showed better performance compared to those with PA, especially when coupled with an external magnetic field. The results indicate that adequate ternary composite materials can effectively enhance specific capacitance and durability of supercapacitors under magnetic fields.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Energy & Fuels
Muhammad Shahid Khan, Imran Murtaza, Ahmed Shuja, Muhammad Adeel Asghar, Carlos Garcia Nunez, Rehan Abid, Ali Haider, Muhammad Faraz
Summary: A novel composite material was developed and used as an electrode for supercapacitors. The composite exhibited significantly improved electrochemical performance, indicating its potential for practical applications.
JOURNAL OF ENERGY STORAGE
(2023)
Article
Materials Science, Multidisciplinary
K. Hareesh, Sachin R. Rondiya, S. D. Dhole, M. A. More, D. M. Phase
Summary: Through comparison experiments, it was found that the CoFe2O4/rGO/CNT emitter has higher current density and emission stability compared to other types of emitters, due to its reduced bandgap and work function, as well as sharp edges provided for easy electron liberation.
Article
Energy & Fuels
Reza Teimuri-Mofrad, Elmira Payami
Summary: This study focuses on the improvement of energy and power densities of supercapacitors by combining carbon nanotubes with redox-active materials. The novel electrode materials, which incorporate carbon nanotube and ferrocene, exhibit fast redox response and durable stability. The fabricated symmetric cell shows high capacity, excellent charge storage retention, and high energy and power densities.
JOURNAL OF ENERGY STORAGE
(2022)
Article
Polymer Science
Nagaraju Macherla, Kuldeep Singh, Kusum Kumari, Ram Gopal Reddy Lekkala
Summary: This study presents a simple and robust approach for designing an efficient and high-performance flexible electrode by doping nitrogen into reduced graphene oxide (N-rGO) and surface chemical polymerization with aniline to form interconnected polyaniline (PANI) nanostructures. The PANI/N-rGO flexible electrode exhibits a higher specific capacitance and notable cyclic stability in a two-electrode system, thanks to the surface-modified in-situ grown PANI nanostructures on N-rGO nanosheets.
POLYMERS FOR ADVANCED TECHNOLOGIES
(2022)
Article
Polymer Science
Ozan Yoruk, Yuksel Bayrak, Murat Ates
Summary: Superior performance of a ternary nanocomposite material consisting of TiO2 and rGO, added to PANI, was observed through various analysis and tests, showing enhanced specific capacitance, energy density, power density, and cycle life compared to individual components.
Article
Chemistry, Physical
Iurii V. Panasenko, Mikhail O. Bulavskiy, Anna A. Iurchenkova, Yenanny Aguilar-Martinez, Fedor S. Fedorov, Ekaterina O. Fedorovskaya, Bjorn Mikladal, Tanja Kallio, Albert G. Nasibulin
Summary: Advancements in supercapacitor performance are driven by both material design and device architecture adjustments. This study focuses on designing unique dead-weight free supercapacitors based on PANI electrochemically deposited on free-standing SWCNT films. The research shows that thin free-standing films of SWCNTs with deposited PANI are less prone to self-discharge, enabling higher gravimetric capacitance values.
JOURNAL OF POWER SOURCES
(2022)
Article
Chemistry, Multidisciplinary
Iftikhar Hussain, Sumanta Sahoo, Tanveer Hussain, Muhammad Ahmad, Muhammad Sufyan Javed, Charmaine Lamiel, Shuai Gu, Thanayut Kaewmaraya, Mostafa Saad Sayed, Kaili Zhang
Summary: The hybrid electrode material, derived from MOF-derived Zr-Mn-oxide and solution-free CuO nanowires, demonstrates excellent electrochemical performance and stability, making it a promising candidate for next-generation supercapacitor electrodes.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Review
Engineering, Environmental
Iftikhar Hussain, Charmaine Lamiel, Muhammad Sufyan Javed, Muhammad Ahmad, Xi Chen, Sumanta Sahoo, Xiaoxia Ma, Majed A. Bajaber, Mohd Zahid Ansari, Kaili Zhang
Summary: The advancement of structured nanomaterials is crucial for the development of supercapacitor electrode materials. By evaluating various nanostructures, current challenges in electrode materials have been significantly improved. Nanomaterials with three-dimensional structures have been extensively explored due to their larger electrochemical active surface areas. This review summarizes the material development of hierarchical structures resembling earth-like and marine life-like morphology for supercapacitor electrode materials and discusses future ideas on sustainable production and assembly methods.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Rajesh Kumar, Sumanta Sahoo, Ednan Joanni
Summary: With the rapid progress in science and technology, the demand for electromagnetic interference (EMI) shielding and microwave (MW) absorption materials has been increasing. Layered materials, such as graphene, MXenes, and transition metal dichalcogenides (TMDs), have drawn significant research attention due to their conductivity, surface area, and porosity. The integration of these materials with other magnetic and dielectric constituents further enhances their electromagnetic absorption ability. This review article focuses on the recent progress, mechanisms, and future perspectives of layered materials in EMI shielding and MW absorption applications.
Article
Chemistry, Multidisciplinary
Annu Kumari, Chandan Kumar Maity, Ganesh Chandra Nayak, Swapan Dey
Summary: Developing a solid organic emitter based on an improved oxazaborinine complex is crucial for meeting the growing demand in optical and electrochemical technology. Two oxazaborinine complexes (TNB and DNB) decorated with naphthalene and triphenylamine have been developed, which exhibit red light emission in the solid phase. Their potential as asymmetric supercapacitor electrodes in aqueous electrolytes is also being investigated.
Article
Chemistry, Multidisciplinary
Le Nhu Minh Tue, Sumanta Sahoo, Ganesh Dhakal, Van Hoa Nguyen, Jintae Lee, Yong Rok Lee, Jae-Jin Shim
Summary: Metal sulfides (MS) and mixed metal sulfides (MTMS), such as NiCo2S4 and 2D MS MoS2, were synthesized through a solvothermal process and used as electrodes for supercapacitors. The resulting electrode showed excellent coulombic efficiency, high specific capacitance, superior energy density, and ultra-high cycling stability. The hybrid supercapacitor device also exhibited impressive coulombic efficiency and good cycling stability, as well as decent energy density over a large number of cycles.
Article
Engineering, Multidisciplinary
Chandan Kumar Maity, Shrabani De, Asutosh Panigrahi, Sourav Acharya, Kartikey Verma, Myung Jong Kim, Ganesh Chandra Nayak
Summary: Utilizing toxic-pollutant cigarette smoke for the synthesis of carbon dots and fabricating supercapacitor electrodes can mitigate energy crisis and environmental pollution issues.
COMPOSITES PART B-ENGINEERING
(2023)
Article
Agricultural Engineering
Chandan Kumar Maity, Shrabani De, Kartikey Verma, Md Moniruzzaman, Sumanta Sahoo
Summary: Energy storage devices are of great importance in modern science and technology due to global population growth and environmental pollution. Developing renewable energy storage devices using sustainable materials is a critical challenge. Nanocellulose and its derivatives have been widely explored in secondary batteries and supercapacitors. This review article discusses the current developments, characteristics, synthetic approaches, application forecasts, advantages, and future prospects of nanocellulose for energy storage technologies.
INDUSTRIAL CROPS AND PRODUCTS
(2023)
Article
Chemistry, Multidisciplinary
Manjiri A. Mahadadalkar, Ganesh Dhakal, Sumanta Sahoo, Deivasigamani Ranjith Kumar, Marjorie Lara Baynosa, Van Quang Nguyen, Mostafa Saad Sayed, Abdelrahman M. Rabie, Woo Kyoung Kim, Jae-Jin Shim
Summary: In this study, a TiO2/In2S3 heterojunction composite photocatalyst was successfully prepared through a simple low-temperature hydrothermal method. The composite showed excellent photocatalytic degradation performance for Rhodamine B under solar light irradiation, with a degradation rate of 99.9% in just 20 minutes. The environmentally friendly synthesis process and high stability make the TiO2/In2S3 composite a promising candidate for cost-effective wastewater treatment.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2023)
Article
Chemistry, Physical
Tensangmu Lama Tamang, Sumanta Sahoo, Jae-Jin Shim
Summary: To design high-performance hybrid supercapacitors, this study proposes the use of hollow ternary mixed metal sulfides as the positive electrode and iron oxide-decorated nitrogen-doped reduced graphene oxide as the negative electrode. The positive electrode exhibits high specific capacity and excellent rate capability, while the negative electrode shows maximum specific capacity. The hybrid device composed of these electrodes demonstrates impressive energy density, providing a facile strategy for optimizing and integrating electrode materials for efficient energy storage in hybrid supercapacitors.
JOURNAL OF POWER SOURCES
(2023)
Review
Thermodynamics
Iftikhar Hussain, Charmaine Lamiel, Muhammad Sufyan Javed, Muhammad Ahmad, Sumanta Sahoo, Xi Chen, Ning Qin, Sarmad Iqbal, Shuai Gu, Yuxiang Li, Christodoulos Chatzichristodoulou, Kaili Zhang
Summary: MXene, a two-dimensional transition metal carbide, nitrides, and/or carbonitrides, shows great potential in various research fields due to its excellent conductivity, hydrophilicity, and abundant surface functional groups. However, challenges in aggregation and low stability greatly limit its applicability. MXenes can be synthesized through techniques such as exfoliation of MAX phases assisted by HF and nonHF materials, and bottom-up approaches utilizing vapor deposition and templating methods. MXene-based heterostructure composites have been investigated as potential nanomaterials for energy storage, and this article provides an overview of MXene synthesis and current developments in MXene-based heterostructure composites for electrochemical energy storage devices. Challenges and difficulties in the future design of MXene-based heterostructure composites are also discussed.
PROGRESS IN ENERGY AND COMBUSTION SCIENCE
(2023)
Article
Energy & Fuels
Rajesh Kumar, Sumanta Sahoo, Ednan Joanni, Raghvendra Pandey, Wai Kian Tan, Go Kawamura, Stanislav A. Moshkalev, Atsunori Matsuda
Summary: Dry microwave (MW) strategy was utilized to synthesize uniformly sized CoO nanocrystals dispersed on nitrogen-doped reduced graphene oxide nanosheets (N-rGO NSs). The MW treatment exfoliated, reduced and combined graphite oxide with available nitrogen, forming N-rGO NSs. Simultaneously, Co ions reacted with oxygen functionalities on N-rGO NSs to form CoO (N-rGO@CoO) nanocrystals. The resulting N-rGO@CoO nanocomposites exhibited excellent surface morphology and electrochemical performance for supercapacitor (SC) applications.
JOURNAL OF ENERGY STORAGE
(2023)
Article
Chemistry, Multidisciplinary
Anadi Singhamahapatra, Chinmayee Pattnaik, Bishnu Prasad Kar, Ganesh Chandra Nayak, Laxmi Narayan Sahoo, Satyanarayan Sahoo
Summary: This work describes the synthesis of a new class of glycolipids with structural diversity in the linkage region and the aglycon part. The glycolipids were synthesized using Cu(I) catalyzed click reaction and incorporated diverse peptide foldamer groups. The synthesized glycolipids were characterized and the impact of different bonds on their morphology was analyzed.
JOURNAL OF THE SERBIAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Rajesh Kumar, Sumanta Sahoo, Ednan Joanni, Raghvendra Pandey, Jae-Jin Shim
Summary: Vacancies play a crucial role in determining the behavior of materials and researchers have introduced vacancies into 2D materials to achieve high-performance electrodes for energy storage. This article focuses on recent advances in vacancy engineering of 2D materials for supercapacitors and secondary batteries. Vacancy defects enhance charge-transfer processes and serve as additional host sites for ion diffusion. The article also summarizes the development of defect creation approaches and detection techniques for vacancies in these materials.
CHEMICAL COMMUNICATIONS
(2023)
Article
Engineering, Electrical & Electronic
Sourav Acharya, Shrabani De, Ganesh Chandra Nayak
Summary: This study focuses on waste processing and the need for cheaper and more efficient energy storage devices. Nanocellulose was extracted from various waste materials and modified with CNT to create supercapacitor electrodes. Ni-Al LDH was added to bind the nanocellulose and CNT and enhance pseudocapacitance. The optimized devices showed high specific capacitance, energy density, and stability, contributing to the goal of converting waste to energy.
ACS APPLIED ELECTRONIC MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Anadi Singhamahapatra, Chinmayee Pattnaik, Bishnu Prasad Kar, Ganesh Chandra Nayak, Laxmi Narayan Sahoo, Satyanarayan Sahoo
Summary: This work describes the synthesis of a new class of glycolipids with structural variations in the linkage region and aglycon part. The synthesized glycolipids were characterized and their self-assemblies were compared to analyze the impact of different structural elements. The use of N-aryl peptoid in glycolipid synthesis was reported for the first time. The optimized structures of the glycolipids were found to be minima in the potential energy surfaces.
JOURNAL OF THE SERBIAN CHEMICAL SOCIETY
(2023)