Article
Engineering, Environmental
Sebastian Wilk, David Medina-Cruz, Marcel Zambrzycki, Piotr K. Szewczyk, Marek Nocun, Elzbieta Menaszek, Thomas J. Webster, Aleksandra Benko
Summary: In this study, carbon nanofiber (CNF) - carbon nanotube (CNT) nanofibrous composites were fabricated by thermal treatment of electrospun polyacrylonitrile precursor. The presence of CNTs affected the structure and chemical composition of the CNF composites and improved their antibacterial performance. These materials exhibited excellent electrical conductivity, cytocompatibility, and antibacterial properties.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Applied
Dan Li, Fangfang Dai, Hao Li, Chi Wang, Xiaowen Shi, Yanxiang Cheng, Hongbing Deng
Summary: In this study, polycaprolactone (PCL) and type collagen (COL) were electrospun to oriented nanofibrous mats, and chitosan (CS) and COL molecules were then deposited on the mats by layer-by-layer self-assembly (LBL) technique. The successful fabrication and modification were confirmed through zeta potential, FT-IR analysis, and XPS measurement. Changes in surface morphology and increased surface roughness were observed during the LBL process, leading to improved mechanical properties and enhanced cell viability on the mats. Cell adhesion and growth along the direction of nanofiber arrangement in LBL modified mats provide an effective strategy for controlled cell growth.
CARBOHYDRATE POLYMERS
(2021)
Article
Biochemistry & Molecular Biology
Mehdi Azizi, Amin Shavandi, Masoud Hamidi, Shayan Gholizadeh, Mahnaz Mohammadpour, Mohammad Saeid Salami, Hadi Samadian
Summary: Tissue engineering is an innovative approach that combines engineering, biomaterials, and biomedicine to improve conventional bone defect treatment. This study developed bioengineered electroactive and bioactive mineralized carbon nanofibers as a scaffold for bone tissue engineering. The fabricated scaffold showed osteoactivity, electrical conductivity, and biocompatibility, making it an effective solution for bone tissue engineering.
JOURNAL OF BIOMOLECULAR STRUCTURE & DYNAMICS
(2023)
Review
Materials Science, Composites
Ayesha Gul, Nader Ghaffari Khaligh, Nurdiana Nordin, Azman Ma'amor, Nurhidayatullaili Muhd Julkapli
Summary: This review presents the synthesis, functionalization, and applications of carbon nanofibers (CNF) in environmental, industrial, and biomedical fields. The article highlights the importance for readers to understand the production, latest trends, and fabrication techniques of CNF to obtain efficient, cost-effective, eco-friendly, and multi-potential applications of CNF-based nanocomposites (CNFN).
POLYMER COMPOSITES
(2023)
Article
Nanoscience & Nanotechnology
Baojin Ma, Alberto Bianco
Summary: Chirality plays a crucial role in the synthesis of biomolecules and the development of life. However, the understanding of the relationship between the intrinsic chirality of engineered materials and biological responses is still in its early stages. This Perspective article discusses three classes of intrinsically chiral engineered materials, namely carbon dots, metal-based materials, and patterned geometries, and highlights the differences in design, structure, and function between enantiomers as well as the effects of intrinsic chirality on biological processes. It also addresses safety concerns, challenges, opportunities, and future directions for the development of intrinsically chiral materials.
NATURE REVIEWS MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Yixing Chen, Chuanjun Tu, Yanli Liu, Ping Liu, Pei Gong, Guangning Wu, Xia Huang, Jian Chen, Tianhua Liu, Jizhou Jiang
Summary: The study presents a synthetic method for carbon nanofibers reinforced carbon graphite composites through liquid-phase mixing. The utilization of carbon nanofibers improves the microstructures and mechanical properties of the composites. The addition of a small amount of carbon nanofibers enhances the densification and mechanical strength of the composites.
Article
Chemistry, Multidisciplinary
Julian Borowec, Victor Selmert, Ansgar Kretzschmar, Kai Fries, Roland Schierholz, Hans Kungl, Ruediger-A. Eichel, Hermann Tempel, Florian Hausen
Summary: An investigation on the conductivity of individual carbon nanofibers (CNFs) and their networks reveals that the microscale CNF networks exhibit good electrical interconnections and a homogeneous current flow. The macroscopic conductivities are strongly correlated with the microscopic results. The presence of highly resistive surface fractions limits the conductivity of CNFs and their networks, and this limitation can be reduced by increasing the carbonization temperature. This study contributes to the understanding of the microstructual models of CNFs and their electrical properties, particularly electron percolation paths.
ADVANCED MATERIALS
(2023)
Review
Materials Science, Multidisciplinary
Victor Morales-Florez, Arturo Dominguez-Rodriguez
Summary: This review article provides a comprehensive overview and discussion on the fabrication methods and mechanical properties improvement of ceramic matrix composites using different carbon allotropes as reinforcements. Although significant improvements have been achieved, there are still some critical issues that need to be addressed in order to fully exploit the potential of this reinforcement strategy.
PROGRESS IN MATERIALS SCIENCE
(2022)
Article
Materials Science, Multidisciplinary
Lulu Zhang, Junchen Luo, Shu Zhang, Jun Yan, Xuewu Huang, Ling Wang, Jiefeng Gao
Summary: The novel photo-thermally induced interfacial sintering method achieves flexible and superhydrophobic CFCs with excellent interfacial adhesion, dual conductive network, and high conductivity, resulting in superb EMI shielding performance in the X band. The CFC also demonstrates durability under cyclic abrasion, stretching, and ultrasonication washing, maintaining its superhydrophobicity, high conductivity, and excellent EMI shielding performance.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2022)
Review
Chemistry, Multidisciplinary
Puranjan Mishra, Junsang Lee, Deepak Kumar, Ricardo O. Lauro, Nazua Costa, Deepak Pathania, Smita Kumar, Jinwoo Lee, Lakhveer Singh
Summary: Nanoenzyme electrocatalyst serves as a powerful tool to explore bioinspired solutions for global energy and environmental concerns. Efforts in designing novel nanoenzymes have led to the creation of innovative catalysts with high catalytic activity, low cost, high stability and versatility, contributing to environmental protection and energy technology development.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Review
Biophysics
Ilias Georgakopoulos-Soares, Emmanouil L. Papazoglou, Panagiotis Karmiris-Obratanski, Nikolaos E. Karkalos, Angelos P. Markopoulos
Summary: This article discusses the correlation between surface roughness and antibacterial properties. It introduces the concepts of surface roughness and texture, and describes the impact of different machining and treatment methods on antibacterial properties. It provides a thorough analysis of bacterial adhesion and growth, and comprehensively reviews the most recent studies in this research area. The authors aim to assist and promote further research by providing a systematic review of recent advances.
COLLOIDS AND SURFACES B-BIOINTERFACES
(2023)
Article
Materials Science, Multidisciplinary
Mahdi Arad, Komeil Nasouri
Summary: In this study, carbon nanofibers were successfully fabricated from a special polyacrylonitrile copolymer/graphene nanoplates composite via electrospinning and subsequent stabilization and carbonization processes. The morphological and structural properties of the composite nanofibers were found to be influenced by the concentration of graphene nanoplates, with higher concentration leading to finer and more crystalline fibers. The addition of graphene nanoplates also significantly improved the electrical conductivity of the carbon nanofibers.
DIAMOND AND RELATED MATERIALS
(2023)
Article
Polymer Science
Mingpan Zhang, Fuli Wang, Xinran Shi, Jing Wei, Weixia Yan, Yihang Dong, Huiqiang Hu, Kai Wei
Summary: In this study, a Fe2O3/CNFs composite was prepared using electrospinning and hydrothermal methods. The characterization showed that Fe2O3 nanoparticles with a size of approximately 90 nm and uniform distribution were obtained under specific reaction conditions. The composite exhibited excellent photodegradation performance in decolorizing MO, achieving a decolorization rate of over 99% within 1 hour.
Article
Chemistry, Physical
Michalina Ehlert, Aleksandra Radtke, Katarzyna Roszek, Tomasz Jedrzejewski, Piotr Piszczek
Summary: The paper discusses the surface modification of Ti6Al4V substrate using alkaline treatment and porous coating production, compared the ability of unmodified and modified titanium alloy to form apatite in simulated body fluids, characterized the structure and composition of the coatings using various analytical methods, and evaluated the biointegration properties of the coatings. The results show that surfaces covered by TiO2 nanoporous coatings modified by titanate layers promote apatite formation and possess optimal biointegration properties for fibroblasts and osteoblasts.
Article
Construction & Building Technology
Dimuthu Wanasinghe, Farhad Aslani, Guowei Ma
Summary: This study investigates the effects of carbon nanofibers, zinc oxide, and activated carbon powder on electromagnetic interference shielding in cementitious composites. The inclusion of 0.5% activated carbon powder combined with carbon fiber showed the best shielding properties among the different additives tested.
CONSTRUCTION AND BUILDING MATERIALS
(2021)
Article
Thermodynamics
Anna Berezicka, Justyna Sulowska, Piotr Jelen, Radoslaw Lach, Magdalena Szumera
Summary: This study provides insights into the influence of sulphate addition on the glass forming properties of SiO2-P2O5-K2O-MgO/CaO/MgOCaO systems. The results show that only the system containing MgO can obtain amorphous materials. The addition of SO3 increases the glass transformation temperature and decreases the vitreous state transformation range and onset of the crystallization process. The precipitate K2SO4 exists in the studied materials regardless of the composition of the base glass.
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
(2023)
Article
Chemistry, Physical
Marcel Zambrzycki, Robert Piech, Sonia Ruiz Raga, Monica Lira-Cantu, Aneta Fraczek-Szczypta
Summary: In this study, a novel Pt-free counter electrode (CE) material, based on hierarchical carbon nanofibers/carbon nanotubes/NiCo (eCNF/CNT/NiCoNP) ternary nanocomposites, was proposed for dye-sensitized solar cells (DSSC). The nanocomposites were obtained through a combination of the electrospinning technique and CCVD synthesis. The morphology, surface chemistry, and structural ordering of the nanocomposites were found to have significant correlations with their electrocatalytic activity. The DSSC with eCNF/CNT/NiCoNP-electrodes exhibited higher efficiencies compared to Pt-based devices, demonstrating the excellent performance of the prepared CE.
Article
Spectroscopy
Anna Kolodziej, Aleksandra Weselucha-Birczynska, Elzbieta Dlugon, Malgorzata Swietek, Maciej Gubernat, Lukasz Skalniak, Marta Blazewicz
Summary: This research investigated the biological potential of two types of polymer nanocomposites and studied the interaction between cells and materials using techniques such as cell proliferation, fluorescence microscopy, Raman spectroscopy, and two-dimensional correlation spectroscopy. The results showed that these nanocomposites have good biological activity and can identify the complexity of cellular response.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2023)
Article
Green & Sustainable Science & Technology
Jaroslaw Chwastowski, Pawel Staron, Ewa Pieta, Czeslawa Paluszkiewicz
Summary: The study investigated using waste beet pulp shreds as a sorbent to remove crystal violet dye from water and explored the antimicrobial properties of the resulting material. Equilibrium and kinetic studies were conducted to examine the sorption process of crystal violet dye on beet pulp shreds. The Langmuir isotherm model showed the best fit, with a sorption capacity of 28.07 mg/g. Kinetic studies and FT-IR analysis confirmed that the sorption process of crystal violet dye on beet pulp shreds is chemical. The obtained material demonstrated growth inhibition of selected microorganisms, with Escherichia coli and Pseudomonas aeruginosa being more resistant than Candida albicans and Staphylococcus aureus.
Article
Materials Science, Ceramics
Krystian Sokolowski, Izabela Pszczola, Stanislaw Blazewicz, Andrzej Bernasik, Kamil Kornaus, Aneta Fraczek-Szczypta
Summary: The purpose of the study was to determine the conditions for preparing CF to obtain carbide composites with favorable mechanical response. The study investigated the relationship between the interfacial properties of fiber/polymethylsiloxane composites and the mechanical properties of resulting fiber/carbide composites. The CF/resin interfacial strength was modified using different methods, and the study revealed different bonding characteristics at the fiber/resin and fiber/ceramics interfaces. Silanization of CF significantly improved the interfacial shear strength, while reducing the flexural properties of the carbide composites. The most promising treatment method for CF in PIP-based ceramic composites was modification with PyC, which resulted in enhanced interfacial shear strength, flexural strength, and work to fracture compared to unmodified CF.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2023)
Article
Spectroscopy
Magdalena Gaweda, Piotr Jelen, Maciej Bik, Magdalena Szumera, Zbigniew Olejniczak, Maciej Sitarz
Summary: Vibrational spectroscopy is an indispensable tool for examining silicon oxycarbide-based amorphous materials. In this study, SiOC glasses were modified with phosphate ions, and the structural examination was mainly carried out using infrared and Raman spectroscopy. The obtained results proved the efficient preparation of desired materials with structural parameters similar to the unmodified one.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2023)
Article
Chemistry, Physical
Anna Kusior, Piotr Jelen, Maciej Sitarz, Konrad Swierczek, Marta Radecka
Summary: Flower-like TiO2 nanostructures were obtained by chemical oxidation and subsequent annealing. The phase transformation of 3D flower-like titanium dioxide nanostructures was analyzed, and the effects of annealing atmosphere, sample thickness, grain shape, and nanoflower size were discussed. SEM, XRD, and Raman spectroscopy were used for characterization. The photoelectrochemical performance of the anode based on flower-like TiO2 was demonstrated, with the thickness and phase composition of the anodes being critical factors.
Article
Chemistry, Analytical
Ewa Pieta, Czeslawa Paluszkiewicz, Wojciech M. Kwiatek, Maria Rosa Lopez-Ramirez
Summary: This study describes the vibrational properties of the anticancer drug batimastat (BB-94) as an inhibitor of extracellular matrix metalloproteinase and its adsorption on a silver roughened electrode surface using surface-enhanced Raman spectroscopy (SERS). The research reveals that the applied electrode potential and excitation wavelengths greatly influence the molecule-metal interface. By calculating molecular geometry and Raman frequencies, the nature of vibrational modes is clarified, and it is found that certain parts of the molecule interact with the metal surface, resulting in enhanced SERS signal. Additionally, different adsorption species or metal complexes on the surface could contribute to the observed SERS spectra.
Article
Chemistry, Inorganic & Nuclear
Patryk Szymczak, Piotr Jele, Anna Adamczyk, Bartosz Handke
Summary: The study investigated the effect of microwave-induced oxygen plasma on Dodecaphenyl-POSS (Ph12T12) thin films obtained by Physical Vapor Deposition (PVD) in an Ultra-High Vacuum (UHV) system. Oxygen plasma treatment resulted in the formation of a new material with preserved cage-like structure in Ph12T12 thin films. XRR, Raman spectroscopy, and AFM were used to examine the films, revealing significant changes in microstructure, chemical composition, and topography after annealing. Thermal and plasma treatment improved the thermal resistance of the surface layer, and XRR modeling enabled the determination of interphase composition.
SOLID STATE SCIENCES
(2023)
Article
Nutrition & Dietetics
Karolina Krupa-Kotara, Jaroslaw Markowski, Agnieszka Gdanska, Mateusz Grajek, Eliza Dzialach, Grzegorz Szlachta, Mateusz Rozmiarek
Summary: This study aims to assess the relationship between global self-esteem, body composition, and physical activity among Polish students. The results showed a negative correlation between body weight and BMI and global self-esteem, while higher levels of physical activity were associated with higher global self-esteem. The study suggests that maintaining healthy physical activity and body composition can help improve global self-esteem.
Article
Engineering, Biomedical
Aneta Fraczek-Szczypta, Natalia Kondracka, Marcel Zambrzycki, Maciej Gubernat, Pawel Czaja, Miroslawa Pawlyta, Piotr Jelen, Ryszard Wielowski, Danuta Jantas
Summary: The goal of this study was to develop electrode materials for nerve tissue stimulation using carbon-carbon composites with a core of carbon fibers and a pyrolytic carbon matrix. The materials were characterized using various techniques to evaluate their microstructural, chemical, and surface properties, and their biocompatibility was assessed using a neuroblastoma cell line.
JOURNAL OF FUNCTIONAL BIOMATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Anna Sliz, Marta Radecka, Piotr Jelen, Dominik Dorosz, Katarzyna Zakrzewska
Summary: This study investigated upconversion as a modification strategy to enhance the utilization of sunlight in titanium dioxide photoanodes. Thin films of TiO2 containing Er activator and Yb sensitizer were deposited on conducting glass, amorphous silica, and silicon. Evaluation of the thin film composition, structure, and microstructure was conducted using various techniques including scanning electron microscopy and X-ray diffraction. The optical and photoluminescence properties were measured, and upconversion effects were observed upon laser excitation.
Article
Metallurgy & Metallurgical Engineering
E. Stodolak-Zych, M. Kudzin, K. Kornaus, M. Gubernat, E. Kaniuk, M. Bogun
Summary: This study aimed to fabricate a non-woven carbon fiber through magnetron sputtering surface modification. The results showed that longer iron sputtering time led to a more uniform layer on the fiber surface and decreased wettability. The material exhibited good biocompatibility with osteoblast-like cells.
ARCHIVES OF METALLURGY AND MATERIALS
(2023)