Functional Metallofullerene Materials and Their Applications in Nanomedicine, Magnetics, and Electronics

Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond

(2019) Fupin Liu et al.   Nature Communications

Changing the Hydrophobic MOF Pores through Encapsulating Fullerene C60 and Metallofullerene Sc3C2@C80

(2019) Haibing Meng et al.   Journal of Physical Chemistry C

High Blocking Temperature of Magnetization and Giant Coercivity in the Azafullerene Tb2 @C79 N with a Single-Electron Terbium-Terbium Bond

(2019) Georgios Velkos et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

RF-assisted gadofullerene nanoparticles induces rapid tumor vascular disruption by down-expression of tumor vascular endothelial cadherin

(2018) Xue Li et al.   BIOMATERIALS

Anisotropic Paramagnetic Properties of Metallofullerene Confined in a Metal–Organic Framework

(2018) Chong Zhao et al.   Journal of Physical Chemistry C

Distance Measurement of a Noncovalently Bound Y@C82 Pair with Double Electron Electron Resonance Spectroscopy

(2018) Guzmán Gil-Ramírez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Endohedral Metallofullerene as Molecular High Spin Qubit: Diverse Rabi Cycles in Gd2@C79N

(2018) Ziqi Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Magnetization relaxation in the single-ion magnet DySc2N@C80: quantum tunneling, magnetic dilution, and unconventional temperature dependence

(2018) D. S. Krylov et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Qubit crossover in the endohedral fullerene Sc3C2@C80

(2018) Zheng Liu et al.   Chemical Science

Optically Controlled Molecular Metallofullerene Magnetism via an Azobenzene-Functionalized Metal–Organic Framework

(2018) Haibing Meng et al.   ACS Applied Materials & Interfaces

Strong carbon cage influence on the single molecule magnetism in Dy–Sc nitride clusterfullerenes

(2018) Christin Schlesier et al.   CHEMICAL COMMUNICATIONS

Carbide clusterfullerene DyYTiC@C80 featuring three different metals in the endohedral cluster and its single-ion magnetism

(2018) Ariane Brandenburg et al.   CHEMICAL COMMUNICATIONS

Mechanisms of Antioxidant Activities of Fullerenols from First Principles Calculation

(2018) Zhenzhen Wang et al.   JOURNAL OF PHYSICAL CHEMISTRY A

DySc2N@C80 Single-Molecule Magnetic Metallofullerene Encapsulated in a Single-Walled Carbon Nanotube

(2018) Ryo Nakanishi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Magnetic hysteresis in self-assembled monolayers of Dy-fullerene single molecule magnets on gold

(2018) C.-H. Chen et al.   Nanoscale

Triptycene molecular rotors mounted on metallofullerene Sc3C2@C80 and their spin–rotation couplings

(2018) Haibing Meng et al.   Nanoscale

An implanted paramagnetic metallofullerene probe within a metal–organic framework

(2018) Haibing Meng et al.   Nanoscale

Partial magnetic ordering in one-dimensional arrays of endofullerene single-molecule magnet peapods

(2018) Stanislav M. Avdoshenko et al.   Nanoscale

Awaking N-hyperfine couplings in charged yttrium nitride endohedral fullerenes

(2017) Chong Zhao et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Switching Molecular Conformation with the Torque on a Single Magnetic Moment

(2017) Aram Kostanyan et al.   PHYSICAL REVIEW LETTERS

Selective arc-discharge synthesis of Dy2S-clusterfullerenes and their isomer-dependent single molecule magnetism

(2017) Chia-Hsiang Chen et al.   Chemical Science

Single molecule magnet with an unpaired electron trapped between two lanthanide ions inside a fullerene

(2017) Fupin Liu et al.   Nature Communications

Gd@C82-(ethylenediamine)8 Nanoparticle: A New High-Efficiency Water-Soluble ROS Scavenger

(2016) Jie Li et al.   ACS Applied Materials & Interfaces

Controlling the magnetic properties of dysprosium metallofullerene within metal–organic frameworks

(2016) Yongjian Li et al.   DALTON TRANSACTIONS

Triangular Monometallic Cyanide Cluster Entrapped in Carbon Cage with Geometry-Dependent Molecular Magnetism

(2016) Fupin Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Methane as a Selectivity Booster in the Arc-Discharge Synthesis of Endohedral Fullerenes: Selective Synthesis of the Single-Molecule Magnet Dy2TiC@C80and Its Congener Dy2TiC2@C80

(2015) Katrin Junghans et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electron transport in endohedral metallofullerene Ce@C82 single-molecule transistors

(2015) Naoya Okamura et al.   APPLIED PHYSICS LETTERS

Steering Metallofullerene Electron Spin in Porous Metal–Organic Framework

(2015) Yongqiang Feng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Thermoelectricity at the molecular scale: a large Seebeck effect in endohedral metallofullerenes

(2015) See Kei Lee et al.   Nanoscale

Molecular design and control of fullerene-based bi-thermoelectric materials

(2015) Laura Rincón-García et al.   NATURE MATERIALS

Gd-metallofullerenol nanomaterial as non-toxic breast cancer stem cell-specific inhibitor

(2015) Ying Liu et al.   Nature Communications

Molecular magnetic switch for a metallofullerene

(2015) Bo Wu et al.   Nature Communications

Radioactive lutetium metallofullerene 177LuxLu(3−x)N@C80–PCBPEG derivative: a potential tumor-targeted theranostic agent

(2015) Guoqiang Zhang et al.   Journal of Materials Chemistry B

A highly efficient and tumor vascular-targeting therapeutic technique with size-expansible gadofullerene nanocrystals

(2015) Mingming Zhen et al.   Science China-Materials

Intra-tumor distribution of metallofullerene using micro-particle induced X-ray emission (PIXE)

(2014) Yohei Yamamoto et al.   APPLIED RADIATION AND ISOTOPES

The Metallofullerene Field-Induced Single-Ion Magnet HoSc2N@C80

(2014) Jan Dreiser et al.   CHEMISTRY-A EUROPEAN JOURNAL

A novel organic electrical memory device based on the metallofullerene-grafted polymer (Gd@C 82 -PVK)

(2014) Dongmei Yue et al.   ORGANIC ELECTRONICS

Tunneling, remanence, and frustration in dysprosium-based endohedral single-molecule magnets

(2014) Rasmus Westerström et al.   PHYSICAL REVIEW B

Carbide Cluster Metallofullerenes: Structure, Properties, and Possible Origin

(2013) Xing Lu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Endohedral Fullerenes

(2013) Alexey A. Popov et al.   CHEMICAL REVIEWS

Micron-sized hexagonal single-crystalline rods of metal nitride clusterfullerene: preparation, characterization, and photoelectrochemical application

(2013) Ying Xu et al.   Nanoscale

A Co-Crystal Composed of the Paramagnetic Endohedral Metallofullerene La@C82 and a Nickel Porphyrin with High Electron Mobility

(2012) Satoru Sato et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper and Oxidative Stress in the Pathogenesis of Alzheimer’s Disease

(2012) Gözde Eskici et al.   BIOCHEMISTRY

Metallofullerene-Nanoplatform-Delivered Interstitial Brachytherapy Improved Survival in a Murine Model of Glioblastoma Multiforme

(2012) John D. Wilson et al.   BIOCONJUGATE CHEMISTRY

Susceptible electron spin adhering to an yttrium cluster inside an azafullerene C79N

(2012) Yihan Ma et al.   CHEMICAL COMMUNICATIONS

Unexpected Formation of a Sc3C2@C80 Bisfulleroid Derivative

(2012) Hiroki Kurihara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Endohedral Single-Molecule Magnet with Long Relaxation Times: DySc2N@C80

(2012) Rasmus Westerström et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electron transport through single endohedral Ce@C82metallofullerenes

(2012) Satoshi Kaneko et al.   PHYSICAL REVIEW B

Molecular mechanism of pancreatic tumor metastasis inhibition by Gd@C82(OH)22 and its implication for de novo design of nanomedicine

(2012) S.-g. Kang et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Current-Driven Dynamics in Molecular Junctions: Endohedral Fullerenes

(2011) Ryan Jorn et al.   ACS Nano

Gadolinium metallofullerenol nanoparticles inhibit cancer metastasis through matrix metalloproteinase inhibition: imprisoning instead of poisoning cancer cells

(2011) Huan Meng et al.   Nanomedicine-Nanotechnology Biology and Medicine

Gd@C82metallofullerenes for neutron capture therapy—fullerene solubilization by poly(ethylene glycol)-block-poly(2-(N,N-diethylamino)ethyl methacrylate) and resultant efficacyin vitro

(2011) Yukichi Horiguchi et al.   SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS

Potent Angiogenesis Inhibition by the Particulate Form of Fullerene Derivatives

(2010) Huan Meng et al.   ACS Nano

[Gd@C82(OH)22]n Nanoparticles Induce Dendritic Cell Maturation and Activate Th1 Immune Responses

(2010) De Yang et al.   ACS Nano

Spin Divergence Induced by Exohedral Modification: ESR Study of Sc3C2@C80Fulleropyrrolidine

(2010) Taishan Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

High Relaxivity Trimetallic Nitride (Gd3N) Metallofullerene MRI Contrast Agents with Optimized Functionality

(2010) Jianfei Zhang et al.   BIOCONJUGATE CHEMISTRY

Effects of H2O2 on electrical membrane properties of skeletal myotubes

(2010) Elisa Luin et al.   FREE RADICAL BIOLOGY AND MEDICINE

Metallofullerene nanoparticles circumvent tumor resistance to cisplatin by reactivating endocytosis

(2010) X.-J. Liang et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Antioxidant properties of fullerenol C60(OH)24in rat kidneys, testes, and lungs treated with doxorubicin

(2010) Branislava Srdjenovic et al.   TOXICOLOGY MECHANISMS AND METHODS

Tuning Conversion Efficiency in Metallo Endohedral Fullerene-Based Organic Photovoltaic Devices

(2009) Russel B. Ross et al.   ADVANCED FUNCTIONAL MATERIALS

Facile Preparation of a New Gadofullerene-Based Magnetic Resonance Imaging Contrast Agent with High1H Relaxivity

(2009) Chunying Shu et al.   BIOCONJUGATE CHEMISTRY

Apoptotic signaling induced by H2O2-mediated oxidative stress in differentiated C2C12 myotubes

(2009) Parco M. Siu et al.   LIFE SCIENCES

Endohedral fullerenes for organic photovoltaic devices

(2009) Russel B. Ross et al.   NATURE MATERIALS

Observation of13C NMR Chemical Shifts of Metal Carbides Encapsulated in Fullerenes: Sc2C2@C82, Sc2C2@C84, and Sc3C2@C80

(2008) Yuko Yamazaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Conjugation of a Water-Soluble Gadolinium Endohedral Fulleride with an Antibody as a Magnetic Resonance Imaging Contrast Agent

(2008) Chun-Ying Shu et al.   BIOCONJUGATE CHEMISTRY

The scavenging of reactive oxygen species and the potential for cell protection by functionalized fullerene materials

(2008) Jun-Jie Yin et al.   BIOMATERIALS

Organophosphonate Functionalized Gd@C82as a Magnetic Resonance Imaging Contrast Agent

(2008) Chun-Ying Shu et al.   CHEMISTRY OF MATERIALS

Hydrochalarones: A Novel Endohedral Metallofullerene Platform for Enhancing Magnetic Resonance Imaging Contrast

(2008) Darren K. MacFarland et al.   JOURNAL OF MEDICINAL CHEMISTRY

The Strong MRI Relaxivity of Paramagnetic Nanoparticles

(2008) Gengmei Xing et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Tunnelling spectra of individual magnetic endofullerene molecules

(2008) Jacob E. Grose et al.   NATURE MATERIALS