4.7 Article

Precise Synthesis of Polymer Particles Spanning from Anisotropic Janus Particles to Heterogeneous Nanoporous Particles

Journal

MACROMOLECULES
Volume 52, Issue 9, Pages 3237-3243

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.9b00199

Keywords

-

Funding

  1. National Natural Science Foundation of China [21872158, 21425314]
  2. National Key R&D Program of China [2018YFC1105301]
  3. National Program for Special Support of Eminent Professionals

Ask authors/readers for more resources

Precise synthesis of polymer particles with topology and surface chemistry spanning from isotropy to anisotropy is critically needed for the fundamental research and industrial production. Herein, we report a seed wettability-manipulated emulsion interfacial polymerization to precisely synthesize polymer particles spanning from anisotropic Janus particles to spherical heterogeneous nano porous particles. The variation of seed wettability from hydrophobicity to hydrophilicity allows a topological transition of obtained polymer particles from anisotropic Janus particles to spherical heterogeneous nanoporous particles, along with the distribution of surface chemistry. This large-span evolution of topology and surface chemistry of obtained particles is due to the shifting of the initially polymerizable emulsion interface from oil-in-water (O/W) to water-in-oil-in-water (W/O/W) driven by osmotic pressure. This seed wettability-manipulated emulsion interfacial polymerization is applicable to a variety of hydrophobic/hydrophilic monomer pairs, allowing flexible fabrication of diverse Janus particles and heterogeneous nanoporous particles.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Multidisciplinary

Hydrophilic/Oleophilic Magnetic Janus Particles for the Rapid and Efficient Oil-Water Separation

Yongyang Song, Jiajia Zhou, Jun-Bing Fan, Wenzhong Zhai, Jingxin Meng, Shutao Wang

ADVANCED FUNCTIONAL MATERIALS (2018)

Article Polymer Science

Janus Particles Synthesis by Emulsion Interfacial Polymerization: Polystyrene as Seed or Beyond?

Jun-Bing Fan, Hong Liu, Yongyang Song, Zhen Luo, Zhongyuan Lu, Shutao Wang

MACROMOLECULES (2018)

Article Chemistry, Physical

Engineering subcellular-patterned biointerfaces to regulate the surface wetting of multicellular spheroids

Luying Wang, Pingqiang Cai, Jing Luo, Feilong Zhang, Jian Liu, Yupeng Chen, Zhongpeng Zhu, Yongyang Song, Bingquan Yang, Xi Liu, Xiaodong Chen, Shutao Wang

NANO RESEARCH (2018)

Article Chemistry, Physical

Emergence of photoluminescence on bulk MoS2 by laser thinning and gold particle decoration

Lili Gong, Qi Zhang, Liangjun Wang, Jianfeng Wu, Cheng Han, Bo Lei, Wei Chen, Goki Eda, Kuan Eng Johnson Goh, Chorng Haur Sow

NANO RESEARCH (2018)

Article Chemistry, Multidisciplinary

Interfacially Polymerized Particles with Heterostructured Nanopores for Glycopeptide Separation

Yongyang Song, Xiuling Li, Jun-Bing Fan, Hongjian Kang, Xiaofei Zhang, Cheng Chen, Xinmiao Liang, Shutao Wang

ADVANCED MATERIALS (2018)

Article Chemistry, Multidisciplinary

pH-Regulated Heterostructure Porous Particles Enable Similarly Sized Protein Separation

Yongyang Song, Jun-Bing Fan, Xiuling Li, Xinmiao Liang, Shutao Wang

ADVANCED MATERIALS (2019)

Article Chemistry, Multidisciplinary

Bioinspired Microfluidic Device by Integrating a Porous Membrane and Heterostructured Nanoporous Particles for Biomolecule Cleaning

Jun-Bing Fan, Jing Luo, Zhen Luo, Yongyang Song, Zhao Wang, Jingxin Meng, Binshuai Wang, Shudong Zhang, Zijian Zheng, Xiaodong Chen, Shutao Wang

ACS NANO (2019)

Article Materials Science, Multidisciplinary

Asymmetric Janus adhesive tape prepared by interfacial hydrosilylation for wet/dry amphibious adhesion

Xizi Wan, Zhen Gu, Feilong Zhang, Dezhao Hao, Xi Liu, Bing Dai, Yongyang Song, Shutao Wang

NPG ASIA MATERIALS (2019)

Article Chemistry, Multidisciplinary

Unusual Nanofractal Microparticles for Rapid Protein Capture and Release

Yongyang Song, Xuefang Dong, Danyi Shang, Xiaofei Zhang, Xiuling Li, Xinmiao Liang, Shutao Wang

Summary: This study demonstrates the synthesis of nanofractal microparticles with rapid protein capture, release, and separation capabilities using a strategy of electrostatic interaction regulated emulsion interfacial polymerization. The controlled growth of nanostructures at the microparticle surface enables fast and efficient protein separation.

SMALL (2021)

Review Chemistry, Multidisciplinary

Emerging Nanoporous Materials for Biomolecule Separation

Yongyang Song, Han Bao, Xinyi Shen, Xiuling Li, Xinmiao Liang, Shutao Wang

Summary: Biomolecule separation is crucial in downstream applications, and nanoporous materials are the leading materials. Recently, emerging nanoporous materials have been reported for efficient biomolecule separation without the need for monolayer modification.

ADVANCED FUNCTIONAL MATERIALS (2022)

Article Chemistry, Multidisciplinary

Utilizing Heterostructured Porous Particles to Improve Traditional Paper Chromatography for Spontaneous Protein Separation

Xu Cheng, Yuemeng Yang, Yongyang Song, Li-Ping Xu, Shutao Wang

Summary: This study presents a method for the spontaneous separation of similarly sized proteins using a combination of heterostructured porous particles and paper strips. The fabricated paper strips are inexpensive, user-friendly, and disposable, and exhibit good separation performance.

LANGMUIR (2022)

Article Multidisciplinary Sciences

Heterostructure particles enable omnidispersible in water and oil towards organic dye recycle

Yongyang Song, Jiajia Zhou, Zhongpeng Zhu, Xiaoxia Li, Yue Zhang, Xinyi Shen, Padraic O'Reilly, Xiuling Li, Xinmiao Liang, Lei Jiang, Shutao Wang

Summary: In this study, the authors synthesized hydrophilic-hydrophobic heterostructure particles (HL-HBPs) using a surface heterogeneous nanostructuring strategy and demonstrated their omnidispersibility. These particles can be dispersed in solvents with different polarity and boiling point, and show efficient adsorption and release of organic dyes.

NATURE COMMUNICATIONS (2023)

Article Chemistry, Physical

Mediator Monomer Regulated Emulsion Interfacial Polymerization to Synthesize Nanofractal Magnetic Particles for Nucleic Acid Separation

Xinyi Shen, Yue Zhang, Duanda Wang, Yanling Huang, Yongyang Song, Shutao Wang

Summary: Polymer-based magnetic particles have been widely used for the separation of biological samples. A new strategy of mediator monomer regulated emulsion interfacial polymerization is presented, which allows effective loading of magnetic nanoparticles and efficient nucleic acid separation. This strategy offers an effective and versatile way for the synthesis of nanoFMPs toward efficient separation in various fields.

SMALL METHODS (2023)

Article Chemistry, Multidisciplinary

Flexible Dry Hydrogel with Lamella-Like Structure Engineered via Dehydration in Poor Solvent

Feilong Zhang, Jiajia Zhou, Zhen Gu, Man Yang, Siheng Li, Yongyang Song, Jun-Bing Fan, Jingxin Meng, Peiyi Wu, Lei Jiang, Shutao Wang

CCS CHEMISTRY (2020)

No Data Available